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Dry Ice Made into Super-tough Glass

janus zeal writes "A form of solid carbon dioxide that could be used to make ultra-hard glass or coatings for microelectronic devices has been discovered. The material, named amorphous carbonia, was created by scientists from the University of Florence in Italy. Writing in the journal Nature, the team says the material was theoretically possible but had never been created. It was made by squeezing dry ice, a form of carbon dioxide used to create smoke in stage shows, at huge pressure. Scientists are interested in the new material because of the potential applications. Also, they believe it could give them clues to the processes that happen in the center of huge gas giant planets such as Jupiter."

45 of 197 comments (clear)

  1. How do we know he didn't invent the stuff? by Anonymous Coward · · Score: 3, Funny

    I don't see this stuff replacing transparent aluminum anytime soon.

  2. Just needs Stability, by klik · · Score: 5, Insightful

    This is a hell of a thing if hey manage to find a way of making it stable at room teperature and pressure - a glass that has a similar strength to diamond made from a highly available source material? I can see a ridiculous number of uses for this!

    --
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    1. Re:Just needs Stability, by kfg · · Score: 5, Funny

      . . . if hey manage to find a way of making it stable at room teperature and pressure. . .

      Easy enough. Simply apply the Congressional Model of engineering; redefine room temperature and pressure.

      KFG

    2. Re:Just needs Stability, by RsG · · Score: 2, Interesting

      I wonder if this is similar to Aerogel?
      http://en.wikipedia.org/wiki/Aerogel

      From the description in TFA it seems similar, but I don't have the background in chemistry to make an educated guess. Anyone with credentials care to enlighten me?

      And if this stuff is just a new aerogel varient, what's the advantage to it? I was under the impression that we'd need to make aerogel in space if we wanted it in quantity, this new stuff seems to have been made on earth, but requires pressure and/or cold to stay stable.

      --
      Erotic is when you use a feather. Exotic is when you use the whole chicken.
    3. Re:Just needs Stability, by ceoyoyo · · Score: 5, Funny

      Um, diamond is made from a highly available source material. Under much the same conditions actually. It also has the minor advantage of not evaporating at room temperature and pressure.

    4. Re:Just needs Stability, by RsG · · Score: 4, Funny

      That, or we use the NASA model and swap the units of measurement. Kelvin you say? Well let's just assume they meant Celsius!

      --
      Erotic is when you use a feather. Exotic is when you use the whole chicken.
    5. Re:Just needs Stability, by ceoyoyo · · Score: 4, Informative

      No, it's like glass, except with carbon replacing the silicon.

    6. Re:Just needs Stability, by ottothecow · · Score: 3, Informative
      No, this is nothing like aerogel

      Aerogel is pretty fricking sweet though. (and for other reasons than the fact that it can float and carry things)
      its a great insulator and there are some (carbon?) aeogel's that are conductive of electricity...pretty cool stuff, quite expensive though

      --
      Bottles.
    7. Re:Just needs Stability, by McBainLives · · Score: 3, Interesting

      Hey- not every member of Congress is that dumb. Don't ask me to name 'em, of course...

      But I digress.

      I think you're on to something here- but instead of redefining the temperature and pressure, re-define the room. Maybe this stuff could be used for constructing deep-sea exploration vehicles and habitats. That'll shave off a few degrees / add a few atmospheres to the temperature and pressure targets.

      Remember:
      Up on the shore they work all day
      Out in the sun they slave away
      While we devotin'
      Full time to floatin'
      Under the sea...

      --
      I came, I saw, I left. It looked better in the brochure.
    8. Re:Just needs Stability, by Martin+Blank · · Score: 3, Funny

      It's also extremely brittle. I have a little bit that an aerogel manufacturing company sent to me after a polite request based on curiosity. It was just an irregular scrap piece from the machineroom floor, about an inch thick, two inches wide, and four inches long, and the gentleman was kind enough to mail it to me free of charge (I offered to pay for it). Within two minutes of taking it out of the plastic case, it had become two pieces, and in the years since has become about seven pieces.

      The MSDS enclosed with it said that it had no known toxic effects, so a friend ate a small piece, just a few millimeters on a side, before I could stop him. It didn't hurt him, but it left his mouth feeling weird. He is a bit of an eccentric, though.

      --
      You can never go home again... but I guess you can shop there.
    9. Re:Just needs Stability, by KozmoStevnNaut · · Score: 3, Informative

      but it left his mouth feeling weird

      You probably already know this, but that was probably an effect of aerogel being extremely absorbant. If it wasn't so expensive to manufacture, it would probably make an ideal replacement for kitty litter for cleaning up oil spills and the like.

