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Scientists Build Graphene From Scratch, Atom By Atom

MrSeb writes "You've heard of 'designer babies,' the idea that you can customize a baby by altering its DNA, but now a team of researchers from Stanford University and the Department of Energy have meddled around with the very fabric of reality and created the very first 'designer electrons.' The bulk of the universe is made up from just a few dozen elements, and each of these elements is made up of just a few subatomic particles: electrons, protons, neutrons, quarks, and so on. For the most part, the properties of every material — its flexibility, strength, conductivity — is governed by the bonds between its constituent atoms, which in turn dictate a molecule's arrangement of electrons. In short, if you can manually move electrons around, you can create different or entirely new materials. That's exactly what Stanford University has done: Using a scanning tunneling microscope, the team of researchers placed individual carbon monoxide molecules on a clean sheet of copper to create 'molecular graphene' — an entirely new substance that definitely isn't graphene, but with electrons that act a lot like graphene (abstract). It is now possible, then, for scientists to create entirely new materials or tweak existing materials — like silicon or copper, or another important element — to make them stronger or more conductive. Where will this particular avenue lead us?"

36 of 185 comments (clear)

  1. Alchemy? by Anonymous Coward · · Score: 5, Insightful

    Is this alchemy?

    1. Re:Alchemy? by CPNABEND · · Score: 2

      I think the bigger question is, "how would you move this process to a FAB"? I don't think it will happen soon, but it seems to me we would need robotic STMs? Research is continuing... I assume.

      --
      My wife doesn't listen to me either...
    2. Re:Alchemy? by NicknameAvailable · · Score: 2, Insightful

      I think the bigger question is, "how would you move this process to a FAB"? I don't think it will happen soon, but it seems to me we would need robotic STMs? Research is continuing... I assume.

      Nice generic smaller technology quip, but I think you missed the point of TFA and what the posters you were responding to (hint, they read and understood it). You should actually read it, its more about a change in the understanding of physics than new chips.

    3. Re:Alchemy? by Hartree · · Score: 4, Insightful

      No, it's not alchemy.

      It's just a slight riff on things we've been doing for a long time. Placing atoms or molecules in layers or patterns so that their associated electrons have certain characteristics.

      We've been doing patterning of atoms/molucules with STMs for decades now.

      It's interesting work, but the description seems awfully breathless.

      "Meddling with the very fabric of reality"?

      Gimme a break. *eye-roll*

    4. Re:Alchemy? by poity · · Score: 2

      the forces holding the nucleus together is many MANY times greater than the bonds holding molecules together (think difference between nuclear bomb vs acid/base reaction). IANAPhysicist, but I think the only place you can get anything close to alchemy would be in a nuclear reactor (nuclear decay would be a kind of undirected alchemy). This process seems to me like "chemistry one-atom-at-a-time." Imagine regular chemistry as making bread dough, you put flour and water together and get an uneven (at the molecular level) glob, with some parts a little drier, some wetter. With this process, you can actually build a perfectly uniform and homogeneous dough -- one water, one flour, one water, one flour, and on and on. With that in mind then, the first thing that comes to mind is super strong materials (uniform at molecular level = no weak points where tears/ruptures can develop)

      --
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    5. Re:Alchemy? by burningcpu · · Score: 3, Informative

      This comment on the main page does a better job of explaining what is going on than the article and summary.
      You are not doing a good job of explaining what is going on (mainly because it is hard to do in one article and is beyond the scope of what your editor wanted). Each different element has a differing ability to attract electrons, this is based upon the number of orbitals filled, or left vacant from their spot in the atomic table. In general elements react according to how many orbitals they have open. Carbon has 4 open spots in its orbital pattern. Hydrogen has 1. Thus when carbon and hydrogen react they can produce methane (CH4). Benzene rings are the basic structure behind graphene, they are particularly unusual because the shape of the orbitals are modified by the 3 dimensional shape of the ring of carbon atoms. This shape in turn, causes the P orbital to become displaced above and below the plane of the carbon ring. The voodoo or magic that happens here is what has everyone excited about graphene. This displaced orbital completely changes the properties of carbon. The only similar type of chemical properties that exist in our world are the properties of living organisms. Not surprisingly, living organisms are full of molecules that have benzine rings in them. What this article is saying is that we will be able to make new materials based upon carefully spacing the placement of atoms on a layer on top of the material that is shaped like the spacing in graphene. This mimics the deformation of the p orbital that carbon has. It is not exactly like it which is even more exciting because it will allow for even more specialized forms of material to be made. The electrons in the example were actually in a magnetic field made by the atoms of the material rather than from the surrounding area. This is an example of quantum mechanical effects effecting the broader material and is another exciting aspect of these experiments.

