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New Way to Make Hydrogen

zymano writes "Hydrogen is expensive to make and difficult to store. The most common way in making hydrogen is electrolyzing pure water. A new startup is trying a new way to make hydrogen. The process uses sodium which industry shuns because it generates sparks and heat when mixed with water. Signa has devised a way to mix sodium with silica gel or crystalline silicon to create a powder that essentially strips electrons from the sodium molecules in advance and stores them. When water is introduced, the chemical reaction proceeds calmly. The powder generates hydrogen efficiently. More than 9 percent of a kilogram of the powder gets converted to hydrogen and little energy is lost through heat."

98 of 591 comments (clear)

  1. The stench that launched a thousand cars by nizo · · Score: 4, Funny
    Thus spake the article:

    Michael Lefenfeld and James Dye of Signa Chemistry wanted to make rooms smell better. Instead, they stumbled on a way that could make hydrogen fuel cells a practical reality.

    Who wants to bet that Michael and James have a room full of stinky unshowered nerds to thank for stumbling onto this innovation?

    1. Re:The stench that launched a thousand cars by boisepunk · · Score: 4, Funny

      Did the scientists that they worked for not get invited to "those kind of parties"?

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      42

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      main(0)
    2. Re:The stench that launched a thousand cars by zerkon · · Score: 2, Informative

      FTA: "Although it's a small company--it only has three full-time employees"

      so I guess only one stinky unshowered nerd

  2. who's electrolysing water? by child_of_mercy · · Score: 4, Interesting

    Coal gas seems to be where the big boys are going.

    Hence here in coal rich australia our rulers are mad keen on the "Hydrogen Economy".

    --
    'There is a Light that never goes out.'
    1. Re:who's electrolysing water? by nokilli · · Score: 2, Interesting

      Yes, but I have enough mercury in my fish already, thank you very much.

      (yeah yeah yeah, you say the new process won't do that, but the coal guys have lied to us sooooo many times now that unless you can pass the no-skid-marks-in-the-briefs test I don't want to hear about it anymore.)

    2. Re:who's electrolysing water? by child_of_mercy · · Score: 2, Interesting

      Oh I agree completely, it's big industry playing for big stakes.

      Just saying don't believe the hype about the so called "Hydrogen economy" being environmentally driven.

      --
      'There is a Light that never goes out.'
    3. Re:who's electrolysing water? by child_of_mercy · · Score: 2, Insightful

      well it all depends on the coal and exactly how they get it out.

      But there are huge markets for the by-products if it's done right.

      There's a lot of money being spent on carbon sequestration (putting it back udnerground) right now as well.

      but with this industry you can bet it'll be the cheapest and dirtiest option they can find.

      --
      'There is a Light that never goes out.'
    4. Re:who's electrolysing water? by flyingsquid · · Score: 4, Interesting
      Just saying don't believe the hype about the so called "Hydrogen economy" being environmentally driven.

      For industry, the advantage of hydrogen is that it's so far in the future: it means they don't have to make changes now. There are a lot of things we could do right now to cut down on foreign oil dependency and greenhouse gas emissions: require better fuel efficiency from new cars, move more quickly towards hybrid vehicles, put in more commuter trains and subways, make cities better designed for walking and cycling. But auto makers and oil companies would lose out. So instead, they throw a few million bucks at hydrogen technologies, and that lets them say "see, we really give a shit!" and then keep building monstrosities of excess like the Hummer 2.

    5. Re:who's electrolysing water? by Green+Salad · · Score: 5, Interesting

      ...and then keep building monstrosities of excess like the Hummer 2...

      Your mostly right, except it's called the H2H for the hydrogen version of the Hummer. (See www.hummer.com and click "Hydrogen Hummer" for a video of the governator of Kalifornia endorsing it.)

    6. Re:who's electrolysing water? by kilodelta · · Score: 2, Insightful

      You are right on the money. For example, Providence, RI used to have trolleys all over the city in from the mid 1800's to the mid 1900's. Granted, the earliest were pulled by horses while the later were propelled by electric motors.

      Not only the city but the entire state has a number of abandoned railways. Of course state government, being in the pocket of big business, thinks turning abandoned rail into bike paths will solve everything. They can't be more wrong.

      There have been many proposals for light rail serving east bay and west bay communities. But the Dept. of Transportation loathes rail. So they dump the money into shoddy highway repairs, etc.

      Our state public transit system is ok, but rail would make it better. But until we're pushed against the wall nobody wants to think about sharing a train car with the unwashed and smelly. In reality, this is a myth at least during commuter hours. But the myth prevails.

    7. Re:who's electrolysing water? by rpresser · · Score: 2, Interesting

      The real problem is that we may not have enough time to change our economy away from oil before rising oil prices do major damage to our economy.

      http://en.wikipedia.org/wiki/Peak_oil

    8. Re:who's electrolysing water? by gordo3000 · · Score: 5, Insightful

      its not something that does damage as in sets us back. people really overblow this problem. It means growth will slow down. And guess what, those rising oil prices are the greatest incentive towards making cars more "green".

      Think about all the people who choose to buy fuel efficient cars. Every person I know who buys them does so because it saves them a great deal of money on gas. Oil prices get up to 70 or 80 dollars a barrel(which isn't hard to imagine with production not increasing by much and China beginning to consume oil on the level of the US) and you will see very few people who are willing to spend 100 dollars to drive a hummer 100 miles. It just gets too damn expensive.

      Money works both ways. Making it drives what companies will produce and saving it drives what consumers demand(in large part). So I say if you really want to protect the environment from car emissions, find some way to double the price of oil rather quickly.

    9. Re:who's electrolysing water? by OwnedByTwoCats · · Score: 2, Informative

      Huge SUVs _were_ popular, up until last year. Sales of medium and large SUVs are down 30% from a year ago.

      There's a GM Assembly plant near here.

    10. Re:who's electrolysing water? by brainstyle · · Score: 2, Insightful
      its not something that does damage as in sets us back. people really overblow this problem

      Unfortunately, this isn't necessarily the case. We are extremely dependent on oil, not just for cheap energy, but as a basis for making stuff. Fertilizers, plastics, lubricants and all sorts of things necessary for the current economy are derived from oil. If the price of oil goes through the roof, things just may go down the crapper.

      Having said that, I hope it's not the case, that the cost of oil keeps rising, and we figure out a way to maintain our standard of living without the reliance on oil we have.

      --
      "Why can't everyone just be straight with me?"
      "Because we live in a bendy world, dear."
    11. Re:who's electrolysing water? by M-G · · Score: 2, Insightful

      And most current production of hydrogen is done by cracking natural gas, not scaling up grade school science class projects...

  3. Yes, but how efficient overall? by dbloodnok · · Score: 5, Informative

    This process may be efficient, but sodium doesnt grow on trees (or mined out of the ground). The easiest way to get it is.... electrolysis of sodium chloride.

    So you've just shifted the electrolysis problem further upstream and instead of using nice friendly water, you're passing current through nasty, mean molten salt.

    1. Re:Yes, but how efficient overall? by red990033 · · Score: 5, Insightful

      This does help solve the problem of distrobution however. You can just ship the powder, and at "gas stations" the water is mixed, and you fill up your tank. Or maybe even a fuel system will be made where you just add the powder directly to the applied device(car, lawnmower, whatever) and the process happens inside the machine itself.

      --
      Do what I say, cuz I said it.
      -Meatwad
    2. Re:Yes, but how efficient overall? by Tatarize · · Score: 5, Insightful

      Well, this is a pretty nice idea. I see it working in only one way. As a storage for the fuel. NaCl doesn't have any energy. H2O doesn't have any energy (chemical). So no matter what the only energy you get out is going to have been put in in a more efficient form. However, if the powder is dense enough in energy that it could be used as the power source itself, and then just recycle the water.

      Ofcourse the original power still come from (mostly) coal to make the electricity to make the split the salt, to break the water, to create the electricity, to power the car, to drive to the house that Jack built. The electrity to electricity conversion is the reason H2 will not be used in cars, unless you can dodge it with a *real* breakthrough, or have the H2 source beat the crap out of batteries it's not going to work. If you could get a pound of Cesium to power the car for a few months that might be worthwhile.

