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Triple-Shape Plastics for Surgery

Roland Piquepaille writes "In Plastics' Day in Surgery, Red Herring reports that an international team of U.S. and German researchers has developed a new kind of plastic that can shift between three different shapes when the temperature increases. Even if these polymeric triple-shape materials have not emerged from the lab, they could eventually be employed as removable 'stents' and self-closing fasteners used by surgeons and more generally by the healthcare industry. The Emerging Tech ZDNet blog has additional references and pictures of these morphing plastics."

27 comments

  1. For those of you who hate Roland Pipqualle... by Stone+Rhino · · Score: 5, Informative
    Here's his additional references and pictures:

    In Plastics Day in Surgery, Red Herring reports that an international team of U.S. and German researchers has developed a new kind of plastic that can shift between three different shapes when the temperature increases. Even if these polymeric triple-shape materials have not emerged from the lab, they could eventually be employed as removable stents and self-closing fasteners used by surgeons and more generally by the healthcare industry. But read more

    This research work has been done partially at the MIT in Professor Robert Langers research lab. Please note that Ive already covered a previous Langers project in "Light Used to Design Shape-Shifting Plastics" (April 14, 2005).

    For this new kind of plastic, Langer worked with Professor Andreas Lendlein, director of the Institute of Polymer Research at the GKSS Research Center in Teltow, Germany, and his team.

    This research work has been published online before print by the Proceedings of the National Academy of Sciences (PNAS) under the name "Polymeric triple-shape materials" (November 20, 2006). Here is a link to the abstract.

    Shape-memory polymers represent a promising class of materials that can move from one shape to another in response to a stimulus such as heat. Thus far, these systems are dual-shape materials. Here, we report a triple-shape polymer able to change from a first shape (A) to a second shape (B) and from there to a third shape (C). Shapes B and C are recalled by subsequent temperature increases. Whereas shapes A and B are fixed by physical cross-links, shape C is defined by covalent cross-links established during network formation.

    The triple-shape effect is a general concept that requires the application of a two-step programming process to suitable polymers and can be realized for various polymer networks whose molecular structure allows formation of at least two separated domains providing pronounced physical cross-links. These domains can act as the switches, which are used in the two-step programming process for temporarily fixing shapes A and B. It is demonstrated that different combinations of shapes A and B for a polymer network in a given shape C can be obtained by adjusting specific parameters of the programming process.

    Below is a series of photographs illustrating this triple-shape effect. On the left is a tube which could be used as a stent and on the right is fastener consisting of a plate with anchors. From top to bottom, you can see the shape evolution when the temperature increases to 40C (in B) and 60C (in C). (Credit: MIT/GKSS Research Center). This image has been extracted from the PNAS paper mentioned above.

    Picture

    In "Morphing Materials Take On New Shapes," Technology Review describes this process in plain English.

    Lendlein says the key to the new structures was developing two types of polymers that have distinct melting points. At room temperature, the material holds its first shape. But when heated above a certain temperature, areas throughout the material soften, allowing it to change to an intermediate shape. At a yet higher transition temperature, the rest of the material softens, allowing the structure to take its final shape.

    But what would be these

    --


    Remember, there were no nuclear weapons before women were allowed to vote.
    1. Re:For those of you who hate Roland Pipqualle... by LiquidCoooled · · Score: 3, Insightful

      I looked at the original article - it was a bit bare.
      Then I clicked on Rolands zdnet blog thing and it was full of information.
      Why are people so against people using the web model for personal profit, especially considering how he adds information to the mix.
      The parent comment wouldn't have a chance to supply so much info if Roland hadn't dug it up, give the guy some friggin' credit.

      --
      liqbase :: faster than paper
    2. Re:For those of you who hate Roland Pipqualle... by Stone+Rhino · · Score: 5, Informative

      Mainly because he has a long habit of being a douche about including the informative links only in his blog post, rather than in the slashdot story itself, where they should be, and often posting stories that only serve to refer readers back to his blog.