      Nano-tech like this will not directly allow the production of elements (gold, platinum ect.) It will make whole new combinations of materials that could not even be imagined by a scientist before this study. Reading between the lines here, what we are seeing is that contrary to current speculation in popular press, the limitations placed upon Moore's Law by the properties of atoms is not a bad thing. It will in all probability allow us to build materials and manipulate matter in ways that were blocked by our inability to control masses of specific atoms in specific ways. A bike built from the placement of individual atoms in specific places will be incredibly light, durable and cheaply made by machines alone. The boundary between living matter and dead will be much harder to see because materials used in ordinary items will have some of the same kinds of strength, regeneration, self replication, and beauty that we associate with living things."

    6. Re:Alchemy? by Ihmhi · · Score: 4, Funny

      "Meddling with the very fabric of reality"?

      Gimme a break. *eye-roll*

      Yeah, they're doing that over at CERN anyway. You haven't lived until you've shaken hands with your nega-universe self and then awkwardly made out with each other. His goatee was kinda itchy though.

    7. Re:Alchemy? by Anonymous Coward · · Score: 5, Funny

      "Whoah... I'm caught on this bit, how can you FOOL an electron? Insane, I love it."

      Anybody can fool an electron, they are dense!

    8. Re:Alchemy? by __aaltlg1547 · · Score: 2

      More like bullshit, or at best wild overstatement of what they did.

      The article epitomizes what's wrong with science reporting. You either have a scientist talking to a complete ignoramus who is totally unable to understand what it is that the scientist is describing, or you have the even worse situation of a scientist who knows the reporter is completely ignorant and dumbs down his explanation to a TV science-fiction level or makes completely false claims in order to grab headlines.

      "The behavior of electrons in materials is at the heart of essentially all of today's technologies," said Hari Manoharan, associate professor of physics at Stanford and a member of SLAC's Stanford Institute for Materials and Energy Science, who led the research. "We're now able to tune the fundamental properties of electrons so they behave in ways rarely seen in ordinary materials."

      Manoharan claims that they can tune the fundamental properties of electrons. And he apparently said he made electrons think.

      Well it turns out that if the author's article isn't misquoting Manoharan, he actually did claim that the electrons had no mass and were moving at the speed of light. That would be a huge scientific breakthrough if it were true.

      I guess they must have because as an associate professor of physics at Standford, this guy ought to be able to know what the fundamental properties of electrons are. And as any sort of professor at all, he ought to be able to accurately describe his research even to a non-science writer. And the non-science writer might have taken the trouble to point out that if there were massless particles moving at the speed of light, they wouldn't have been on the surface of the copper wafer very long while the scientists tinkered with their fundamental properties.

      But then he goes on to describe things that have fuck-all to do with changing he properties of electrons. What they did is made an arrangement of ATOMS that has an arrangement of electrons similar to that of graphene, and it behaves a lot like graphene, and they made some other interesting synthetic strutures. Good for them. This could be a step toward making a new class of exotic materials for special purposes. (But if you want, graphene properties, I'm sure it's cheaper to use real graphene.)

    9. Re:Alchemy? by semi-extrinsic · · Score: 5, Informative

      Well it turns out that if the author's article isn't misquoting Manoharan, he actually did claim that the electrons had no mass and were moving at the speed of light. That would be a huge scientific breakthrough if it were true.

