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Ohio Researchers Advance Heat Reclamation Technologies

Downchuck writes "Researchers at Ohio State University claim to have synthesized a new material capable of delivering electricity directly from heat, at an efficiency far better than existing thermoelectric materials. Scott at ArsTechnica has an interesting take: 'Merge this with the new MIT solar dish and you're in business!'"

124 comments

  1. Yeah, frying ants with a parabolic is cool and all by iminplaya · · Score: 5, Interesting

    But I like this better.

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    What?
  2. Finally! by Anonymous Coward · · Score: 5, Funny

    Finally, we have a truly renewable source of energy - we can just harness all the hot air coming from our politicians.

    1. Re:Finally! by whopub · · Score: 1

      Better yet, attach one of these devices to a domestic heater and it will feed itself perpetually. Just don't ask me how turn it on initally though...

  3. Technical point by Bruce+Perens · · Score: 5, Insightful

    It's not possible to make electricity directly from heat. It is possible to make it from a difference in heat between two points.

    1. Re:Technical point by ettlz · · Score: 5, Funny

      Yes, on this site we obey the Laws of Thermodynamics!

    2. Re:Technical point by cnettel · · Score: 4, Informative

      You make electricity directly from heat. You can't make electricity directly from temperature (or stored heat) though.

    3. Re:Technical point by Anonymous Coward · · Score: 5, Informative

      It's not possible to make electricity directly from heat. It is possible to make it from a difference in heat between two points

      heat != temperature

      But you are right that you have to have a cold reservoir to get any work from the system. But heat in thermodynamics is not the same as temperature, and it generally denotes the amount of transfered thermal energy between two systems of differing temperature.

      I'm assuming that the cold reservoir is the cooler temperature air surrounding the device.

    4. Re:Technical point by cool_arrow · · Score: 2, Informative

      Yes that is true and I believe that the most efficient thermoelectric devices are somewhere in the range of about 5% efficiency in practical applications.

    5. Re:Technical point by Bruce+Perens · · Score: 2, Insightful

      Oops, I'm getting whipped for "heat in a thermodynamic sense is not the same thing as temperature". But yes, the point here is that they've invented better thermocouple wire and thus possibly an improvement in thermoelectric generation and maybe the Peltier effect. Doubling the efficiency of those things would not necessarily make them competitive with other processes for heating and cooling.

    6. Re:Technical point by MillionthMonkey · · Score: 1

      Yes but if we were driving our cars around on Pluto, even a tiny temperature gradient could be made to do far more useful work than the same difference in temperature on Earth. This planet is a little too warm for these gizmos and so you see signs of desperation such as thallium.

      We need to build a giant ring in space that orbits the sun and keeps the Earth in perpetual shadow. That would allow a wider selection of designs for engineers trying to use exhaust heat to turn wheels. Of course, that's only if you think that the American people deserve a break with these high gas prices.

    7. Re:Technical point by Anonymous Coward · · Score: 0

      It's impossible for you to admit that you are wrong, isn't it.

    8. Re:Technical point by Anonymous Coward · · Score: 4, Funny

      The other campaign may call it pandering, but I think the American people deserve a temporary holiday from the Laws of Thermodynamics.

    9. Re:Technical point by pushing-robot · · Score: 1

      I also propose a 90-day gravity holiday, during which time I will get rich selling flying cars.

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      How can I believe you when you tell me what I don't want to hear?
    10. Re:Technical point by oldhack · · Score: 0, Redundant

      NERD!!

      (and the autistic filter)

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      Fuck systemd. Fuck Redhat. Fuck Soylent, too. Wait, scratch the last one.
    11. Re:Technical point by Doc+Ruby · · Score: 4, Informative

      But quadrupling them would. The old max zT these researchers were improving was about 0.87. They've now got it to about 1.5. And are targeting about 3.0 in their current research.

      Freon refrigerators have a zT of about 3.0. Which makes these new materials look directly competitive with them for cooling when they reach that efficiency. Since zT 1 materials are about 10% efficient, zT 3 will be able to reclaim about 30% of waste heat. That would be about 20 points of the ~60% of gasoline energy wasted as heat in car engines. Since car engines are about 20% efficient now, that would mean doubling their fuel efficiency.