      This said, I'll let you savvy people in on the future. The cars of the future are going to be several generation advanced hybrid cars. They will be flexible fuel hybrids that you can directly charge with your house's power. They will also be augmented with solar panels on the roof, which will also be used to charge the batteries. And if by some freak event H2 becomes available it will also have a fuel cell to charge up the batteries. They will work like a normal car, an electric car, and a solar car all in one, with reclaiming breaks and shocks ofcourse. In theory you could do your driving for the day without using a drop of your gas, but it's there if you need it. And if it's not there you could probably do a few miles per hour with just the solar.

      --

      It is no longer uncommon to be uncommon.
    3. Re:Yes, but how efficient overall? by Tatarize · · Score: 5, Informative

      You are taking a highly efficient easy to transport form of energy (electricity) and using it to perform electrolysis of water (or in this case salt) and then going through a bunch of other steps to end up back at electricity. H2 is really hard to transport, and so long as it takes electricity to make, it's going to be less efficient than just putting the electricity right into the car. And by less efficient I mean way less efficient. It's really a gas so it's energy density is actually much less than that of gasoline. In fact, a gallon of gasoline has more hydrogen than a gallon of liquid hydrogen. Also, as a hydrocarbon you are burning, not only the hydrogen but also the carbon. Hydrogen is hard to transport, hard to use, hard to store, and hard to make. And we make it with the same stuff we want the fuel cell to make it back into.

      As for your comments about NASA this argument is flawed in too many ways. First, hydrogen is used for electrical generation this is obviously true, but batteries just store energy. They are never used for electrical generation. Next we have the problem of scalability. Converting water to H2 takes electricity. And, for storage (if I am to understand) NASA would just store the H2 they could pull it off. There's a large energy loss converting from one form of energy to another. For NASA they can waste a bit of energy if it works out better for them in the long run. They can get the super expensive solar panels and use any amount of energy on land based operations if it saves anything in space based operations because even if it costs a boat load it will still be cheaper than doing it in space.

      NASA could take a 40% loss in overall energy. Compare this loss with all the cars in the US. That's going to be huge. NASA is obviously a special case. They can use spend 20k dollars if it saves ten pounds they don't have to shoot into space.

      Coal -> Electricity -> Hydrogen -> Electricity -> Kinetic.
      or
      Coal -> Electricity -> Sodium -> Hydrogen -> Electricity -> Kinetic.

      Both of these suffer from the same problem. They loop through the same type of fuel (electricity). This is never going to work. It's too inefficient when we are talking about large scale deployment.

      Coal (powerplant) -> Electricity -> Kinetic.
      Solar -> Electricity -> Kinetic.
      Gasoline -> Electricity -> Kinetic.
      Biofuel -> Electricity -> Kinetic.
      Hydrogen (assuming there's a major breakthrough) -> Electricity -> Kinetic.

      From what I can tell here the argument is that hydrogen makes for really crappy batteries so we should use it as such. Even if this were the case the lack of fueling stations for hydrogen should mean that you should just replace your batteries with a closed system electrolysis/water/fuelcell battery, to store the energy. They would have to be secondary to actual batteries and just take in the overflow. Because, we aren't talking energy creation here, we are talking energy storage. In any case putting hydrogen into the car isn't really going to work out on a large scale. And if you're going to burn off that much energy in the process there's probably better ways to have such inefficient batteries.

      And unlike hydrogen powered cars, my suggested design could start rolling off the lines next year.

      --

      It is no longer uncommon to be uncommon.
    4. Re:Yes, but how efficient overall? by markov_chain · · Score: 3, Informative

      Both of these suffer from the same problem. They loop through the same type of fuel (electricity). This is never going to work. It's too inefficient when we are talking about large scale deployment.

      In theory though, they could still be more efficient than the internal combustion engines. See the following article on modern diesel engines, and note the projected fuel cell efficiencies which include fuel production.

      Having said that, the modern diesels look like a serious contender to FCs, since they are already available, are competitive in efficiency, and yield well to hybridization. Once cleaner diesel fuel starts rolling in look out!

      --
      Tsunami -- You can't bring a good wave down!
    5. Re:Yes, but how efficient overall? by eheldreth · · Score: 2, Informative

      It's actually quite easy to make "Bio Diesel". Basically you add methanol to used cooking oil and use lie to reduce the acidity. Used cooking oil can be obtained free from a lot of restaurants (some may even pay you) or for a nominal fee from others. Bio Diesel runs much cleaner than Petrol Diesel, and can acutely increase your engines horsepower while cleaning out the sludge left behind from years of petrol. The biggest down side is if your diesel is more than say 3-5 years old you may need to replace some of the rubber fittings in the fuel system to keep them from degrading.

      --
      The perversity of the Universe tends towards a maximum. - O'Toole's Corollary
  4. Uhhh Summary by Ex+Machina · · Score: 4, Informative
    More than 9 percent of a kilogram of the powder gets converted to hydrogen and little energy is lost through heat.

    Not to be overly pedantic but even though this may correspond to the yield, the hydrogen is originally part of the water, not the sodium.

  5. Wow. by Daxster · · Score: 3, Interesting

    This is a very signifigant step up to using hydrogen as a fuel source, although we're still a ways away from using fuel cells as TFA states.

    Hydrogen is expensive to make and difficult to store.
    You might want to check out http://unitednuclear.com/h2.htm, which is their R & D page. They have been working on hydrogen powered vehicles in a much more sensible method for the short-term: just convert gasoline engines to run on hydrogen. They use a solar-powered electrolysis station (though they do say their current models are too slow) to get hydrogen from water. It's then transfered into metal-hydride tanks in your vehicle, which is a brilliant way to store it. Heating elements inside the tank release the hydrogen, and very little modification needs to be done to the engine. If the tank is cut and burned, the hydrogen is still released slowly enough to just smolder.
    This is a neat method, since most people think of hydrogen powered cars as electric vehicles that run off of fuel cells.
    Sadly, it isn't available for diesel vehicles due to the lack of a spark plug.

    --
    Death by snoo-snoo!
    1. Re:Wow. by ErikTheRed · · Score: 5, Interesting
      You might want to check out http://unitednuclear.com/h2.htm, which is their R & D page
      You might want to check out BMW, who has built some 7-series dual-fuel (hydrogen / gasoline) cars on a production line, albeit in very small quantities (I believe a dozen or two). They have two tanks, and can switch between hydrogen and gasoline seamlessly while the car is running / being driven.

      They are also using solar power to create the hydrogen - they have an experimental plant in the Mojave desert, here in California.

      The cool thing is that this is a functional, buildable product created by a major car manufacturer. As soon as the hydrogent fuel supply infrastructure exists, they could start cranking these out more or less immediately. If a driver gets stuck in an area where no H2 fueling stations exist, it runs just fine on old-fashioned gasoline. For more information, see their website.
      --

      Help save the critically endangered Blue Iguana
    2. Re:Wow. by TerranFury · · Score: 2

      The instant you burn something to run a heat engine you lose about half of its exergy (that is, the energy potentially available to do work). The best thing that hydrogen power has going for it is NOT that hydrogen is great (it isn't. As fuels go, it's inconvenient in a lot of ways), but that you can use it with fuel cells which are not limited by the Carnot efficiency (they're basically batteries). Using H2 in a heat engine is taking the worst of both worlds.

  6. "make" hydrogen? by Call+Me+Black+Cloud · · Score: 4, Insightful


    Liberate it, perhaps. I think any method of actually making it would come with its own set of problems.

  7. Fossil Fuels... by samtihen · · Score: 3, Informative

    Being able to produce hydrogen in a way that does not use fossil fuels "at all" is a huge step in the right direction.

    Another process in development involves bacteria that have a hydrogen waste product, if my memory serves me correctly.

    Of course, solar, wind, and geothermal are also reasonable ideas.