      As a physicist, I would say that Manoharan was probably spot on, but the journalist failed to understand and relay him correctly. You're correct that "massless electrons moving at lightspeed" is a scientific breakthrough, that's why it was awarded the Nobel prize in 2010.

      To explain: in graphene, the dispersion relation becomes a bit funny. See explanation on Wikipedia. This means that electrons behave as if they were massless and moving at the speed of light. They are neither, of course, they just behave as if they are.

      Car analogy: if you drive your car on ice covered with water, it will behave as if it had no brakes. It still has brakes, it just behaves as if it didn't.

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  2. To infinity and beyond... by Kawahee · · Score: 4, Interesting

    Where will this particular avenue lead us?

    Space Elevators.

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    1. Re:To infinity and beyond... by mosb1000 · · Score: 3, Interesting

      Room temperature superconductors.

    2. Re:To infinity and beyond... by del_diablo · · Score: 2

      And a proper AfricanEuropeanAsian united powergrid, where Sahara and Coast nations produce all the power.

    3. Re:To infinity and beyond... by Snard · · Score: 2

      I didn't realize there was such a thing as an Asian swallow.

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      - Mike
    4. Re:To infinity and beyond... by semi-extrinsic · · Score: 3, Informative

      No. You read the article, then have a look at this and this.. Come back when you understand the concept of electron mobility versus DC resistance.

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    5. Re:To infinity and beyond... by del_diablo · · Score: 2

      It has a ladden velocity greater than the European swallow.

  3. Issues of scale by ancienthart · · Score: 4, Insightful

    It is now possible, then, for scientists to create entirely new materials or tweak existing materials — like silicon or copper, or another important element — to make them stronger or more conductive. Where will this particular avenue lead us?

    Nowhere, unless you only want blocks of it 1 or 2 nanometers across, and are prepared to take a few hours to manufacture it.
    In this case, a scanning tunnelling microscope is being used by having a single massive (on an atomic scale) probe manipulating single atoms at a time. Until we can control millions of atoms at this degree of resolution AND at the same time (smaller parallel probes, or some fancy trick with complex electrical fields on a single probe tip), this is scientifically interesting, but useless for the bulk manufacture the poster hints at.

    1. Re:Issues of scale by dbIII · · Score: 4, Insightful

      Are you merely another "wake me up when you can buy it all Walmart" cargo cult luddite or do you set your sights higher?
      Science is often a series of steps instead of great breakthoughs. For example the aluminium metal used around you today was not initially produced by the current method, but instead by an incredibly difficult and expensive method which later inspired other ways to produce it.
      Currently we don't know the best way to make graphene but doing it the difficult way that will actually work may inspire a better way to do it and may uncover materials we've never seriously thought of because there's no obvious simple way to do it.

    2. Re:Issues of scale by tysonedwards · · Score: 2

      This is "useless" with regards to bulk manufacturing procedures as proposed today...

      Step 1 is always to figure out whether something is even possible.
      What this shows us is that we do have the ability to "dial up" matter characteristics on-demand. Sure, it is highly impractical today, but that is in no way to say that significant research won't now be undertaken to take what now is a cool proof-of-concept and create a practical, workable model to exploit the findings of what we have discovered.

      Decades ago, it was also believed that photo lithography was highly impractical, however it now is the dominant method of designing integrated circuits.

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  4. Summary is loony even for Slashdot. by John+Hasler · · Score: 5, Insightful

    What the hell does this guy think he's talking about? The article is interesting but "designer babies"? "The fabric of reality"? Where do you people get this stuff?

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  5. Re:Designer baby doesn't mean what you think it me by John+Hasler · · Score: 4, Insightful

    "Designer baby" is just a buzzphrase. It serves no purpose other than to derogate people who might want to reduce the role of chance in the genetics of their children. It means whatever the speaker wants it to mean.

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    Warning: this article may contain humor, sarcasm, parody, and perhaps even irony. Read at your own risk.
  6. Its all about the protons by perpenso · · Score: 3, Funny

    Aww man! Now can Gold from Lead be far behind?