      It can be treated to become extremely hydrophobic, though, allowing it to be cut with precision water jet cutters and such.

      --
      Eat the rich.
    10. Re:Just needs Stability, by svtdragon · · Score: 5, Funny

      At the right temperature and pressure, a ring made from dry ice leads to frostbite and ring made from diamonds leads to sex. That's another advantage.

    11. Re:Just needs Stability, by maxume · · Score: 3, Funny

      Isn't a diamond ring the beginning of the end of sex?

      --
      Nerd rage is the funniest rage.
    12. Re:Just needs Stability, by ceoyoyo · · Score: 2, Informative

      The way they describe making this stuff -- compressing and heating in a diamond anvil -- is the way they used to make diamond. Then they figured out how to make vapour deposition work well, which is what's scaring DeBeers now.

      So the way they're making this stuff is they way they used to make diamonds before they discovered the more practical CVD method. The summary (and the article's) suggestion that they're going to make skyscraper windows out of this stuff is... optimistic. Plus the problem that it sublimates as soon as you take it OUT of the diamond anvil.

    13. Re:Just needs Stability, by tgd · · Score: 2, Funny

      Fostbite can be cured. Eventually that sex is going to take half your stuff.

    14. Re:Just needs Stability, by StikyPad · · Score: 2, Funny

      Easy -- it already remained stable after being cooled to room temperature. Just increase room pressure to 5.7M PSI and you're all set. (Don't forget to swallow or yawn to equalize the pressure!)

  3. Re:Needs a bit more work first though.... by ronz0o · · Score: 3, Funny

    At room temperature, dry ice vaporizes. The only way for it to maintain its structure is under pressure. All we need to do is find some way to lower the global temperature and increase pressure...

  4. Well, Duh... by Baldrson · · Score: 5, Funny
    The next stage of the research is to work out how to make the glass stable at room temperature and pressure.

    Reminds me of the cartoon of the scientist at the blackboard with a series of equations on one side and concluding equation on the other with "And then a miracle happens." in between.

    1. Re:Well, Duh... by cp.tar · · Score: 2, Funny
      the cartoon of the scientist at the blackboard with a series of equations on one side and concluding equation on the other with "And then a miracle happens." in between.

      Do you have that cartoon?

      It would come in very handy next time I have enough free time to go argue with Creation Scientists.

      --
      Ignore this signature. By order.
    2. Re:Well, Duh... by kfg · · Score: 4, Funny

      "And then a miracle happens" . . .

      We mixed it with a bit of room temperature and pressure gaseous diamond. Unfortunately this only works so long as we keep it immersed in room temperature and pressure molten gold.

      If we can just work out how to. . .

      I find it interesting that one of the things this company is pushing is that it would be a solution to binding excess carbon dioxide in the atmosphere. I thought the solution to that was simple and obvious:

      Take your carbon dioxide and some plain water. Crack the water into hydrogen and oxygen. Crack the carbon dioxide into carbon and oxygen. You're left with a lot of . . .oxygen. Hurray! Let it go in the air and breath deep.

      Now you've got carbon and a hydrogen. Combine the two and you'll get a sort of brown-black goo which will be a bit of a disposal problem, since you'll eventually end up with billions of barrels of the stuff, but really, all you have to do is inject it under pressure into underground sand and shale deposits and it can sit there safe for millions of years.

      Problem solved.

      Of course you have to be careful. There's a certain risk that when the hydrogen and carbon combine you'll just end up with billions of barrels of vodka instead of brown-black goo and lord only knows how we'd manage to dispose of that.

      KFG

    3. Re:Well, Duh... by swillden · · Score: 2, Informative

      And I felt bad for the poor little kids - they'll never understand even basic level science if the adults in their life encourage them to use faulty logic and reasoning.

      Just to be sure: You did realize that whole web site is satire, right?

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  5. Most important use by chiller2 · · Score: 5, Funny


    Scratch-proof iPod screens of course! ;)

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    1. Re:Most important use by __aardcx5948 · · Score: 2, Funny

      Well, it might crack, it's glass afterall... :-p

    2. Re:Most important use by waferhead · · Score: 3, Informative

      Diamond-like-carbon (DLC) has been used to make scratch resistant plastic for years.

      It is either sputtered on or PECVD, applied under vacuum.

      It _is_ carbon glass.

      It exists already, just not made using the high pressure method the article blathers on about.

  6. Re:Needs a bit more work first though.... by RsG · · Score: 4, Funny

    Well, we could suck all the Co2 out of the atmosphere. This would remove the greenhouse effect, both the manmade one and the naturally occuring one, and drop the planetary temperature. And we get our Co2 for making this stuff in the bargin! It's a win-win situation (well, except for the living - they'll be royally screwed - but they were just taking up space anyways).