      If these materials can be made, deployed, and recycled with close to (or less than) the energy inputs required now to make the car radiators/manifolds/exhaust systems they'd probably mostly replace, the benefits would be revolutionary.

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    12. Re:Technical point by Anonymous Coward · · Score: 0

      You make electricity directly from heat.

      That depends on what you mean by directly.

      Imagine that heat is "water" (the low quality energy) and electricity is "wine" (the high quality energy). You can turn "wine" directly into "water" but you can only make water into wine if you have two containers with different amounts of water and you let the water flow from the container with more water to the container with less water. Even then, not all the water that flows between the containers can be converted into wine.

      You can also reverse the process and use the process of turning "wine" into "water" to cause some of the water in the container with less water to flow back into the container with more water.

      So how much water flows between containers compared to how much is converted to/from wine? Well, it depends. If the difference in the amount of "water" in the two containers is small relative to the total amount of "water" in the containers then lots of "water" flows between the containers and only a small amount of "water" is converted to/from "wine".

      If the difference in amount of "water" is large relative to the total amounts of "water" then the amount of "water" flow is small and the amount of conversion to/from "wine" is large. In fact, if the one container didn't have any "water" at all (corresponding to absolute zero) then there would be only conversion and no flow at all.

      It's worth noting in our analogy that we can always convert "wine" completely into "water" and we can always let "water" flow between the containers to reduce the difference in the amount of water between the two containers. What's hard is converting the "water" into "wine" and increasing the difference in the amount of "water" in the containers. In fact, according to the Second Law of Thermodynamics eventually all the "wine" in the universe will turn into "water" and all the "containers" in the universe will have the same amount of "water" in them.

      A subtle point is this. Imagine that we have have our containers with different amounts of "water" in them. Imagine that we have two processes. For these same containers, one process (that we can run either in forward or reverse) has a lot of flow between containers and only a little conversion to/from "wine" and the other process (that we can also run in either forward or reverse) has only a little flow between containers but lots of conversion to/from "wine".

      Well, here's what we do: use the small-flow/high-conversion process to make "wine" and then we use the large-flow/low-conversion process to create a bigger difference in the amount of "water" in our two containers. At the end of the day we have a bigger difference between our containers and we can even have a bit of "wine" left over.

    13. Re:Technical point by Orange+Crush · · Score: 1

      ^Even if improved thermoelectrics can't directly compete in a refrigerator-type application, any improvement in their efficiency will be useful in other applications (computer cooling, portable thermoelectric cooler/wamers, etc.)

    14. Re:Technical point by Doc+Ruby · · Score: 4, Interesting

      The Technology Review article about the tech is more specific about the material's heat/electricity conversion efficiency. Evidently the current zT:0.87 material is about 6% efficient; the zT:1.5 material already achieved therefore is about 10% (about 10.3448276%) efficient. A zT:3.0 device is about 21% (about 20.6896552%) efficient.

      10% of the 60% of gasoline's energy content wasted as heat is 6% of the gasoline's energy. If the car got the average 20% fuel efficiency, that extra 6 points would be 30% more than the original 20%. A zT:3.0/21% would be 12.6 points extra, or 63% more than 20% to 32.6%.

      A 30MPG car today would get 39MPG tomorrow with the current version material. It would get 48.9MPG with the forecast zT:3 material.

      What I'm really interested in seeing is how embedding the higher zT materials inside fuelcells boost their efficiency. Because fuelcells aren't heat engines, they're not limited to the Carnot Cycle's 40% max efficiency. They already get 50% efficiency or greater at "native" voltages (like 1.48V), where their max theoretical efficiency is 83%. But still, much of their 17%+ inefficiency is generating heat. So they can be even more efficient with heat reclamation, perhaps in practice actually approaching that 83% efficiency.

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    15. Re:Technical point by DrMrLordX · · Score: 1

      It wouldn't take 90 days for us all to die if gravity took a holiday. In fact, I'm sure it'd be a matter of seconds.