      --


      Remember, there were no nuclear weapons before women were allowed to vote.
    3. Re:For those of you who hate Roland Pipqualle... by Anonymous Coward · · Score: 0

      Roland has a history of plagiarism and a questionable association with at least one of the products he purposely pimped to get people to buy into. That company took a lot of people's money without delivering a product.

    4. Re:For those of you who hate Roland Pipqualle... by jspenguin1 · · Score: 1
  2. Look out Viagra... by Anonymous Coward · · Score: 3, Funny

    hello prosthetic "limb" and a warming massage oils

    haha

    (couldn't resist)

  3. Many good uses for this technology by dangitman · · Score: 1

    Plastic surgeons could create artificial boobies that can morph into three different shapes, depending on the weather. Four if you count erect nipples.

    --
    ... and then they built the supercollider.
    1. Re:Many good uses for this technology by MousePotato · · Score: 1

      heh...

      just imagine the set of devils horns you could display when angry...

      or

      the pinochio nose when fibbing...

      or

      the spock ears for the next trekkie convention...

  4. MGS by GammaKitsune · · Score: 0, Offtopic

    I could have sworn they used something like this in one of the Metal Gear games... But I think it was a key, instead of plastic. Could have been a plastic key.

    --
    Gamertag: WyleType
    1. Re:MGS by Anonymous Coward · · Score: 0

      That was my first thought after reading the summary. It's from the first Metal Gear Solid game.

    2. Re:MGS by JAppi · · Score: 1

      Actually I do believe it was from the second Metal Gear game called. "Metal Gear: Snake Solid" Metal Gear Soild is actually the 3rd game in the series and actually borrows a lot from the second game.

  5. Morphing Plastics by loid_void · · Score: 1

    All of this brings new meaning to 98.6.

    --
    Anyone seen my jagged little pill?
  6. Easy by SuperStretchy · · Score: 1

    I have some plastics that change shape with temperature. Its called melting?

    All kidding aside.. think of the uses this might have in other fields.

    Security- don't want someone opening your door? heat a blob and it keeps it closed.
    Theme parks- Ever-changing water slides on hot days!
    PC's- Talk about modding!

    Brain hurts... kthxbye

  7. Morphing Plastics?! by Karganeth · · Score: 3, Interesting

    I have a feeling that we will soon see a new generation of dildos.

  8. Help the handicapped by PopeRatzo · · Score: 1

    I'm inclined to give the guy a break. Growing up with that name could not have been an easy row to hoe.

    I didn't say I'd visit his blog or click through any of his sponsors, but I will give him a break, just based on the fact that I get a little chuckle whenever I read his name.

    --
    You are welcome on my lawn.
    1. Re:Help the handicapped by PopeRatzo · · Score: 1

      Let's see:

      Mike Hunt ... "here, Sister"

      Dick Gazinya ... "here, Sister"

      Roland Pip... I suppose you boys think that's funny!

      --
      You are welcome on my lawn.
  9. Oh boy! by flyingsquid · · Score: 1

    Now Michael Jackson can have a nose that morphs into different shapes to fit his mood and coordinate with his outfit!

  10. slashdot and roland by Anonymous Coward · · Score: 0

    Plea to the editors .. Can you give Roland his own category? Just put all his crap in there .. pay him whatever you like.
    That way him and all his fans can have a huge kissfest orgy without inviting us.

    Ever wonder why Roland's articles and his "read here for more information and pictures" dont get play on digg?

  11. Just Imagine.... by Anonymous Coward · · Score: 0

    Just imagine the penis enlargement possibilities! Oh wait, this is Roland we're talking about... never mind.

  12. screw that! by macadamia_harold · · Score: 1

    nevermind the prosthetic "limb"... hello prosthetic girlfriend!

  13. Shape Changing Plastics and iPods by iendedi · · Score: 1

    So, how long until the iPod touchscreen will have a shape-changing plastic cover that allows for various dynamic tactile surfaces?

    Hehe... I put my iPod in my pocket and my body heat changed it into an [insert your joke here]..