    The first person/company that is able to produce hydrogen cheaply using renewable resources will be an unbelievably good investment. (Assuming patents are taken care of properly)

    1. Re:Fossil Fuels... by amliebsch · · Score: 2
      How about putting a big-ass nuke plant out in the middle of the ocean?

      We call those "aircraft carriers." But seriously, the real problem is, how do you effeciently ship the gas from such a remote location?

      --
      If you don't know where you are going, you will wind up somewhere else.
    2. Re:Fossil Fuels... by NarrMaster · · Score: 5, Funny

      Well, you combine it with oxygen to form water, and then ship it through a pipeline.... oh, nevermind...

      --
      That's right. All your base.
    3. Re:Fossil Fuels... by D'Sphitz · · Score: 2, Interesting
      or wind farms destroying the skylines and slaughtering migratory birds?

      Destroying skylines? I've seen maybe 2 windmills in my life, much less a wind farm. Smog and pollution does much more to destroy any views I may have than a windfarm would.

      And I can't believe birds getting chopped up in windmills is a big problem. If i'm wrong, please link me, but for one there aren't many wind farms, and for two birds tend to travel much higher than the blades of any windmill.

    4. Re:Fossil Fuels... by Anonymous Coward · · Score: 5, Interesting

      Coming from a country where a sizeable percentage of energy is generated by wind mills..

      - We don't put them right next to places where migrating birds are known to stop. There are no problems with dead birds - they avoid the mills, but it wouldn't do to upset them.
      - LF and interference; They are noisy yes, but the LF/interference thing is tinfoil-hat stuff.
      - They are ugly; yup. So are smokestacks.

      Anyway. Trials are underway to stuff carbon back into the drilling holes instead of releasing it into the air. That shuld keep oil and natural gas CO2 emmission close to zero for power plants.

    5. Re:Fossil Fuels... by the+grace+of+R'hllor · · Score: 2, Interesting
      But seriously, the real problem is, how do you effeciently ship the gas from such a remote location?
      Zeppelins. Makes sense.
    6. Re:Fossil Fuels... by AndrewHowe · · Score: 2, Insightful

      I travel sometimes between Vienna and Gyor (Hungary), and the train passes through a great big wind farm. I think they look pretty sweet.

    7. Re:Fossil Fuels... by RockModeNick · · Score: 2, Insightful

      My main problem with wind power is inconsistencies in wind generally necessitate extensive, ugly, expensive backup systems for keeping dips in power service from doing harm and the fact that the ecconomy of wind and solar power is an ecconomy where land area and production are equivilent, and a land dependent ecconomy leads to feudalism, not a direction we can so much go from here.

  8. Combine with by wakejagr · · Score: 2, Interesting

    this and things are starting to pick up for fuel cell cars to the public.

    --
    Don't save Windows XP! http://www.petitiononline.com/jjw1xp/petition.html
  9. What do you do with the by Anonymous Coward · · Score: 5, Insightful

    mush of reacted silica gel, sodium, and water??

    Say you need one kilo of hydrogen... (Which is about 6 cubic inches in liquifidy form, which is roughly equal to 7.5 gallons of gasolene for the energy you get out of it.. and I go thru around 15 gallons of gass in a week due to my job) ..you'd have about 10-11 kilos of mush left afterwards.

    What do you do to recycle or reuse this stuff? How much energy do you have to put into (transporting it, creating/obtaining it, mixing it, etc) it before you can get any out, and how much energy is needed to deal with the waste afterwards?

    Because at my current usage a person would have to produce 88 kilos of left overs... per month. Just for me to keep my job with a hydrogen powered car instead of a gasolene powered one I already own.

    seems very innefficient for such a efficient proccess.

    1. Re:What do you do with the by watzinaneihm · · Score: 2, Informative

      You would not get mush of sodium, water and silicon. What you most probably have is a mixture of sodium silicates and sodium hydroxide. pass chlorine through this and then you probably can dump it in the sea without too many problems (NaCl+ silicon =sand (or waterglass) +salt?). Unless you want to sell the sodium hyroxide, it is a quite useful chemical.

      --
      .ACMD setaloiv siht gnidaeR
  10. Is it a chemical reaction or a catalyst? by stuartkahler · · Score: 2, Insightful

    So is their sodium-silica gel a catalyst that reduces the energy barrier to split oxygen from hydrogen through electrolyzing, or is it sucking up the oxygen atoms and releasing hydrogen as a byproduct of the reaction?

    Basically what I want to know is, do you just keep feeding more water and electricity into the system, or are you going to be continuously replacing the used up sodium-silica gel?

  11. Re:They're not making Hydrogen by cperciva · · Score: 2, Funny

    They're not making hydrogen.

    Yes they are... they're taking a bunch of protons and putting them together with a bunch of electrons.

    They're just gathering the stuff that was formed at the start of the universe

    There wasn't any hydrogen in the early universe; it didn't form until about half a million years later, once the temperature of the universe had dropped to around 3000K.

  12. Re:great... by drgonzo59 · · Score: 2
    Before it does there is a mandotory alarm saying "oh the humanity". When you hear that comming from a car in the parking lot run the other way.

    Seriously though, using water directly might not yield as much H but it is a much simpler process. If a nuclear plant is built then the electricity and distilled water is all you need to get some hydrogen. With this company's process you have to get the sodium from somewhere, then the silica gel. Anyone know of any pure sodium lingering around ready to be picked up, what about silica gel. All those chemicals need to be prepared, the energy to do so might as well be used to electrolize waterp. I personally would like to see more nuclear power plants being built in this country. Then we can use the electricity anyway we want.

  13. Ahem. by copponex · · Score: 2, Funny

    "...if you're a dumb creationist."

    You've repeated yourself.

  14. Misleading post and bad article by orzetto · · Score: 5, Interesting

    The idea is not producing hydrogen with sodium as an energy source. There is no pure sodium whatsoever around, it's too reactive (same reason there is no hydrogen in the atmosphere).

    So, instead of buying methanol cartridges, we would buy sodium sticks, put some water in a small tank in our laptop, and this would produce hydrogen and power for the machine.

    Furthermore, the most common way of producing hydrogen is not electrolysis, but reforming of hydrocarbons (oil and natural gas), which is done on an industrial scale in any refinery.

    The article itself has a good number of inaccuracies. For instance, other than the electrolysis thing, you read:

    9 percent of a kilogram of the powder gets converted to hydrogen

    This is insane. The powder does not get converted to hydrogen, the water does. And still I'm afraid a unit error may be lurking.

    The PEM fuel cells are not a way to store hydrogen, but a way to convert it to electricity; the solid oxide fuel cells will never be used in vehicles, since they are expensive, running at temperatures up to 1000 degrees, good only for large-scale plants, and brittle. And they take 8 hours to start up, and they can start up only so many times before they start cracking (about ten).

    Did you know that hydrogen is a greenhouse gas?

    Oh my, did they know that hydrogen is extremely reactive, and will burn with oxygen at the first occasion? You don't even need a spark, all it takes is the static electricity of a windy day. CO2 accumulates, hydrogen would disappear rapidly.

    Methanol is flammable

    Of course it is. It contains energy. There is no such thing as an energy carrier that does not contain some sort of danger. It would not be much of an energy carrier if it were inert. So, gasoline burns, hydrogen burns, nuclear goes bad big time, methanol burns, and lithium batteries explode if you hammer them or if they are produced with poor standards.

    oxide fuel cells require a catalyst

    Solid oxide fuel cells do not require a catalyst. They are the only ones that do not, since they operate at high temperatures. Assuming the article meant SOFC.

    Hydrogen fuel cells produced with the company's powers could also run a car, although not particularly economically in the foreseeable future.

    Common misconception, hydrogen costs about 0.8 euro per gasoline liter equivalent: in Europe that's already way convenient. It's the infrastructure that's missing.

    "That side of the periodic table people tend to ignore," he said.

    Alkaline metals being ignored? Of all the bullshit... they might not be C, O or even Al, but most know sodium better than technetium, praseodimiun or some transition metal forgotten somewhere in the limbo of rare earths.