    16. Re:Technical point by Anonymous Coward · · Score: 0

      *WOOSH!* (stupid lameness filter)

    17. Re:Technical point by pushing-robot · · Score: 1

      True, but I can't say a holiday from thermodynamics would be any more enjoyable.

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      How can I believe you when you tell me what I don't want to hear?
    18. Re:Technical point by Lisandro · · Score: 2, Informative

      RTGs (radioisotope thermoelectric generators) would benefit greatly from this aswell. They tend to have long life spans (in the order of the half-life of the radioactive material used), but radiation decay and thermocouple wear reduce their power output much before that.

    19. Re:Technical point by dna_(c)(tm)(r) · · Score: 1

      The other campaign may call it pandering, but I think the American people deserve a temporary holiday from the Laws of Thermodynamics.

      Meanwhile, in Cobb County, those would be referred to as the Theories of Thermodynamics, after all energy is^H^H could be inteligently designed...

    20. Re:Technical point by I+cant+believe+its+n · · Score: 1

      Have you been smoking moon rocks? Dont you know thats loco?

      Somebody think of the children!

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      She made the willows dance
    21. Re:Technical point by Sandbags · · Score: 1

      Well, first, when we get these materials to 30%, not their "we'll be a 3% soon" level, you let me know.

      Until then capturing 3% of 60%, but adding weight, complexity, and cost to the vehicle, I doubt will have any real benefit. Even at 10%, we're still looking at better improvement simply by switching to electric drive with gas backups.

      If we follow the ideas presented by www.dotyenergy.com, then we don't need to worry about it anyway. If we replace oil with man made liquid fuel, produced using free energy from wind combined with byproducts from coal energy, then we don;t really have a CO2 issue, and since free energy is not a market limited comodity, the price of WindFuels should only rise with inflation, not other market factors, allowing us to at least get past the next few hundred years until another technology that costs less and has lower environmental impact comes along.

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      There is no contest in life for which the unprepared have the advantage.
    22. Re:Technical point by Doc+Ruby · · Score: 1

      Current zT:0.87 can get about 6% efficiency; these new materials at zT:1.5 get about 10%; their forecast zT:3 materials will get about 21%, in engines like in our cars. I don't know where you're getting that 3% efficient heat recovery figure from.

      Every mechanical process could benefit from recovering significant amounts of heat. Most heat engines, especially gasoline/diesel types, include extra machinery for exhausting heat which could be replaced with probably simpler devices that are like "catalytic converters" capturing the heat instead of exhausting it. Even the windmills and other turbines you prefer would benefit from the increased efficiency: everything would.

      The question with a device like a heat reclaimer is whether the energy it captures during its lifetime is greater than the energy it costs to make, deploy and recycle it. Since these devices are said to last a long time, decades perhaps, they probably can pay for their supper. And in constant-duty machines like windmills, they're probably a faster payback than in cars that run for only about 5% of their calendar lifetimes.

      We need to use everything we've got to get past the energy/Greenhouse crisis already upon us. We're never going to not care about efficiency, especially as we power ever smaller devices, more mobile and independent of a wired infrastructure.

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    23. Re:Technical point by BrotherBeal · · Score: 3, Funny

      What's hard is converting the "water" into "wine"...

      So what you're saying is that Jesus can create electricity directly from heat? I'm confused...

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      I'm disabling ads until because I choose not to reward redesigns that are less usable than "view source".
    24. Re:Technical point by BlackPignouf · · Score: 1

      Please mod this guy down!

      Would you mind explaining us what the "difference in heat between two points" is? Heck, what is the heat of a point? (hint: it's undefined)
      Make yourself a treat : buy yourself a good thermodynamics book and come back when you're finished.

      Thank you.

    25. Re:Technical point by Sandbags · · Score: 1

      The exhaust process is a function of vapor expansion,not so much heat dissipation. If we impede that process, we reduce the efficiency of the engine itself. Can we collect enough heat as it flies through the exhaust pipes to recoup more than the combined engine impact, additional weight, and cost?

