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Carbyne: a Form of Carbon Even Stronger Than Graphene

New submitter Dialecticus writes "Sebastian Anthony at ExtremeTech has written an article about research into the physical properties of carbyne, an elusive form of carbon. A new mathematical analysis by Mingjie Liu and others at Rice University suggests that carbyne may achieve double the strength of graphene, stealing its crown and becoming the strongest material known to man. 'While carbyne cannot be stretched, it can be bent into an arc or circle — and by doing so, the additional strain between the carbon atoms alters the electrical bandgap. This property could lead to some interesting uses in microelectromechanical systems (MEMS). By adding different molecules to the end of a carbyne chain, such as a methylene (CH2) group, carbyne can also be twisted — much like a strand of DNA — again adding strain and modifying the electrical bandgap. By "decorating" carbyne chains with different molecules, other properties can be added, too: Tack some calcium atoms on the end, which like to mop up spare hydrogen molecules, and suddenly you have a high-density, reversible hydrogen storage sponge. It’s also important to note that, just like graphene, carbyne is just one atom thick. This means that, for a given mass of carbyne, its surface area is relatively massive. A single gram of graphene, for example, has a surface area of about five tennis courts. This could be very important in areas such as energy storage (batteries, supercapacitors), where the surface area of the electrode is directly proportional to the energy density of the device.'"

48 of 82 comments (clear)

  1. When do I get my exoskeleton? by haruchai · · Score: 4, Funny

    Been hearing so many wonderful things about exotic forms of carbon but when do I get something I can buy ( at a reasonable price )?

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    1. Re:When do I get my exoskeleton? by Anonymous Coward · · Score: 1

      When it can be made cheaply in bulk, that's the problem.

    2. Re:When do I get my exoskeleton? by NEDHead · · Score: 4, Funny

      When I was a kid, I used to buy a sophisticated carbon product for data recording. At the time a pencil was two cents...

    3. Re:When do I get my exoskeleton? by haruchai · · Score: 1

      You could BUY carbon?
      We had to set fire to the school so all the kids could have something to write with.

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    4. Re:When do I get my exoskeleton? by strack · · Score: 2

      welcome to science journalism. so many wonderful promises, unfufilled

    5. Re:When do I get my exoskeleton? by EdZ · · Score: 1

      You get your exoskeleton as soon as battery density increases, or generator+turbine volume decreases. If you;re happy with a tether, the XOS2 (and countless other research devices) work just fine right now.

    6. Re:When do I get my exoskeleton? by haruchai · · Score: 1

      I guess it's hard to say when a breakthrough will happen. Progress tends to be very incremental. When I was much younger, I was promised that flying cars, flat screen TVs you could hang like a painting and fusion would be "a few years" at most.

      Took over 30 yrs just for the TVs, fusion, er, well, "somewhat more than a few years" and counting and the flying cars, well, I suppose we could make them happen very soon if you've got megabucks to spend.

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    7. Re:When do I get my exoskeleton? by ShanghaiBill · · Score: 1

      Been hearing so many wonderful things about exotic forms of carbon but when do I get something I can buy ( at a reasonable price )?

      Like a trip to the moon. They should use this stuff for the space elevator.

    8. Re:When do I get my exoskeleton? by MrL0G1C · · Score: 1
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    9. Re:When do I get my exoskeleton? by lxs · · Score: 1

      If you don't obey the voices your dog will die.

    10. Re:When do I get my exoskeleton? by jellomizer · · Score: 1

      Well, there is a lot of issues here.
      1. Nano-technology needs a lot of money for research and development. Most companies do not want to fund in R&D as they cannot quantify the value.
      2. Governments are trying to show that they are responsible with money so they are not funding R&D because they will get on some media expose on how they are wasting their money playing with pencil lead and scotch tape.
      3. Colleges are getting tight on R&D because there is pressure to cut college costs down.

      Higher Ed + Government + Private Enterprise combined makes new advances. Right now we are blaming our problems on these portions making it difficult for them to help with innovation.

      Higher Ed comes with the early theory's, government pays higher Ed to do further research, private enterprise uses these results to make a product which government and private sectors buy, allowing private enterprise to improve their process, which could bring to new discoveries that Higher Ed to analysis and process and make new theories.

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  2. The real crown... by Anonymous Coward · · Score: 1

    ...will go to whichever material can be put to practical use outside of the research lab.

    1. Re:The real crown... by cyclopropene · · Score: 1

      ...will go to whichever material can be put to practical use outside of the research lab.

      I'd give some cheers if they could even find impractical use outside of a silicon chip!

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  3. But its not... by who_stole_my_kidneys · · Score: 3, Funny

    Transparent Aluminum, I'm still waiting....

    1. Re:But its not... by Anonymous Coward · · Score: 1

      wait no longer..
      http://makezine.com/2012/01/17/transparent-aluminum/
      http://www.youtube.com/watch?v=RnUszxx2pYc

    2. Re:But its not... by Khyber · · Score: 4, Informative

      Oh you silly 7-digit UID holder. You know what we call transparent aluminum?