    Yes, very far. You have to manipulate protons, not electrons, to convert an atom from one element into another element. Sorry, humor has to respect science a little bit. :-)

  7. The bulk of the universe... Wrong! by FridayBob · · Score: 5, Informative

    ... The bulk of the universe is made up from just a few dozen elements, and each of these elements is made up of just a few subatomic particles: electrons, protons, neutrons, quarks, and so on. ...

    Wrong! The bulk of the universe -- about 70% -- is made of dark energy and we have no idea what that's made of. Then there's dark matter -- about 25% (no idea what that's made of either) -- while less than 5% is made of normal, barionic matter (electrons, protons, neutrons, quarks, and so on).

    1. Re:The bulk of the universe... Wrong! by Tablizer · · Score: 2

      If it's dark matter, it's anti-made-up-of. Or, "unmade of".

    2. Re:The bulk of the universe... Wrong! by Jeremi · · Score: 2

      Wrong! The bulk of the universe -- about 70% -- is made of dark energy and we have no idea what that's made of. Then there's dark matter -- about 25% (no idea what that's made of either)

      I think you'll find that Sturgeon's Law gives us a pretty good indication of what this 'mysterious 90% of the universe' is made of.

      --


      I don't care if it's 90,000 hectares. That lake was not my doing.
  8. FRIB by quetwo · · Score: 4, Interesting

    Too bad the government is canceling most of the funding that is going towards moving this type of research forward. The FRIB (Federal Rare Isotopes Beam) project, currently under construction in Michigan had most of its funding cut for the budget this coming year. Congress is claiming that the research is better done in France with the current accelerator (which will be half-way through its useful life when the FRIB is expected to go online).

    But hey, why spend money on furthering science and building your ability to be a "thinking" country (we've already given up the ability to be a "making" country), when you can give it to people who just gamble it on the markets and push money around?

    1. Re:FRIB by Beelzebud · · Score: 2

      I'm sure that money all had to be funneled to defense projects.

    2. Re:FRIB by roman_mir · · Score: 2

      You can't be a thinking country without being a making country.

      Once you don't make anything, why would anybody waste time thinking?

  9. They read and understood which citation? by perpenso · · Score: 5, Informative

    I think the bigger question is, "how would you move this process to a FAB"? I don't think it will happen soon, but it seems to me we would need robotic STMs? Research is continuing... I assume.

    Nice generic smaller technology quip, but I think you missed the point of TFA and what the posters you were responding to (hint, they read and understood it). You should actually read it, its more about a change in the understanding of physics than new chips.

    I don't think so. The cited and heavily quoted article seems to start with a fundamental misunderstanding of freshman level physics: "the bulk of the universe is made up from just a few dozen elements, and each of these elements is made up of just a few subatomic particles: electrons, protons, neutrons, quarks, and so on". Quarks are not subatomic particles, they are the elemental particles that subatomic particles are made from. In other words your proton is made of quarks. That makes phrases like "meddled around with the very fabric of reality" a bit suspicious. Reading the article confirms this suspicion.

    If you look at the second citation, the one from real scientists, they are using phrases like "new nanoscale materials with useful electronic properties". So if you only read the fist citation then yes we are on the verge of star fleet manual type science. However if you the second article we are closer to new fabrication technologies.

    1. Re:They read and understood which citation? by theshibboleth · · Score: 4, Informative

      Is it really "ignorance"? He's knowledge of physics/atoms/subatomic particles seems solid enough. What's really at issue is the semantics of "sub-atomic". And that's a perfectly fine thing to investigate, but it's a bit of a leap to go from "you didn't read closely enough" to "you are ignorant". Besides which I'm inclined to agree with the above poster that the quote seems wrong--electrons are on the same level as protons and neutrons, but quarks of of a lower order yet that phrase seems to lump them all in the same set.

  10. "Currently we don't know the best way to make ..." by Anonymous Coward · · Score: 2, Insightful

    "... graphene".