      If our fuels come from green sources, and if CO2 emission of the engine is a non-issue, than only distance per gallon is of concern. If we use WindFuels (www.dotyenergy.com), at least until something better comes along in 30-75 more years, then heat reclamation will only be perused if it is both more effective and/or lower cost than other methods to improve efficiency that we already have and don't use.

      We can simply mandate better headers and larger, smooth bend exhaust pipes and improve engine efficiency by nearly 5%. By running an engine only a peak torque (4000-5500 RPM depending on the engine) and use it only to make electricity to poewr electric motors, we can get nearly 40% out of the engine. Replace the ICE with a recombinant turbine, and the heat generated is less of an issue still, and we can approach 50%. All of these methods are available today, and can be implemented without radical vehicle redesign or the use of exotic metals.

      I agree, in large installations, factories, power generation systems, and more, heat exchanger technology has clear advantages and uses, but in small scale engine systems, we have a lot of things we can do before we get to using this technology.

      You're right, we'll constantly improve and demand more efficiency, but when we're talking about cars that will already be getting 150MPG (GM Tesla) on average commuter drives, the heat available to collect will not dramatically improve the efficiency. Further, how will such a system effect available vehicle space? Fuel cells are a great idea, if you like having a Dodge Durango as a 2 seat model....

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      There is no contest in life for which the unprepared have the advantage.
    26. Re:Technical point by Doc+Ruby · · Score: 1

      Even if we extract 20% of the energy from hot exhaust, it'll still have 80%, which will make it work about how it works now. But the radiator and manifold won't have to work as hard, be made as durable, consume as much energy in manufacture, deployment and recycling.

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    27. Re:Technical point by Sandbags · · Score: 1

      Again, with their current hopes of 10%, 20 sounds like quite a bit off from now in time. Also, can that 20% be maintained without adding back pressure to the engine, reducing it's efficiency, and also, what will this system add in vehicle costs, space requirements, maintenance charges, complexity, and weight?

      I think the system is great for large scale applications, but my understanding of the technology is that it 1) does not translate well to extremely small scale (the inside surface of an exhaust system) 2) works less efficiently on gasses than on liquids (maybe we use the radiator to capure the heat from the engine block, then transfer that to the reclaimer), 3) is a somewhat complex system, which, in the end produces electricity, not propulsion, so we still have to recycle that energy further through a hybrid engine, and at 150MPG or better average on new hybrids (electric drive, engine for battery charging only) the 20% of 150MPG would boil down to a whopping $64 per year saved (at $4 per gallon) I assume this system will cost a lot more than $600, a fair break even point for an average car over 10 years. Also, if we're using this to offset charging, but look at it across short commutes, we're competing at $2 per 150 miles, not 4, as charging at home is about half the cost, so this recouping would only be a benefit on trips longer thanh 60 miles in any given day.

      If the system CAN be installed in electric drive crossover hybrids without dramatically increasing vehicle weight, or reducing cargo space beyond marketable limitsa, and if it's cost is less than $1000 over the LIFE of the vehicle (additional maintenance included) then I'm onboard, especially if we're talking about using it in larger less efficient personal vehicles. If it will cost more, there is no market reason to work on the technology on this scale. We can simply use WindFuels in place of oil based gasoline, and the cost issues and environmental impact issues both become non-issues, rendering the technology on this scale pointless.

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      There is no contest in life for which the unprepared have the advantage.
    28. Re:Technical point by Doc+Ruby · · Score: 1

      The scientists say they'll have a product on the market in something like 3-4 years. Which, since they're working under the Ohio State patent office, means they're probably close to producing the product itself, and are just talking about patent and licensing time. The zT:1.5 material isn't a very competitive product, at 10% efficiency, to enter the very conservative automobile market with its new technology and approach. I expect that they expect to market the zT:3 material, with its 21% efficiency in the car engine operating range.

      A device made from this stuff wouldn't be complex at all, about as complex as a catalytic converter, and possibly combined with one (or just a "premuffler"). The electricity it uses would be useful right away for all the car's accessories other than driving the wheels. Hybrids could use it directly for motive power. And within 5 years, regenerative brakes will likely be standard on many models, with the electricity used inside the car already.