    --
    Erotic is when you use a feather. Exotic is when you use the whole chicken.
  7. Stable at room temp? by MustardMan · · Score: 5, Informative

    I'm not on campus (it's saturday, wee!), so I can't access the original Nature article, but I have a feeling the "stable at room temp" bit was misinterpreted by the BBC writers. I really don't see any practical way to keep the molecules together at room temp and atmospheric pressure - there's a reason CO2 is a gas. Silicon glass is a sort of weird case - most materials that show a glassy transition do it at a much lower temperature, or are largely temperature independent. When people try to run simulations to describe glassy behavior, they generally assume zero-temperature and quenched disorder.

    FWIW, I spent the last two years working on computational study of spin glasses, and am working on my PhD in soft condensed matter, of which glasses are a huge part.

    1. Re:Stable at room temp? by Sky+Cry · · Score: 2, Informative

      From TFA: "The next stage of the research is to work out how to make the glass stable at room temperature and pressure." BBC got it right - it's not stable at the room temperature yet.

    2. Re:Stable at room temp? by NoMaster · · Score: 2, Funny

      So what sort of pussy lab do you work in where you don't regularly immerse your undergrads in custard?

      --
      What part of "a well regulated militia" do you not understand?
  8. Not so much with the dry ice any more by jfengel · · Score: 4, Interesting

    For stage shows, fog machines are far more controllable and produce better results than dropping dry ice in water. They use "fog juice" rather than dry ice.

    Though sometimes you'll use dry ice to cool the resulting fog. The hot fog gives you a smoky, atmospheric effect. If you want ground-hugging fog, you've got to cool it down, and dry ice is a pretty good way to chill it quickly.

    1. Re:Not so much with the dry ice any more by Bo'Bob'O · · Score: 2, Interesting

      I suppose this is a bit off topic, but what the heck.

      I use both regularly at work, for as much an expert that does or doesn't make me. Refrigerated heavy fog machines are great, but both are still used. In my experience at least, when used properly dry ice has a much richer, heavier effect then the machines like Jem (which we have) or Le Maitre makes. Of course, from a practical standpoint the heavy foggers are much more convenient. But for a good, one shot effect, we still often go with a large dry ice machine.

    2. Re:Not so much with the dry ice any more by falconfighter · · Score: 3, Funny

      There's other reasons - such as the fact that fogging oil condenses on the optics for the lights - you don't know real joy until you've cleaned 200+ stagelights.

      --
      "Give a man a fire, he's warm for a day, set a man on fire, he's warm for life."
  9. Re:Um... a bit too intricate? by MustardMan · · Score: 5, Informative

    With my experience in scientific publications (especially physics!) there is usually a paragraph at the beginning of every paper trying to find some practical application. Probably 50% of these applications are pure horseshit thought up at the last minute. A lot of us do things for the sake of better understanding the world around us, and don't really know if there will be a practical application. And, if there DOES turn out to be an application, it's sometimes something we certainly didn't predict.

    I haven't read the Nature article yet, but I have a feeling the "understand a planet and coat lenses" bit was thrown in as fluff to justify the research. It's pretty much accepted practice, and I know I'm not the only one who barely glances at the first paragraph in most papers.

  10. Re:Needs a bit more work first though.... by Anonymous Coward · · Score: 2, Funny

    So are nipples. But you don't see those used in construction, do ya?

    (Well, actually you do. But on the workers, not the buildings. And let's face it, those aren't nipples most of us want to see.)

  11. Carbonia is lovely this time of year by ScentCone · · Score: 3, Funny

    Cheap flights into Elbonia often connect through the Amorphous, Carbonia international airport. Unfortunately the town's not very stable when it's warm out.

    --
    Don't disappoint your bird dog. Go to the range.
  12. Finally! A solution to global warming! by brian0918 · · Score: 3, Funny

    All we have to do is start sucking up all the carbon dioxide out of the air, and convert it into little waste cubes that can be dumped in landfills or baby seal breeding grounds. It's foolproof!

  13. I think this takes ... by AstronomicUID · · Score: 5, Funny


    the term Vaporware Windows to a whole new level!

    --
    You must write The Book, and then tear away belief. Only you can save the light of man --Gary Numan
  14. Re:Big question: Does it flow? by agrippa_cash · · Score: 4, Informative
  15. Re:Um... a bit too intricate? by 1u3hr · · Score: 2, Interesting
    But you would agree if it were known apriori there could be NO application to a research avenue, there isn't much use for the research.