    We may not know the best way to make it, but we sure know one that's a hell of a lot simpler and more scalable than assembling it atom by atom, and that's the technique where you pull individual molecular layers off graphite by sticking a piece of sticky tape to it and ripping it off quickly. A chinese factory full of workers doing that all day long will produce a ton of graphene a hell of a lot more quickly and cheaply than anyone with an AFM.

  11. Where will this lead? by prisoner-of-enigma · · Score: 2

    To replicators, of course. Star Trek-style replicators, not Stargate-style replicators, for those of you inclined to think every new technology is going to destroy humanity.

    Granted, assembling a few atoms in a lab is a far cry from replicating food, parts, and so forth, but the principle is the same. Fabrication at the sub-atomic level gives us the ability to replicate damned near anything. Once can only imagine how disruptive such a technology will be when things like gold, diamonds, and currency can be perfectly replicated by anyone with access to such a machine.

    --
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  12. Re:Ode to Mr. Scott by Kreigaffe · · Score: 2

    No, Aluminum.

    http://en.wikipedia.org/wiki/Aluminium#Etymology

    The guy who first isolated it called it Aluminum. Some anonymous chucklehead suggested changing it to sound more like other elements.

    --
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  13. Alchemy is Nuclear Physics by JSBiff · · Score: 5, Interesting

    Alchemy happens when you change the nucleus of the atom, not the electrons. For example, in a nuclear reactor when you split Uranium or Plutonium and create entirely different daughter atoms which different numbers of protons in the nucleus than the parent had. Or, in fusion when you combine two nuclei into a single daughter nucleus.

    Simply arranging atoms without changing what element they are, would not really be alchemy as the term is generally understood.

  14. What is going on by mattr · · Score: 4, Informative

    The journalist is making it harder to understand what is going on.

    IANAP but here's how I understand it thanks to google.

    First, 85 tesla have been generated for very short instants in the lab so the article is wrong in saying 60 tesla is higher than ever achieved.

    Graphene forms a two-dimensional lattice surface like a chicken wire fence.
    For each molecule of graphene a single electron sticks out from the surface.
    These electrons are free to hop around to other atoms.
    In fact they act just like particles that have no mass and can travel at 1% of the speed of light. These quasiparticles are called massless dirac fermions. A fermion is a particle with certain properties, the nucles of a helium atom being one kind of fermion.
    Electrons travelling at relativistic speeds is not earth shattering since that is what happens in gold atoms too. But the point is the electrons are free to sweep through the lattice without hindrance, and that if you can control the way the electrons move, you can control the apparent properties of the quasiparticles.

    In 2010 Francisco Guinea in Madrid predicted that stretching graphene along all the axes of it crystal structure will make the electrons act as if subjected to a magnetic field.
    http://www.gizmag.com/straining-graphene-creates-strong-pseudo-magnetic-fields/15891/
    http://physics.berkeley.edu/research/zettl/pdf/386.Science.329-Levy.pdf

    In July 2010 Michael Crommie proved the prediction, by growing bubbles of stretched graphene that stick up like pyramids from the platinum surface they were grown on. The electrons acted as if they were subjected to 300 tesla fields.
    This technique works at room temperature.

    The paper mentioned by the OP talks about designer Dirac fermions which means that you can create quasiparticles possessing the characteristics you desire by simply moving atoms around so they make electrons move in the way necessary to make the quasiparticles appear to exist. You can thereby freely mess with simulated mass, electrical and magnetic fields, etc. which might be very useful.
    http://www.nature.com/nature/journal/v483/n7389/full/nature10941.html

    The technique used in the OP experiment is low temperature and nanoscale. But based on Crommie's work it should not be hard to imagine processes in the future that could allow similar structures to be built quickly on a larger scale.

    This is an exciting a relatively new field of research apparently but breathless reports using terms like designer babies or designer electrons when it is really designer quasiparticles, and saying that the fabric of reality is being messed with, is just distracting and does not help people who are not prepared to dive into the actual research paper to find out what is going on.

  15. BS summary by gweihir · · Score: 2

    This has nothing to do with "designer babies" or "the fabric of reality". Why do people that have noting relevant to say feel the need to blow their claims up all out of proportion.

    I mod the story "-1, stupid".

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