    --

    It is your personal duty to fight for what is right on a daily basis. Ignoring injustice is identical to approving
  14. Sealing stems? by GNious · · Score: 1

    Self-sealing stembolts?

  15. even more interesting medical temp sensitive stuff by docinthemachine · · Score: 1

    The concept of a temperature sensitive plastic is interesting but I have seen in clinical trials substances even more strange and amazing. These are substances with "reverse thermal gelation properties". In general, stuff is liquid when hot and when colled becomes solid (really just about any stuff in the world). Well-- substabnces have been created with reverse properties - that is they are liquids when coooler and SOLIDIFY when heated! THe first medical use was a spray on scar tissue prevention substance. It seals cut raw edges inside the body. Sprays on as a liquid (ie easy to apply and fills the nooks and crannies) then it solidifies as it warms and forms a shell like protective coating (not chocolate however) while the body heals underneath- then dissolves. The substance being tested is called Poloxamer 407 see another spray-on stuff to block adhesions with a video at (different mechanism here): http://docinthemachine.com/2006/09/16/sprayable-po lymer-system-antiadhesion-now-but-in-the-future-vi deo/

  16. Shapes 1, 2, and 3 by Anonymous Coward · · Score: 0
    Shape 1:

    Woman: Come here, honey, I got what you want.
    Man: Okay.

    Some hot time later.... Shape 2:

    Man: *doink!*
    Woman: WTF is this?!
    Man: That's just my Shape 2.
    Woman: It just got curly!
    Man: Uh huh.

    Some more hot time later... Shape 3:

    Man: *doink!*
    Woman: AAAAUGH!
    Man: What?!
    Woman: It's like a cross between a watermelon and a raccoon!

  17. Medical uses by Ambidisastrous · · Score: 1

    I know it's not even out of the lab yet, but for the record, using this for removable stents is sketchy. I'm picturing a design where the stent automatically expands off the catheter as it reaches body temperature, and changing the temperature of the stent again (e.g. placing another balloon catheter in there and filling it with cold water) causes it to contract back onto a catheter. Depending on body chemistry, the blood vessel usually grows around the implanted stent over time, so to be removed, either (a) the stent needs to rip out of the vessel in order to contract again, if it's made out of these polymers, or (b) the surgeon resorts to open-heart surgery (this is what's normally done if stent implantation goes awry). So attempting to remove the stent after several weeks this way is a bad idea, but it might be possible to recover if there's a minor mistake during the actual surgery -- if the stent needs to be moved, the surgeon could squeeze some cold water into the catheter and try again, without resorting to open-heart surgery.

    With traditional stainless-steel stents, there's no negative effect to leaving the stent inside the vessel permanently, since the vessel eventually envelops the stent. If there's a benefit to having the stent gone after 6+ months (e.g. patient has inconvenient body chemistry and is likely to develop excessive scar tissue around the stent), it would be better to make the stent out of a bioreabsorbable material, so that it disappears on its own, rather than needing another surgery to remove it.

    Y-shaped vessels have always been a problem, and a stent that can fit itself to the vessel would be useful. Right now, the approach is to use a truncated-cone-shaped stent to prop open the Y, then use a second, normal stent to address the actual problem area. Without that first stent for support, placing a stent in either of the (upper) branches of the Y causes the other branch to collapse. This situation happens frequently, and there's money to be made in finding a one-stent solution -- if it's cheaper and safer than the existing two-stent solution.

    Now, what happens to a person who has one of these stents in the event of fever or hypothermia? For open-heart surgery, the patient's blood is also cooled down, and this stent's antics could add another level of complexity to the surgery. Stainless steel, optionally coated with parylene, is the material of choice for stents now. It's flexible, durable, and stable inside the body. A triple-shape plastic would have to be just as flexible, durable and stable in order to be usable for implantable devices.

    For self-sealing parts, this could be good. This material would be great for creating a seal or lock that can only be opened within a certain (safe) temperature range -- I could picture it being used in airplanes, spaceships, boats and submarines, and as a safety measure for lab equipment.