      Oh, and $4 a gallon is already disappearing in the rearview mirror. $10:gal gasoline makes all those other changes closer than they appear.

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    29. Re:Technical point by Sandbags · · Score: 1

      Even at $10/gallon (which we'll have Windfuels competing with at $3.50 a gallon) at 12,000 miles per year, and 150MPG average use, we're talking $160 per year savings at 20% reclamation. Over a 10 year vehicle lifespan, assuming maintenance or material replacement is nominal, you'd still need to have this total system cost less than $1600, with no impact on engine efficiency at 20% re-use. I assume there will be some engine impact. and although the material may make 20%, that assumes constant contact with the heat source. unfortunately, most of the heat will pass right by the material, never contacting the sides of the pipes, as it spewes out the rear end.

      The cars we'll be running already have regenerative breaking, so that's another non-issue. $4 per gallong should last the year, by next summer we'll be aproaching $4.50, maybe $5. Predictions are $6 by 2012 and we won't cross $10 until after 2015, worst case (the economy will likely fail if it accelerates faster than that, and it won't be fun for anyone at that pace.

      WindFulels should be entering the market within 3 years. Full electric hybrids this coming year with more than half the cars produced being full electrci hybrids by 2015. Many others will be home converting their old cars to electric gas hybrids (a guy here in Columbia SC already convertid his 1980-something pickup into a plug-in electric, and did it for less than $3000 in his own garage, others will follow).

      Even if it was on the market in 3 years, and we started putting it in 50% of new cars by 2015, the cars you're talking about adding it to will have the $80 annual benefit I'm talking about. This technology won't benefit ICE powered cars, since generating electrcity through heat, even to produce electricity for interior items, accessories, lights, etc, does not remove the need for an alternator nor improve overall MPG in older cars. Maybe it would have 1 or 2 MPG difference if you put in a bigger battery, giving battery only drive until enough heat was being generated to recycle back to the battery through this system, but on short, less than 10 mile trips, you'd have issues since the engine won't get hot enough to add engough energy back to the battery.

      Again, great technology in some areas, but since there's no real impact on older cars (without massive redesign and thousand of dolars in labor, more expensive likely than simply trading in for a used electric hybrid), and since the value in new cars would top out at about $160 per year, even at $10/gallon, (and about $80 per year now) it's simply not an economical addition to the car.

      The material may be inexpensive, and light, and similar to a cat converter, but then we have to take that electricity through a system to balance the load, syncronize the current frequency, and safely add that current to the battery. You can't just feed randomly generated energy into the cars systems... This is where the weight and complexity will come into play. This is made worse since a car will not produce a consistant amount of heat, nor will it produce much at all for the first few minutes of driving.

      We have a dozen ways to improve vehicle efficiency before such a system as this makes sense. Those ways can be put in place today. Further, since we now know how to make unlimited fuel without Oil, the market pressures and CO2 generation limits are no longer issues, so vehicle efficiency improvements beyond 2015 will not be for environmental or consumption reasons, but for cost lowering. This system increases costs, which means it unmarketable.

      In power plants, yes, constant heat, steam pressure does not really effect power generation, and we can capture that heat to make more electricity. Sure, it still needs to be made in a grid syncronous way, and it will be expensive. It will only be likely to be deployed if collecting that 20% costs less than simply generating more electricity (which it likely won't be, since power plants are about 70% efficient), or if we legislate a requirement to use it.

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      There is no contest in life for which the unprepared have the advantage.
    30. Re:Technical point by Doc+Ruby · · Score: 1

      20% reclamation of the 60% energy wasted as heat is 12% extra efficiency. If that 12% is worth only $80, that means that 100% of annual gasoline expenses is only $670. At $4 a gallon (which is 2008's average, not 2013's), that's 166.7 gallons, which at 35MPG is 5833 miles. 500 miles a month.

      Something's wrong with your math. Average annual mileage is at least double that.

      Besides, there are other costs for the lower mileage. More frequent fillup stops/trips. Environmental damage.

      People will pay more than $500 more for a car to get 33.6 instead of 30MPG, even if they don't save as much in gas expenses while they own the car.