    --
    Victims of 9/11: <3000. Traffic in the US: >30,000/y
    1. Re:Misleading post and bad article by Snags · · Score: 2, Informative

      Furthermore, the most common way of producing hydrogen is not electrolysis, but reforming of hydrocarbons (oil and natural gas) Ding ding, we have a winner. That's exactly what I was going to say. At this point, whenever we "make" hydrogen, we release a large amount of CO2 into the air because we're getting the hydrogen from CH4 (natural gas = methane).

      --
      main(O){10<putchar((O--,102-((O&4)*16| (31&60>>5*(O&3)))))&&main(2+ O);}
      LN2 is cool!
  15. Mind bogglingly stupid by panurge · · Score: 4, Interesting
    The article suggests using the stuff as an emergency fuel supply for cars that run out of gas.

    Obviously the emergency jerrycan is a technology too complex and difficult to arrange compared to a simple sodium store, water tank, reformer, purifier and additional carburetor...face it guys, most of the easily led idiot investors lost their cash in the dot-com bubble.

    BTW there is an existing technology for producing "safe" sodium involving mixing it with mercury to form amalgam. This has been around for many years (it is the basis of early plants for producing sodium hydroxide from salt.) It has not revolutionised fuel cells or led to a practical mobile phone fuel cell. So explain why this should be any different?

    --
    Panurge has posted for the last time. Thanks for the positive moderations.
    1. Re:Mind bogglingly stupid by Idarubicin · · Score: 2, Funny
      BTW there is an existing technology for producing "safe" sodium involving mixing it with mercury to form amalgam. This has been around for many years (it is the basis of early plants for producing sodium hydroxide from salt.) It has not revolutionised fuel cells or led to a practical mobile phone fuel cell. So explain why this should be any different?

      This must be some novel use of the word "safe" I'm not familiar with....

      Scientist 1: So we'd like to use sodium as part of our fuel, but it's dangerously reactive.
      Scientist 2: I know! Let's add a neurotoxic metal to it in large quantities. I'm sure the EPA won't mind.
      Maybe it didn't catch on because mercury is expensive to store, manipulate, and dispose of? How is your local public works department going to feel about mercury-sodium amalgam entering the waste stream?
      --
      ~Idarubicin
  16. Finally by hobotron · · Score: 5, Funny


    A use for all those "WARNING DO NOT EAT ME" packets.

    --
    There is truth in humor.
    1. Re:Finally by Anonymous Coward · · Score: 2, Funny

      ...other than giving them away at Halloween.

  17. What this is really all about by child_of_mercy · · Score: 2, Informative

    Bear in mind that this stuff will take energy to produce and there will be waste to dispose of.

    Also bear in mind that electrolysed hydrogen also takes more energy to produce than it will release (until we get perpetual motion sorted out).

    So all of this stuff is about finding more efficient ways to generate energy and store it.

    In this case the innovation seems to be that this product will make it easy (in water rich environments) to create hydrogen which (it is anticipated) will be easy to make electricity from.

    I've made hydrogen by mixing good old caustic soda (sodium hydroxide) with aluminium cans and water.

    Year 8 science, same result as this "innovation" although we only got enough hydrogen out of the bottle to inflate a baloon which was able to take off with a 3 metre piece of string drenched in methanol.

    lit the bottom as it went by and the whole thing made a very satisfying fireball.

    --
    'There is a Light that never goes out.'
  18. Re:Converted to hydrogen? by openpoop · · Score: 5, Funny

    if i only had some mod points... you have, good sir, embiggened us all with your cromulent analysis.

  19. What about the chlorine? by Timbotronic · · Score: 3, Funny

    IIRC pure sodium is generally extracted from molten salt by electrolysis. So that means not only do you have to expend a huge amount of energy to get your sodium, you're also producing toxic, ozone destroying chlorine gas as a byproduct. Oh well, at least they can say it's GREEN!

    --

    One of these days I'm moving to Theory - everything works there

    1. Re:What about the chlorine? by pclminion · · Score: 2, Informative
      you're also producing toxic, ozone destroying chlorine gas as a byproduct.

      The chlorine produced would be no threat to the ozone layer. Chlorine is too reactive to survive in elemental form all the way up to the ozone layer. The entire reason why CFCs were so destructive is because they were so stable they were able to survive all the way to the upper reaches of the atmosphere, where they were finally broken down by UV and released the chlorine they carried. (This process is actually still continuing, even though CFCs have been banned for many years. That's how stable these compounds are.)

      Elemental chlorine is not exactly a fun-time gas but it's not going to harm the ozone layer.

  20. Flammable by Bastian · · Score: 4, Insightful

    FTA: Methanol is flammable

    And hydrogen isn't?

  21. WHY?! by ValiantSoul · · Score: 2, Interesting

    Hydrogen is the most abundant resource in the UNIVERSE! Why the hell would we need to make it? We should stop worring about making more of what covers almost all of the universe and worry about stuff that matters - like fuel, greenhouse gasses, bandwidth wars, online duals, and reading slashdot?

  22. Re:WHY?! by phatslug · · Score: 2, Informative

    Because much of it happens to be in places from which it is rather difficult to obtain it, such as in stars. Even here on earth the hydrogen happens to be bonded with oxygen, therefore we must seperate them first.

  23. Why MAKE Hydrogen? by Anonymous Coward · · Score: 5, Funny

    Why do we need to make hydrogen? There's TONS of it sitting right out in the open, ripe for the taking!

    My fellow slashdotters, what we need only to do is MINE THE SUN!

    All we need is a space shuttle, and a team of roughneck oil workers. With a bit of training they will be SPACE MINERS, and we can send them on their merry way into the sun to mine it for us!

    1. Re:Why MAKE Hydrogen? by Scarblac · · Score: 5, Funny

      (obligatory)

      And for all those naysayers who claim it can't be done because the sun is too hot - we'd only mine the sun AT NIGHT!

      --
      I believe posters are recognized by their sig. So I made one.
  24. United Nuclear by EvilMidnightBomber · · Score: 4, Interesting

    Take all claims by United Nuclear (aka United Nyuck Nyuck Nyucklear) with a grain of salt. It is run by the infamous Bob Lazar Whose claims to fame include reverse-engineering alien spacecraft and working with their power source "element 115"(which doesn't exist in this part of the galazy) and advanced degrees in physics from MIT and CalTech which no paperwork can be found on. His old site has got some "interesting" info on the alien craft.

  25. Interesting, but impractical by Anonymous Coward · · Score: 2, Informative
    As requested: 2M(s) + 2H2O(l) -> 2M+(aq) + 2OH-(aq) + H2

    (as a note, as you progress down the alkali metal group, the reaction with water becomes more violent. Lithium and sodium fizz, potassium will ignite on the surface of the water, and you do not want to be around rubidium or cesium [Caesium if your British] if they go into water unless you want to be covered in molten metal.)

    As a further note, the reason that there is no hydrogen in the atmosphere is that it is so light it escapes from the atmosphere.

    As a final note, silica gel as a support is making leaps and bounds. Binding a reactant to silica gel allow reaction purification by simple filtration, which is always a good thing. I suspect that if their claims pan out, the reason that its less violent is that the Na/SiO2/SiOH is a less powerful reducing agent than pure Na metal [though SiOH's probably react with the sodium forming NaOSi]. But as someone pointed out, pure sodium metal does not exist on the earth. Sodium exists as salts, which have to be electrolyzed to make pure sodium metal (at about 850C to boot).

  26. Re:New type of electrolysis by Anonymous Coward · · Score: 2, Informative

    Old school con, and very dangerous. By alternating the current, you will be generating oxygen and hydrogen at both ends, and it will recombine to release the energy you've put in through electricity immediately.

  27. Re:Shipping hydrogen by child_of_mercy · · Score: 3, Interesting

    not so good fo return trade if you're ripping them open for that.

    Liquefied Natural Gas is shipped in specialised tankers with a row of enourmous domes.

    they look pretty cool.

    here's one I prepared earlier.

    (ok, i just googled it then)

    --
    'There is a Light that never goes out.'
  28. Hydrogen is usually made from fossil fuels by erl · · Score: 5, Informative

    The story states:

    "The most common way in making hydrogen is electrolyzing pure water."