      Sapphire. Been known as that for a couple centuries.

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  4. Comment removed by account_deleted · · Score: 4, Interesting

    Comment removed based on user account deletion

  5. Five tennis courts by Deadstick · · Score: 2

    ...How much is that in Volkswagens per story?

    1. Re:Five tennis courts by hyades1 · · Score: 1

      If I had even a single moderator point, I swear it would be yours.

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    2. Re:Five tennis courts by Anubis+IV · · Score: 1

      That depends entirely on the current conversion rate between Volkswagens and Libraries of Congress, of course.

    3. Re:Five tennis courts by Anonymous Coward · · Score: 1

      What is the surface area of a tennis court anyway?

      Since they have that funky material on the ground with all those cracks for grip..

  6. Re:Carbyne != Carbine by qwijibo · · Score: 1

    Gun nuts can be scientists too. Or scientists are so myopic that they didn't know that was already a word. Could go either way, but it's cool to see new things like this still being discovered.

  7. Re:Space Elevator by Goldsmith · · Score: 1

    We're still on simulated space elevators.

  8. Re:Space Elevator by wjcofkc · · Score: 1

    What I gather from the article is that it has impact strength but not much in the way of tensile strength. It appears to have a few other interesting properties though.

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  9. It's an alkyne. by Valdrax · · Score: 4, Informative

    Because it's an alkyne of pure carbon. At least, the single/triple alternating version is.

    The double/double form could be named carbene except that that name is already taken. Then again, that didn't seem to stop them here either. The better name for this material is linear acetylenic carbon. Sadly, I don't remember enough organic chemistry to know what the double/double would be called.

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    1. Re:It's an alkyne. by Valdrax · · Score: 1

      Sadly, I don't remember enough organic chemistry to know what the double/double would be called.

      Here's an article on cumulenes, but I don't know what a the proper name of a long chain of it would be.

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    2. Re:It's an alkyne. by cyclopropene · · Score: 1

      Sadly, I don't remember enough organic chemistry to know what the double/double would be called.

      Here's an article on cumulenes, but I don't know what a the proper name of a long chain of it would be.

      The proper name is cumulene. In fact, that's pretty clear from the first line of the Wikipedia article you tried to link:

      A cumulene is a hydrocarbon with three or more cumulative (consecutive) double bonds.

      Emphasis mine.

      One of those days... :)

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  10. Gah, how do I link web? by Valdrax · · Score: 2

    Sorry, here's that article on cumulenes.
    (Stupid Slashdot posting delay... *grumble grumble*)

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  11. It doesn't steal the crown... by tlambert · · Score: 3, Funny

    It doesn't steal the crown... ...until we can freeze Han Solo in it.

    I'm holding out for carbonite.

  12. Re:Carbyne != Carbine by reverseengineer · · Score: 1

    The -yne ending is already in common use for carbon compounds with a triple bond. For example, ethyne (the IUPAC systematic name for acetylene). It's not a very good name in this case though- "carbyne" already refers to a type of reactive species of carbon with three unpaired electrons, in analogy to the more common "carbene" which has two unpaired electrons. Wikipedia suggests a better name for the carbon chain to be "linear acetylenic carbon," though I'll admit it doesn't roll off the tongue. Shorter versions of this molecular chain, which terminate with a hydrogen on each end are generally called polyacetylenes or polyynes.

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  13. Re:Carbyne != Carbine by reverseengineer · · Score: 2

    From the non-chemistry side of the etymology, it is apparently not known with certainty why a short rifle is called a carbine in the first place:

    short rifle, 1580s, from French carabine (Middle French carabin), used of light horsemen and also of the weapon they carried, of uncertain origin, perhaps from Medieval Latin Calabrinus "Calabrian" (i.e., "rifle made in Calabria"). A less-likely theory (Gamillscheg, etc.) connects it to Old French escarrabin "corpse-bearer during the plague," literally (probably) "carrion beetle," said to have been an epithet for archers from Flanders.

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  14. A bit too advanced, perhaps by dutchwhizzman · · Score: 1

    But... how about that flying car?

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  15. Re:Space Elevator by EdZ · · Score: 1

    An straight-up Space Elevator is still way beyond us, even if we could pump out molecularly perfect nanotubes of indefinite length. But smaller tether systems are totally possible; 'stationary' and hypersonic Bolos and Skyhooks, depending on the orbital velocity and tip velocity (itself depending on tether length and rotation rate). You don't need a massive anchor site, you could fly some of the smaller ones in a single launch, and we could make some of the smaller ones with materials we already manufacture in bulk (e.g. Spectra and other tensile Aramids).

    Then there are just fun things you can do, like conductive tether generators and propulsion inside a magnetosphere, or linear tether launchers.

  16. Re:Space Elevator by Anonymous Coward · · Score: 1

    But you're not describing a structure that stretches; you're describing one that telescopes. Not the same thing.

    And while a space elevator won't be fixed at both ends the way a bridge is, it's still going to be subject to outside forces acting on it (high-speed winds in the upper atmospheres, for example). If the bridge parallel bothers you, consider a skyscraper instead - and skyscrapers also need to be elastic enough to sway a little bit.