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  4. For those who didn't RTFA: by magus_melchior · · Score: 0

    The new material contains thallium. Greenpeace will have a field day with this one.

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    "We are Microsoft. You shall be assimilated. Competition is futile."
    1. Re:For those who didn't RTFA: by magus_melchior · · Score: 5, Informative

      And since I can't make hyperlinks correctly on slashdot, I'll try again: thallium.

      Nasty stuff, as its compounds are very easily absorbed through potassium uptake pathways in your body, but behave very, very differently from potassium. I seem to remember a chemist friend telling me that if you deal with thallium, you practically need an entirely separate lab for it.

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      "We are Microsoft. You shall be assimilated. Competition is futile."
    2. Re:For those who didn't RTFA: by Anonymous Coward · · Score: 0

      Greenpeace should pick their poison already, so to speak.

    3. Re:For those who didn't RTFA: by maeka · · Score: 1

      Greenpeace should pick their poison already, so to speak.

      I'll take the continuation of gradual environmental change with its multiple solutions over widespread exposure to fast-acting poison, thank you very much.

    4. Re:For those who didn't RTFA: by mosb1000 · · Score: 2, Interesting

      It's doped with thallium, that means that the thallium is imbedded in the metal alloy. I don't think it's going anywhere.

    5. Re:For those who didn't RTFA: by maeka · · Score: 1

      If there's no issue, then there's no issue.

    6. Re:For those who didn't RTFA: by Doc+Ruby · · Score: 1

      Not if they recycle it. The scientists point out that the heat reclaimer component, with no moving parts, will last the lifetimes of several cars. So it should be reused rather than disposed.

      Besides, cars already contain lots of highly toxic materials, especially if you consider the toxic products when cars burn, which many do.

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    7. Re:For those who didn't RTFA: by gormanw · · Score: 0

      A friend of mine was studying using solar to heat salts, as the salts were very poor thermal conductors. I am reminded of the principle that when changing energy from one form to another, there is always loss. It is in this loss where we find costs. There is a blog http://www.economicefficiency.blogspot.com/ that talks about the cost of "green" technologies. I would like to see more discussion on those topics.

  5. Put that in a power plant? by 4D6963 · · Score: 3, Insightful

    Could it be used to get more power out of a nuclear power plant?

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    1. Re:Put that in a power plant? by Anonymous Coward · · Score: 0

      As a matter of scaling, a nuke plant's steam turbines are converting a LOT of heat to mechanical energy. Even if you plastered an outflow heat sink with this stuff, I think the quantities you're talking about are drawfed by what the turbine converts. Although every little bit counts, there is a point at which running after waste heat produces diminishing returns. With fancy new materials which cost dozens of times more for patent licensing than the component materials and manufacturing costs, the point of diminishing returns can be frustratingly low.

    2. Re:Put that in a power plant? by 4D6963 · · Score: 1

      Interesting, however I was rather thinking of putting it like straight against the very hot part of the reactor.

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      You just got troll'd!
  6. So, this is a reverse peltier? by metalcup · · Score: 1

    Peltier elements are used to rapidly cool small surfaces (such as PCR racks, etc), and they use electricity and some trick of semiconductors to do it (http://en.wikipedia.org/wiki/Thermoelectric_effect). So this is a reverse peltier effect then? cool...

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    "Laziness is an optimisation protocol"
    1. Re:So, this is a reverse peltier? by cnettel · · Score: 3, Informative
      Any Peltier element can give you power as well. The point is that even the theoretically optimal difference is totally lousy if your heat difference is somewhere like the one between water freezing and water boiling. You need a colder cold sink, or a much hotter heat source, to get some serious efficiency. RTGs tend to be quite hot in the hot end.

      This allows better RTGs, but they would only be marginally efficient for, say, reclaiming computer case waste heat. This is especially so as you can't put them on the CPU directly, where the differential is great, because they are insulating as well. You will need to put it at the radiating end, over a large surface.

    2. Re:So, this is a reverse peltier? by famebait · · Score: 1

      You can run peltier elements backwards.