    From what I understand, this is wrong. I've heard that most hydrogen is ironically produced as a byproduct of refining oil.

    Wikipedia for instance http://en.wikipedia.org/wiki/Hydrogen says that:

    "Commercial bulk hydrogen is usually produced by the steam reforming of natural gas."

  29. Re:great... by J.+Random+Luser · · Score: 2

    Seriously, I wondered about this. Because TFA says deprecatingly of methanol fuels cells that "methanol is flammable". And I thought, uhuh, these guys have invented non-flammable hydrogen, WTF good is that in an automotive engine?

    OK cheap jokes out of the way, the process may be intended to combine hydrogen generation and re-absorption within one "closed cycle" container. Seems to me they might have a better chance of a prize to get the electrons directly off the sodium and eliminate hydrogen from the whole process...

  30. You've got to be frickin kidding me! by barfy · · Score: 3, Insightful

    You want to make 10 times the volume of stuff for hydrogen you need, and you end up with 9 times the volume of stuff as *waste*?!

    You've got to be fricken' kidding me.

    Ok here is a major hint to the world leaders of this planet...

    Nuclear power plant, Gulf of Mexico == Hydrogen. Ship it to all the countries that don't want or have nuclear. Become new major energy provider...

    This is not rocket science people! Stop making it harder than it is!

  31. Re:great... by StuckInSyrup · · Score: 2, Informative

    Well, according to BMW, hydrogen fueled cars are actualy safer than common gas fueled ones.
    http://www.bellona.no/en/energy/hydrogen/report_6- 2002/22966.html

    --
    Ni.
  32. Waste - NOT by quarkscat · · Score: 2, Interesting

    All of the current technologies employed for the
    "hydrogen economy" either (1) require more energy
    to produce than can be stored, (2) are derived
    from the "hydrocarbon economy" it's supposed to
    replace, or (3) rely upon nuclear energy which
    has a 50,000 year environmental pollution problem.
    The "hydrogen economy" provides continued
    centralized control over energy distribution, but
    is not a viable long term solution.

    The best long term solution is reliance upon only
    renewable energy sources, including initially bio-
    diesel/hybrid. The main obstacle to this goal
    has to do with political will overcoming vested
    corporate interests that continue to seek total
    centralized control over energy distribution.

    Reliance upon the "hydrocarbon economy" for the
    source of the "hydrogen economy" does not make
    economic or environmental sense. Hydrocarbons
    are a limited resource. Excess carbon must be
    "sunk" in order to derive any real benefit from
    hydrogen, since COn are greenhouse gases.

    IMHO, every politician involved in promoting
    nuclear energy as "the solution" should be
    willing to commit themselves, their children,
    their grandchildren, their great-grandchildren,
    (et.al) to perpetual servitude to the new "quasi-
    religious order" that oversees the continued
    safe storage of radioactive nuclear waste -- for
    the next 50 to 60 thousand years.

    Reliance upon renewable energy, with increasingly
    modest demands upon hydrocarbons like biodiesel,
    is the only solution (barring the improbable
    development of controllable fusion reactors).

  33. How much energy is neccessary to make this powder? by Frit+Mock · · Score: 2


    To evaluate overall efficency of this way to create hydrogen we would have to know, how much energy it takes to make the powder.

  34. The key is sodium... by TapeCutter · · Score: 4, Interesting

    Great post, I was skeptical to start with, so I stopped reading TFA shortly after "The key is sodium" statement. IIRC (and I bow to your chemistry knowlage), isn't sodium created in commercial quantities by melting salt? Doesn't the molten salt also create equal quantities of chlorine gas? Is this anymore envriomentally friendly than mixing "Draino" with aluminum and water to produce hydrogen?

    PS: You're right, I've never heard of technetium or praseodimiun. When I saw the quote "That side of the periodic table people tend to ignore", I got a mental picture of a bunch of whitecoats (ala "The Farside" cartoons). They were hudled over a poster size periodic table that was spread out on a lab bench. None of them could complete the formula scrawled on the whiteboard because Eric was leaning on the Alkaline metals and nobody noticed them.

    --
    And did you exchange a walk on part in the war for a lead role in a cage? - Pink Floyd.
  35. 'Most Common Way'? by pfdietz · · Score: 3, Informative
    The most common way in making hydrogen is electrolyzing pure water.

    Sorry, but this is just wrong. Millions of tons of hydrogen are made every year around the world (for ammonia synthesis, for example), and very little of it comes from electrolysis. Thermal reforming of natural gas and other carbonaceous compounds is much more economical.

  36. Hydrogen is a red herring by Colin+Smith · · Score: 4, Insightful

    Any electricity which can be used to generate hydrogen can now be stored in batteries with a higher energy density than compressed hydrogen gas and yes, with negligible degradation. Go check out the state of the art in battery technology.

    e.g.
    http://www.toshiba.co.jp/about/press/2005_03/pr290 1.htm
    http://www.sionpower.com/

    You'll see them in mobile phones and laptops first. They'll make it into electric vehicles in a few years.

    Generating electricity to produce hydrogen to produce electricity is, well, stupid.

    --
    Deleted
    1. Re:Hydrogen is a red herring by crawling_chaos · · Score: 4, Insightful
      How many charge cycles before the nasty insides of those batteries end up inside a landfill? A hydrogen tank can get a lot more re-use and is probably simpler to recycle than a battery. Sion says that their batteries can be recharged "hundreds of times" which, in addition to smelling of marketing speak (look ma, no numbers!), is still a pretty fast degradation cycle.

      Lithium is considered a pollutant, as is sulfur. Perhaps you might wish to re-think the stupidity of fuel cells in that light?

      --
      You can only drink 30 or 40 glasses of beer a day, no matter how rich you are.
      -- Colonel Adolphus Busch
    2. Re:Hydrogen is a red herring by Colin+Smith · · Score: 2, Interesting

      "How many charge cycles before the nasty insides of those batteries end up inside a landfill"

      The insides are lithium based rather than heavy metal based for a start and if you had bothered to follow the link and read the article before bothering to reply you would have known before bothering to reply that there is a one percent degradation per one thousand full cycle discharges. Battery electric cars have been capable of 300+ miles per charge for several years now. We are talking hundreds of thousands of miles, more probably millions of miles of life out of the battery.

      "Lithium is considered a pollutant, as is sulfur"

      Hydrogen is highly explosive and oxygen makes things burn very quickly, the combination of the two must be horribly dangerous, I wouldn't like to have any dihydrogen monoxide anywhere near me, would you... Do you have any idea what you're talking about?

      --
      Deleted
    3. Re:Hydrogen is a red herring by zerus · · Score: 2, Interesting

      That and reclaimation of materials from the batteries has improved as well. So you could reprocess the material and remake batteries from old ones, some waste product is to be expected of course. Still, battery technology is a whole lot more efficient than hydrogen. Using straight electrical power instead of a combustible mass to heat, electricity, and motion means a much, much greater efficient. Tack on a few regenerative cycles to recharge that battery and we'd be set. I change my car battery every 5 or 6 years out of habit, not necessity, so I think battery packs might be a whole lot more reliable than a large tank of explosive material. Maybe it's just me, but I wouldn't want my car to explode like a Pinto from a fender bender on the freeway. As much as I'm for new energy methods, I'd still like to see the journal article on this method before I believe it's the next big thing. Somehow I'm doubting efficient conversion using a silica gel and sodium.

    4. Re:Hydrogen is a red herring by jridley · · Score: 2, Interesting

      Currently we're better at making batteries last a long time than we are at making either I.C. engines or fuel cells last a long time.

      According to my friends in the industry, one of the big problems with fuel cells is that they get easily poisoned and ruined by pollutants in the air that they suck in to consume the O2. Batteries actually last longer, and it is possible to properly recycle them, particularly if they're part of a large bank of batteries in a car. Junkyards have really become pretty darn efficient at recycling; it makes good business sense for them to be as efficient as possible.

    5. Re:Hydrogen is a red herring by zippthorne · · Score: 4, Funny

      Two words: hydrogen embrittlement.