    You can confidently say there is no application (this millenium at least) for at least half of physics research, most astronomical or maths research, not to mention the Arts, where people would be highly offended if you even asked them for a practical application.

  16. Re:Um... a bit too intricate? by fermion · · Score: 2, Interesting
    I know what you mean about the application section. It seems that sometimes researchers just look around the room and figure out an application for the first thing they see.

    In this case the lens thing may not be so crackpot. SiO2, quartz, is the lens and glass material used in certain situations. Single crystal is just in the more demanding cases, but amorphous is used where possible. The size of a single crystal quartz stone is limited due to growth constraints. Chemicaly CO2 and SiO2 might bind well enough to allow the amorphous glass to be used in more situations. Don't know, been a while since I worked with eitherbut it seems like on of the first things that might be tried as soon as they get the process working.

    --
    "She's a scientist and a lesbian. She's not going to let it slide." Orphan Black
  17. Re:Um... a bit too intricate? by susano_otter · · Score: 4, Insightful
    It isn't as if science is going to send us for heaven for paying it lip service.

    True, but it does consistently reward us for methodically searching for interesting things in unusual places.

    Think of it as a form of assay: You assay every square mile of territory, not because you like assaying, or you think there's something worth mining in every square mile of territory, but to find out which square miles have something worth mining.

    I'm not paying for science for the sake of science. I'm paying for a thorough assay of the territory.
    --

    Any sufficiently well-organized community is indistinguishable from Government.

  18. Re:Needs a bit more work first though.... by IWannaBeAnAC · · Score: 2, Insightful
    Well, just goes to show how useless the slashdot moderation system is.

    At least I read the article!

  19. Fog machine fog isn't toxic, but can be a problem. by CFD339 · · Score: 4, Interesting

    I am a firefighter. Actually, I'm a Lt. on an Engine company -- one of the volunteer firefighters who protect about 40% of the US population (most people don't realize how much of the US is protected by volunteer firefighters).

    We train using fog machines frequently, because if something goes wrong you can remove your SCBA and breath normally.

    In a training event for "Explorers" not too long ago, we used this fake smoke on a hot day. We had to cancel the use of it because several of the kids has asthma attacks. After investigating, the only explanation we could find, was that the appearance of smoke creates the expectation that it will be difficult to breathe. That expectation can be self fulfilling -- especially in young people who have had bad reactions to actual smoke in the past.

    Oh well.

    --
    The problem with quotes on the internet, is that nobody bothers to check their veracity. -- Abraham Lincoln
  20. Re:Needs a bit more work first though.... by WuphonsReach · · Score: 3, Insightful

    Well, just goes to show how useless the slashdot moderation system is.

    That, or not enough people are meta-modding.

    --
    Wolde you bothe eate your cake, and have your cake?
  21. Re:Big question: Does it flow? by camperdave · · Score: 2, Informative
    Either that, or it was standard operating procedure to put the thick edge of the crude glass panes at the bottom of the window. From the links in the ancestral post:

    It is sometimes said that glass in very old churches is thicker at the bottom than at the top because glass is a liquid, and so over several centuries it has flowed towards the bottom. This is not true. In Mediaeval times panes of glass were often made by the Crown glass process. A lump of molten glass was rolled, blown, expanded, flattened and finally spun into a disc before being cut into panes. The sheets were thicker towards the edge of the disc and were usually installed with the heavier side at the bottom.

    In the October 1999 issue of Discover, Yvonne Stokes, a mathematician at the University of Adelaide in Australia, says that it would take a mere ten million years for a windowpane to get 5 percent thicker at the bottom.
    --
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  22. Re:Stability - by Alamar3 · · Score: 3, Informative

    You're misunderstanding the use of the word 'stability'. All glasses are thermodynamically unstable. A glass is, essentially, a liquid that has been cooled really quickly past the melting point to a temperature at which the atoms do not have enough energy to re-arrange themselves into the thermodynamically preferred crystalline ordering. This leaves you with a thermodynamically unstable - but kinetically stable - solid that has an amorphous structure (one with no long-range atomic order).

    Since this glass is also kinetically unstable, it won't remain a solid at RTP. However, it probably won't explode: it will simply crystallise, melt and evaporate as you heat it up. I suppose if you did this fast enough it might explode, but I think at 'normal' heating rates it's likely to just crack along flaws in the material to relieve internal pressure.

    Of course, since you mentioned what would happen when it 'breaks'... this would require it to be at whatever conditions the glass is kinetically stable (from the article) - as I've explained above, the material won't exist as a solid at RTP and therefore cannot be broken. If it's kinetically stable, when it breaks it will just behave like a normal glass: it will fragment.

    (And, yes, I am a glass scientist!)