      The problem is that efficiency is utterly lousy to begin with, and then degrades, so it is only used in very niche applications. If the new material improves even just the lifetime issue, it expands usefulness quite dramatically.

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      sudo ergo sum
  7. Hot technology by gmuslera · · Score: 2, Interesting

    That material reach its peak at 950F (~500C). Not sure if MIT approach will worth combining with this as maybe the area needed could make electricity by other means.

    But there are a lot of areas where heat is produced, and some of this could be used to get extra electricity.

    Maybe the most important point, at what cost? how rare/expensive is that new material? If is very, maybe the main use would be not for our normal lifes, but maybe for i.e. space probes.

    1. Re:Hot technology by jonadab · · Score: 1

      > That material reach its peak at 950F (~500C).

      I think my attic gets nearly that hot in the summertime...

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      Cut that out, or I will ship you to Norilsk in a box.
    2. Re:Hot technology by sokoban · · Score: 2, Informative

      Maybe the most important point, at what cost? how rare/expensive is that new material? If is very, maybe the main use would be not for our normal lifes, but maybe for i.e. space probes.

      Lead is very cheap, Tellurium is about 20 some odd dollars per pound, but Thallium is damn expensive. In the late 90's Thallium was running about $600 per pound. That said, I'm not sure how much Thallium will be needed for this application.

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      09 F9 11 02 9D 74 E3 5B D8 41 56 C5 63 56 88 C0 is the magic number.
    3. Re:Hot technology by im_thatoneguy · · Score: 3, Insightful

      Well we are using Platinum in extremely warm car parts as it is. So placing rare earth metals in our exhaust system isn't a far out idea in the automotive industry. ;)

    4. Re:Hot technology by sokoban · · Score: 1

      Well we are using Platinum in extremely warm car parts as it is. So placing rare earth metals in our exhaust system isn't a far out idea in the automotive industry. ;)

      Right, but there is roughly 1-3 grams of catalyst in a catalytic converter in a car. The article doesn't say how much Thallium is needed in this application.

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      09 F9 11 02 9D 74 E3 5B D8 41 56 C5 63 56 88 C0 is the magic number.
    5. Re:Hot technology by Cor-cor · · Score: 1

      Maybe the most important point, at what cost? how rare/expensive is that new material? If is very, maybe the main use would be not for our normal lifes, but maybe for i.e. space probes.

      They already use materials like this in space probes - you put a hot radioactive isotope at the end of one of those long rods and thermoelectric generators through the rod - they're ridiculously inefficient right now, but there are no moving parts they're less likely to break down, which is more important on long, unmanned space missions. I'm a materials engineering major and one of the things we were told in our intro class was that if anyone ever figures out a way to make this type of material more efficient, they will make bank.

      Theoretically, you can pump them up to a higher efficiency than modern generators and keep the moving parts out, eliminating nearly all of the maintenance costs in power production. So I find this very exciting, although a little disappointing that there's one less target to go after now.

  8. Geothermal plug in by SubComdTaco · · Score: 3, Interesting

    From the article: "the material is most effective between 450 and 950 Fahrenheit" So simply plug this into a geothermal source, instant energy solution until Earth's core freezes.

    1. Re:Geothermal plug in by CDMA_Demo · · Score: 1

      From the article: "the material is most effective between 450 and 950 Fahrenheit" So simply plug this into a geothermal source, instant energy solution until Earth's core freezes.

      How about those floating colonies on venus?

  9. Thallium by MillionthMonkey · · Score: 2, Interesting

    Thallium accumulates in your testicles. I remember hearing stories about labs handling thallium where only women were allowed.

    1. Re:Thallium by moderatorrater · · Score: 2, Funny

      Great, now I'm going to start getting spam about using thallium to enhance my testicles.

    2. Re:Thallium by value_added · · Score: 4, Funny

      Thallium accumulates in your testicles. I remember hearing stories about labs handling thallium where only women were allowed.

      Well, the article does explicitly state that "The material does all the work."

    3. Re:Thallium by Mspangler · · Score: 2, Interesting

      "I remember hearing stories about labs handling thallium where only women were allowed."