  17. A mythical compound by Anonymous Coward · · Score: 1

    Perhaps a little more emphasis should be given to the fact that the compound in question has never been synthesized, despite decades of effort. And that one strand would combine explosively with a second, if two such strands could be made.

  18. Re:Space Elevator by fisted · · Score: 1

    > A bridge is fixed at both ends.
    Wrong. Learn2bridges.

  19. one atom thick, is there inner surface & outer by Anonymous Coward · · Score: 1

    Normally, one could measure the inner surface and the outer and compare. You could use any unit of measurement you wanted, such as "atom lengths". For example, you could say that the inner surface is a million atoms long and the outer surface is a 1.03 million.

    This stuff is one atom thick. In this case, the atoms that make up the inner surface are SAME ATOMS as the outer surface. The inside and the outside are the same side! So of course they are the same length, since they are the same atoms.

    In t

  20. Re:Bending IS Stretching by Khyber · · Score: 1

    In a single-atom thick layer, which 'side' stretches?

    There's your answer. Back to school with ye.

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  21. Re: Space Elevator by ceoyoyo · · Score: 1

    I highly doubt we'll ever be able to make strands of this stuff several thousands of km long, so shorter strands will have to be combined. The epoxy or whatever is used to hold them together will undoubtedly have some stretch.

    Also, carbon bonds may not be particularly stretchy, but over that kind of length even a tiny amount will add up to a decent distance. If that's not enough, use the helical form.

  22. Re: Bending IS Stretching by ceoyoyo · · Score: 1

    Atoms have thickness, but bonds are essentially one dimensional.

  23. Methylene by Cow007 · · Score: 1

    Methylene! If they can get their hands on it that is I guess they will probably be stuck a 30 gallon drum or stopping a train, killing anyone who happens by Sorry I just couldn't resist #breakingbad

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  24. Re:Space Elevator by MrL0G1C · · Score: 1

    So sandwich or encase the Carbyne molecules, am I missing something here?

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  25. Re:Space Elevator by Rhywden · · Score: 1

    Instability in organic molecules does not neccessarily mean that it reacts with gasses in the air (namely oxygen).

    It usually means that there's a more stable form it will inevitably convert to. There are countless conversion reactions in organic molecules - exposure to heat, air or light usually only fastens the process. Preventing exposure to these factors does not stop the degradation, however.

    Take batteries as an example. LiIon batteries will degrade regardless of outside factors - and those are pretty much isolated systems. It's only the speed of the degradation you can influence. But rule was, whatever you do, after about three years you'd take a massive hit to the capacity of LiIon batteries.

  26. Re:Bending IS Stretching by jellomizer · · Score: 1

    You got to think 2 dimensionally! Think of having a bunch of sphere magnets, you clip them into a 1 magnet high sheet. Now you can bend the sheet of magnets without stretching them they just roll on each other. You pole is more 3 dimension so you have rows and rows of these things so the upper part will stretch assuming that its bonds are equal on all dimensions.

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  27. Raw Tensile Strength Is Now High Enough by Scotland · · Score: 1

    As a mechanical engineer, I have only ever needed integral calculus outside of school work (including tutoring) three times:
    1. With a friend, for fun, to win a bet. Yay, free beer!
    2. To answer a particular question for work. Yay, happy boss!
    3. Just now, for fun, to determine the required material stiffness for a cable hanging down from geostationary orbit (i.e. a space elevator cable) to support its own weight. Yay, Science!

    Calculated minimum required material stiffness for space elevator cable: 4.9x10^7 N*m/kg.

    This jives with what the 10x10^7 N*m/kg quoted on http://en.wikipedia.org/wiki/Space_elevator (referencing: Edwards, Bradley Carl. The NIAC Space Elevator Program. NASA Institute for Advanced Concepts). This would make perfect sense that he is assuming a safety factor of 2 (safety margin of 100%)

    So, assuming that the nano-scale cross-linking issues mentioned previously in this thread do not reduce the tensile strength too much, and assuming we're okay with a safety factor of only 1.5 (50% safety margin), then we're finally in the ballpark with Carbyne having a material stiffness of about 7.5x10^7 N*m/kg.

    We have the material; we can build it. So now, it's no longer a question of can the physics work, but rather a question of the political and business will to put in the engineering work to make this a reality.

    Very, very cool.

    1. Re:Raw Tensile Strength Is Now High Enough by slothman32 · · Score: 1

      You only use calculus rarely!
      Right now I am using it to have compare 2p and 3s orbitals.
      I get calculus and quantum mech at the same time - wohoo.

      Math and science in general are fun and I do them recreationally all the time.

      Some people watch sports, I multiply polynomials.

      Are you related to the country of Scotland?
      If so then what are your thoughts on the referendum about countyhood next year?

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  28. Question by justthinkit · · Score: 1

    Acetylene features the single & triple carbon bonds. It burns so hot because these bonds are inherently unstable. So how is it that this new substance, with these more-unstable-than-normal-carbon bonds, supposedly *stronger*?

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