      It turns out that one of the most useful ways to store and transport hydrogen is by chemically bonding it in long chain carbon molecules. The resulting liquid has a high energy density (per volume) and is relatively easy to store.

      --
      Can you be Even More Awesome?!
    6. Re:Hydrogen is a red herring by skelly33 · · Score: 2, Insightful

      "Any electricity which can be used to generate hydrogen can now be stored in batteries with a higher energy density than compressed hydrogen gas and yes, with negligible degradation."

      But the entire world does not and will not operate from rechargable batteries. Take a home in rural Anytown, U.S.A which has no connection to the power grid, in the middle of the woods so that solar and wind power are out and the only power they get is from a low-output hydro-power generator from a dammed up creek on the property. Rechargable batteries are not the best option for powering their water heater.

      The best solution is a comustible gas supply and gas-powered appliances. We have such a model in place today in the form of natural gas and propane services. Hydrogen is nearly a drop-in substitute for those systems, but has the versatility to be ran through a fuel cell to generate electricity as well. Rechargable batteries do not have the option to be used for a combustion-type heat source.

      I think this does not invalidate the usefulness of batteries, but that it does illustrate that rechargable batteries are not the end-all solution to stored energy and that there are cases where we have a need for a transportable, combustible fuel.

  37. Cut out the middle man by shiloh.sharps · · Score: 2, Insightful

    Correct me if I'm wrong, but aren't we just using hydrogen as a energy storage system here?
    That is, we take energy (in the form of electricity) from the sun or wind or where ever and use it to create hydrogen gas or compounds that will create hydrogen. All of which methods are less than 100% efficient
    Shouldn't we instead work on ways to store the electricity directly, using batteries or whatever?
    We already have a electrical distribution system that works fairly well, why not use it?

    --
    When you're hammered everything looks like it needs nailed....
    1. Re:Cut out the middle man by KillerBob · · Score: 3, Insightful

      The problem is that batteries, even Lithium-Ion batteries, are extremely heavy by comparison. A Lithium cell produces about 3V potential difference. In order to produce enough juice to run something like an electric car, you need a lot of them wired in series. And then, in order to have decent battery life, you end up needing even more of them wired in parallel. By the time you've got a viable option for running an electric car, you're talking 300-500kg depending on the size of the car. When cars themselves often weigh less than 1500kg, that's a significant increase in weight.

      There's also the cost. A Prius is a great alternative for a hybrid car, but what the manufacturer doesn't want to tell you when you're buying it is that the batteries only last about 6-8 years, and then they cost $10,000 to replace.

      Others have wondered the same thing you just asked. And then they've looked at the price tag, and the increased weight, and decided that they need an alternative that can be as cheap and easy to refill as gasoline. Personally, I think the solution lies not in fuel cells, but in implementing a renewable-energy way to generate hydrogen.

      Consider... I was at Canadian Tire yesterday. There, I saw a 400W wind generator for $700. 400W of juice is more than enough to run an electrolysis reaction. Set it up with a rain barrel and something in which to store the hydrogen, and you've got a renewable source of hydrogen for less than $1500 outlay. Sure, there are more efficient ways to store the energy being generated, but it's also freely renewable (no $10,000 expenditure every 8 years). All that's missing is a car that burns hydrogen.

      And for times of drought, or during the winter, all it needs is a source of water, such as city water or a well. (You *could* use some of the wind power to melt snow, but that, like a rain barrel, wouldn't be all that useful on a scale larger than one or two cars)

      --
      If you believe everything you read, you'd better not read. - Japanese proverb
  38. You obviously weren't alive in the 1970s by HBI · · Score: 2, Insightful

    Within the measure of current technology in 1973-4, let us say, all of those measures were tried back then. The motivator was the Arab oil embargoes intended to punish the West for supporting Israel. At the same time, lead catalysts were restricted for environmental reasons, resulting in all new cars from the 1976 model year on being unleaded-only.

    There was another gasoline shortage in 1979.

    The popularity of the US government response, which was to mandate changes to automobiles, compel odd/even license plate rationing, and make a lot of noise about alternative energy sources, can be partially seen in the 1980 election results.

    --
    HBI's Law: Frequency of calling others Nazis is directly correlated with the likelihood of the accuser being Communist.
    1. Re:You obviously weren't alive in the 1970s by madro · · Score: 2, Insightful

      Is it difficult to set up better public transportation in the US?

      Yes. US consumers have had cheap gas so long, the effects (sprawling metro areas, big box stores) make it much harder to construct a transit system that people will use. (They'll want other people to use it so that the roads become clearer for *them*.)

      Also, most other countries are smaller than the US. Amtrak has been a disaster in part because the notion of a nationwide passenger rail company does not fit well when much of the population is concentrated on near coasts thousands of miles apart.

      I think it's possible to set up better public transportation -- but it requires a lot of zoning changes, support for biking and walking paths, and some innovative pricing of road use (somehow make them more expensive) and transit use (make sure it's cheap or free). And don't even *think* about passenger rail -- a fixed infrastructure (track) in a flexible world isn't the best idea.

      As the price of oil rises, people will adapt. It's just unfortunate that because of the lack of foresight, many people will end up in trouble because the economy will suffer for a while, and a recession plus higher gas prices would hit the working poor the hardest.

    2. Re:You obviously weren't alive in the 1970s by Doc+Ruby · · Score: 2, Informative

      Those sprawling metro areas were made by better public transportation. LA is an example: I remember, after the Northridge quake in 1994, several LA car overpasses collapsed, paralyzing traffic and the city. Critics on Usenet (much higher signal:noise ratio then ;) told Angelenos that they'd be a lot less screwed if they had public transport, which could route around such holes in the network. Angry Angelenos fired back "if you lived here, you'd know how sprawled we are - we could never have streetcars service this farflung city". But then others responded with maps of the LA streetcar network, which ran up into the canyons and out across the flats, when literally no one lived there yet. Which let everyone live in all those places, building the city in its spread-out topology. Until a joint venture of GM, Goodyear and Standard Oil bought up all the tracks, pre-WWII, scrapped the system, and repaved with roads and cars. LA is still a great place for streetcars, topologically and weather-wise. They should put them back. When oil hits $100:gal, people will start talking about it seriously, though it will be too late to do it cheaply - and after LA has burned uncounted billions of gallons of cheap gas.

      Amtrak has a similar story, as the robber barons who built the phenomenal US rail system sold out to a government they stuck with a deliberately noncompetitive transport system. So they could safely invest in cars, trucks, airlines and the oil companies that are the blades to those vehicles razors. The US rail system was a blazing success when the country wasn't very dense anywhere but NYC and Chicago. The increased density along the coasts just makes those areas even more ripe for rail.

      As for passenger rail's "flexibility" demands, commuter arteries show that's not strictly necessary. In Brooklyn, literally millions of people a day drive across a town on local roads that has highways only around its perimeter. One road, Atlantic Avenue, cuts across town, running from the 3 bridges (& 1 tunnel) to lower Manhattan, to the nexus of 3 or 4 highways that run across the sprawling suburbs. Right past JFK, the major airport, and within a few miles of Jamaica, the existing commuter/subway hub (also connected to the airport with new rail). There is a 4-channel subway line along that road, and a 2-channel commuter rail line alongside it. All underground. The city should run a "car train" continuously shipping platforms from lower Manhattan to the airport parking lots, around that 6-channel rail line, which is mostly unused capacity most of the time. Literally millions of New Yorkers would have a guaranteed 15-minute commute every day, rather than burning gas into the air (and missing home/work) for anywhere from 45 minutes to 2 hours, in each direction, fighting traffic and collisions. There are other "trunk lines" which are mostly just routes for millions of people between two points.

      Then there is the long-overdue subway upgrade in the rest of the City. The signaling system dates from the late-1930s, and has become quite the boondoggle in recent years, preventing expansion, threatening years-long outages on major lines after inevitable breakdowns. If they integrated the 3 track systems, and replaced the signals/switches with a "packet switching" system, instead of the current "circuit swithes", we could have an Internet-style subway that trumps the old one like an old "Ernestine" operator-switched one. The flexibility to get a station-to-station trip, anywhere in the system, cutting commute times, congestion and energy consumption by orders of magnitude.

      These are expensive capital investments. The AirTrain line from JFK airport to the rail hub, and eventually LaGuardia airport, was at least $8B, probably $15B when it's "done". But that was Giuliani's scam to pay his mafia contractor buddies some of the numbers coming out of the Bubble during his reign, and included behemoth new stations and new rights-of-way thru crowded, expensive NYC land. When we're talking about million

      --

      --
      make install -not war

  39. Designing cities by sczimme · · Score: 4, Insightful


    make cities better designed for walking and cycling

    You know, in discussions like this someone will usually mention that cities should "be designed for X". This strikes me as a slightly silly argument:

    1) The most densely-populated cities (where X would likely provide the greatest benefit) have already been built. Retrofitting features to implement X would very likely be hideously expensive and impractical, e.g. where X == bike paths in a major city.

    2) Are new cities founded/designed/built at such a rate that changing the designs to accommodate X would provide any substantial benefit?

    --
    I want to drag this out as long as possible. Bring me my protractor.
    1. Re:Designing cities by king-manic · · Score: 2, Interesting

      1) The most densely-populated cities (where X would likely provide the greatest benefit) have already been built. Retrofitting features to implement X would very likely be hideously expensive and impractical, e.g. where X == bike paths in a major city.

      2) Are new cities founded/designed/built at such a rate that changing the designs to accommodate X would provide any substantial benefit?


      Zoning laws and long term urban planning can reduce the need for cars by making urban sparl less desirable for developers. Say put a constuction surcharge of X dollars on developement and have X grow as the distance from downtown increases, make incentives for residentual reclamation of parts of the downtown areas ect... All these things can reduce emission by making distant suburbs less desirable.

      --
      "There are more things in heaven and earth, Horatio, than are dreamt of in your philosophy."
    2. Re:Designing cities by sczimme · · Score: 3, Insightful


      Zoning laws and long term urban planning can reduce the need for cars by making urban sparl less desirable for developers... make incentives for residentual reclamation of parts of the downtown areas ect

      Fair enough - that's a good point. However, the problem (as I see it) is that essentially every extant city already has a significant amount of sprawl around it; this was the result of the urban flight that took place [IIRC] from the 1950s to 1970s. Some places - like the suburbs of Chicago, e.g. Naperville - are experiencing their own housing/development booms right now. Unfortunately I don't see an opportunity to redesign such areas for at least another 50 to 75 years, and that is if an entire neighborhood can be razed/rebuilt en masse.

      Perhaps /. should commandeer part of Nebraska or something and start from scratch. Flat land means easy walking. :-)

      --
      I want to drag this out as long as possible. Bring me my protractor.
    3. Re:Designing cities by birdman17 · · Score: 3, Interesting
      We're in for such a rude awakening when the oil runs out.

      We're in for such a rude awakening much earlier than that. Long before the oil runs out, the demand is going to exceed the supply. More specifically, the supply follows a rough bell curve shape, and we are pretty much at the peak now. This means that although demand is rising faster and faster (especially as India and China start to think that their billions of people all need cars), the supply is more or less immediately going to start to decrease. When this happens, the price is going to go ballistic. (And $60/barrel isn't ballistic, not by a long shot.) So long before we run out of the stuff, it is going to become totally uneconomical to use it for little things like driving to work.

  40. Convenient but globally inefficient by redelm · · Score: 2, Informative
    Sondium on silica nicely solves the nasty Hydrogen transport & storage problems. It presents a few of it's own -- quality control and hydration in transport.

    A tougher problem is upstream. Making sodium is gross and inefficient. It's done from brine (salt domes) the in old chlor-alkali process with mercury electrodes. This needs more [over]voltage 3.5V IIRC than hydrolysis. It is the voltage, and particularly the overvoltage needed to drive the process at industrial scales, that makes the process inefficient.

  41. Re:They're not making Hydrogen by CaptainFork · · Score: 2, Informative
    But a proton is a hydrogen ion, and elements pass through ionised states in reactions all the time. You haven't really made an element when all you've done is involved it in a reaction during which an electron gets stripped off or added for a short time.

    However, Hydrogen gas has chemical formula H2, and this is neither the same as, nor part of H20 or polycrystalline Na. So the claim to have created hydrogen gas is valid.

  42. Air Freshener by Clowning · · Score: 2, Interesting

    There was an article in the NY Times about the inventor of this. Apparently, it started out as his grandfather's idea for an air freshener. The original idea was to capture some kind of deodorizer in the silica gel which would be released when dissolved in the toilet. The grandfather envisioned naming the product "Plop and Drop"

  43. Re:Converted to hydrogen? by dug_silver · · Score: 4, Interesting

    This thread is so puerile.

    Seriously though, this whole thread is refreshingly optimistic. Let me be the pessimist: it isn't just inefficiency that will stop the advent of this new technology. The oil industry is keeping a lot of powerful people rich, who could give a flip about anything new or better. It also gives a seemingly great reason for the US to exert its global muscle.

    Now I want to respond seriously to the Anonymous Coward who frowns on the use of the word pedantic. Some of us have a vocabulary, something that's good for self expression. It does not make us pricks, we are not speaking with condescension (well you know, some of us). I really get riled when someone lashes out at another because they say "whom" or because they don't otherwise contribute to what is, in my opinion, the language being dumbed down.

    If the Family Guy can get a new word out to the masses, then I applaud it (moreso). Screw you, consciousness shrinker.

  44. Nobody is saying the energy cost fo this stuff by Overzeetop · · Score: 2, Insightful

    So, what is it? Is the process of mining, refining, fabricating, combining, dissociating, and transporting all off this stuff net-energy-positive, or are we just shifting the burden. The latter, of course, as this is just a storage mechanism.

    It seems like we're doing an awful lot of work, in terms of energy in, to get hydrogen in a form that can be stored, transported, and used. I'm sure batteries produce lots of crap too, but what are the relative effects, and does this particular process scale to global proportions? Seems like a pretty low yield (9%) with a lot of unsavory byproducts produced.

    (Of course, this doesn't even meniton my normal "hydrogen is a bad thisg to give to consumers" rant. Example: 2 rednecks, a trashcan liner, a full tank of hydrogen, and a lighter.)

    --
    Is it just my observation, or are there way too many stupid people in the world?
  45. Re:better by C0vardeAn0nim0 · · Score: 2, Informative

    ethanol (AKA alcohol) doesnt take more energy than it produces to make.

    1- crush sugar cane
    2- burn the pulp leftp to produce steam power to drive the crusher
    3- ferment sugar cane dip
    4- distil the result of fermenatation using whatever is left from the pulp to heat the distiler
    5- let the next sugar cane crop capture the carbon spilt in the atmosphere
    6- ...
    7- PROFIT!!!

    this business model is what drives a considerable part of brasilian cars. my next car will sure be flex fuel, so i can choose between more power (with alcohol) or more autonomy (gasoline).

    now, methanol i agree takes more power to produce than what it gives back when you burn it inside an engine

    --
    What ? Me, worry ?
  46. Re:better by cecille · · Score: 3, Interesting

    As another alternate fuel - what about biodiesel?

    I worked with a fuel company for a while, researching the possibility of introducing a bio-diesel blended fuel for trucks and heating. I'm fairly convinced that this will be one of those big milestones on the road to more environmentally friendly fuel. It's safer to handle, has a higher lubricity and cetane rating and reduces almost all the major emissions (except SO2). Not only that, but some of the newer manufacturing techniques really lower the impact of the manufacturing - using chemicals that can be reclaimed, room temp and pressure production etc. Plus, in low blends (~10%), you can stick it right into a diesel engine (at higher blends, usually the manufacturers get worried about warrently, and there may be some effect on certain types of rubber seals with really high blends). Not only that, but you can make it out of TONNES of stuff - we were working with soy based fuel, but we also had a bin of fuel from rendered animal fat. Not the greatest smelling stuff, and it wasn't as good as the soy, but they company we were working with was doing major reserach with a rendering plant - killing 2 birds with one stone - enviro-fuel and a way to recycle rendered fats. In fact, the most major problem to the introduction of these fuels is cost, and the gap between the bio (soy) diesel and the regular fuel is closing fairly rapidly. We managed to get to market for farm fuel with 2, 5 and 10% blends, and I think they're expanding those soon.

    As the parent points out, hydrogen isn't the only alternate fuel out there, and it's a fairly long way off from being a viable source. Using stuff like ethanol and biodiesel would be an excellent first step, and would be way easier than transitioning to hydrogen, since the infrastructure is already in place. The current fuel prices are making this more viable than ever before.

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    ...no two people are not on fire.
  47. Re:The problem with Hydrogen by Waffle+Iron · · Score: 2, Informative
    Water vapor, good old H2O is also a powerful greenhouse gas.

    Before you make statements like that, you should consider how much water vapor is generated naturally on this planet. If we assume that on average 500cm of rain falls annually all over the earth, then 500l/m^2 of water must have been evaporated, mostly by solar energy. At 2260kJ/kg, that comes out to 5.8e23 joules of solar energy that goes into evaporating water annually. Since the human race currently uses only about 5e20 joules of energy per year, converting to all hydrogen would only create an extra amount of water vapor equal to about 1/1000 of the natural production.

    Moreover, unlike CO2, water vapor easily condenses out of the atmosphere, and any problem goes away within a few days. It doesn't just keep building up.

  48. There are other alternatives... by TheUnknownCoder · · Score: 2, Interesting
    ... already in place in other countries, like Brazil's "flex-fuel" cars that run:
    • Gasoline
    • Ethanol (a.k.a. Alcohol)
    • A combiation of Gasoline and Ethanol, at any ratio
    • Natural Gas
    While Gasoline and Natural Gas are fossil fuels, ethanol comes mainly from corn (here in US) or sugar cane (Brazil). Renewable, clenaer sources of energy. Check out:
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    Uncopyrightable: The longest word you can write without repeating a letter.
  49. Full of Errors by Molecular+Mechanic · · Score: 5, Informative

    1) The most common source of hydrogen is hydrocarbon reforming, done at oil refineries. It's the only economically viable method for bulk quantities. Thus, hydrogen energy is currently dependent on fossil fuels.

    2) You cannot electrolyze pure water -it's a poor conductor. You need some salt, or other electrolyte. Even then, the amount of electrical energy that goes in is less than the energy value of the hydrogen that comes out. And guess where most of the electricity comes from . . .

    3) Sodium metal causes a fire when dropped into water because of the hydrogen it releases. The activation energy for the reaction between oxygen and hydrogen is very low, and the heat released from the sodium metal - being converted into sodium hydroxide (aka lye, or Drano)- is more than sufficient to cause the reaction (fire).

    4) Sodium metal is made by electrolyzing molten sodium chloride (table salt). A very expensive, energy consuming reaction, not to mention nasty (it releases chlorine gas, also).

    5) The amount of energy released when an electron is stripped from a sodium atom is the same, whether it's in water or in silica.The energy is either converted to heat or to some other form of energy. Ever hear of conservation of energy (or mass/energy for nuclear reactions)? Unless they've developed something that can do what the transporters and replicators on Star Trek do, the enrgy is still going somehwere. Entropy demands it, otherwise we'd have perpetual motion machines, and ebergy would not be an issue.

    6) Mediating the reactivity of alkalai metals is nothing new - that's what amalgams do.

    This story does not deserve the attention it has already received.

    MM

  50. Writers who know science??? by Atraxen · · Score: 2, Insightful

    More than 9 percent of a kilogram of the powder gets converted to hydrogen and little energy is lost through heat.
    I can't wait for the day when science writers actually know a tiny bit about their covered subject. Now, I'm no chemist (actually, holy cow, I AM!) but it seems to me that neither silicon nor sodium is hydrogen, so the powder is not being converted. It may be consumed by the reaction, but not converted. I teach this concept in general chemistry - it's called conservation of mass. I also see it taught in 7th grade public school classrooms. (Perhaps we should revisit the education reform posting of a few days ago...)

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    Be careful of your thoughts; they could become words at any minute...
  51. Stop trying to engineer human behavior. by RoverDaddy · · Score: 2, Insightful

    I'm sick of people trying to find ways to punish others for the way they want to live. At least in America, it's obvious that millions of people want to be spread out and don't want to live on top of each other in cities. The 'American Dream' of owning a home is still valid even as prices skyrocket so fewer young people can get there.

    I think the problem with suburbs is not that the population is so spread out, but actually that there are not -enough- downtown centers. As the formerly rural space between towns starts to fill up with McMansions, it's too bad that zoning boards don't allow (and perhaps encourage) new commercial centers to form at the town borders. Then, those comfy suburbanites would not have to fill up the overburdened roads leading to the 'old' town center just for a gallon of milk or a trip to the post office.

    Way way back when towns were founded, a distance of 5 to 10 miles from town to town probably made sense. Even into the late 20th century, the population on the outskirts of a town was fairly low, so there weren't that many people driving long distances to the town center. Now, the towns where I live are facing the prospect of 100% build-out of developable land (at least I hope people realize that's where we're headed). Since so many people just don't want to move to the commerce, I think the solution is to move the commerce out to them.

    By the way, I happen to be somebody who has never commuted into a city to work. I live in the suburbs and work in the suburbs. No it's not ideal for finding a public transit solution, but it means that I neither suffer from nor contribute to the congestion of the city. I don't understand why the people who scream about sprawl seem to assume that all jobs are in the cities, and that every last surburbanite is stuck in traffic at rush hour. There are alternatives.

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    RETURN without GOSUB in line 1050
  52. So much misinformation. by Anonymous Coward · · Score: 2, Interesting

    First my bias: I am a chemical engineer with a few years experience designing refineries and chemical plants. I am currently an equity analyst--it is partly my job to be up to date on trends that affect oil and natural gas consumption.

    Now some facts:
    - Hydrogen is not not not not made from electrolysis, because that would be stupid. It's made from reforming methane (passing high temperature steam and methane across catalyst) in an endothermic (ie, energy-consuming) reaction.
    - The vast majority of hydrogen produced in North America is consumed near the source at oil refineries, to "crack" the heavy oil fractions into gasoline. In other words, hydrogen is an intermediate chemical in the methane-to-gasoline value chain.
    - There is no commercially competitive process to produce hydrogen. The DOE is investigating nuclear-to-hydrogen, but that's about it for non-fossil hydrogen generation.
    - Electricity is either primarily fossil fuel (in North America) or nuclear (in Europe and Japan). Pick your poison, but don't pretend that electrolysis is clean.

    Now for some opinions:
    - The "hydrogen economy" is a stupid expression. As time has passed, society's energy needs have been met by progressively less carbon and progressively more hydrogen (wood to coal to oil to natural gas). This is a continuing evolution, not an end state.
    - The methane transportation infrastructure cannot be co-opted to transport hydrogen, because of metallurgical and chemical reasons... hydrogen has a fraction of the energy density per unit volume of methane. Metallurgically, hydrogen is extremely challenging and even today results in explosions and fires.
    -The lower energy density of hydrogen (compared with methane) means higher compression costs and lower transportation efficiency. This is non-trivial.

    There is too much wasted natural gas in the world to even contemplate manufacturing hydrogen by another process. Once oil and natural gas prices start moderating (and they will, it's just a matter of when), it will be even harder to compete.

    So you can stay hopeful about hydrogen fuel cells divorcing you from relying on dead dinosaurs, but you're living a fantasy. Your energy is better served in turning the lights out, slowing down, and STOP DRIVING SUVs!!

  53. Quitting Slashdot by Danathar · · Score: 2, Insightful

    Seriously....the lack of quality that Slashdot has degraded to is getting out of control.

    After this article...maybe I'll try just ignoring Slashdot or a week or so...read Ars Technica and Tomshardware.

    In the beginning Slashdot was pretty cool...Now it's not so cool