      True. While I was at the U of I my chemistry professor was trying to stick thallium atoms to a cyclopentadiene molecules for some odd reason. The students working on it were all girls.

    4. Re:Thallium by MillionthMonkey · · Score: 2, Informative

      my chemistry professor was trying to stick thallium atoms to a cyclopentadiene molecules for some odd reason.

      Usually when they stick goofy metals on organic compounds they intend for the metal to be replaced with some organic moiety. The metal guides the reaction so that the organic replacement attaches to the right carbon atom. Thallium cyclopentadiene is a starting material for prostaglandin synthesis. You add methoxymethyl chloride to it, and the methoxymethyl group replaces the thallium and you get methoxymethylcyclopentadiene plus thallium chloride.

      Benzoxymethylchloride works too if you want to start with benzoxymethylcyclopentadiene.

    5. Re:Thallium by Anonymous Coward · · Score: 0

      While I was at the U of I my chemistry professor was trying to stick thallium atoms to a cyclopentadiene molecules for some odd reason. The students working on it were all girls.

      No, that's just because your chem prof liked to hit on barely legal chicks. He probably also kept the thermostat high in the lab, so they'd wear skimpier outfits to work.

  10. patent pending & ah, (insert MIT randomly) aga by CDMA_Demo · · Score: 1

    This research was funded by the BSST Corporation; the State of Ohio Department of Development's Center for Photovoltaic Innovation and Commercialization at Ohio State University; the Beckman Institute; the Swedish Bengt Lundqvist Minne Foundation; and NASA's Jet Propulsion Laboratory.

    Heremans' team is continuing to work on this patent-pending technology.

  11. Detailed Scientific Analysis Here by Doc+Ruby · · Score: 4, Informative

    The article at the Green Car Congress site titled New Approach to Developing Thermoelectric Materials Doubles Efficiency" has a lot more scientific details than that article linked from the summary, especially on the actual formula that determines "zT", which is the thermoelectric conversion efficiency coefficient:

    The dimensionless zT for thermoelectric materials is calculated by the formula zT= T*(S2)/), where S is the thermoelectric power or Seebeck coefficient of the TE material, and are the electrical and thermal conductivities, respectively, and T is the absolute temperature.

    And also detailed nanomaterials engineering analysis of the quantum structure of the quantum chemistry's thermoelectric effects.

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  12. How much does it cost? by eccenthink · · Score: 1

    No mention of actual cost as far as I can tell. It's twice as efficient but does it cost 100 times more or twice as much? The former probably makes it far less useful, the latter would be great.

    1. Re:How much does it cost? by Anonymous Coward · · Score: 1, Funny

      does it cost 100 times more or twice as much? The former probably makes it far less useful, the latter would be great.

      A very good point! But let me make sure I understand it. You're saying that it would be better if it cost less? Man that's some good thinking. How do you do it?

    2. Re:How much does it cost? by Doc+Ruby · · Score: 1

      Cost compared to what?

      Gasoline and other petrofuel prices are going nowhere but up, up, up, until there isn't enough to use for fuel anymore (oil and natural gas, anyway). And the actual costs of pumping all that CO2 into the Greenhouse are hard to calculate: how much does Greenland melting the seas 20 feet higher cost?

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  13. The comments attached to the fine article... by Horar · · Score: 4, Informative

    ... contain a link to a possibly more useful article with some more comprehensible numbers:

    http://www.technologyreview.com/Energy/21125/

    e.g. The device could increase fuel efficiency of vehicles by approximately 10 percent.

  14. 2. ??? by pr0nbot · · Score: 1

    Merge this with the new MIT solar dish and you're in business!'

    Ah cool, now we know:

    1. xyz
    2. ???^H^H^H Invent thermoelectric material
    3. Profit!
  15. Themoelectrics Already Pretty Good by Doc+Ruby · · Score: 5, Interesting

    Even though that article linked from the summary says that typical engines in cars get about 25% of the gasoline's energy content into car motion, it's actually about 20%. That's a lot of wasted energy: about 4:1 waste:use.

    But lots of combined cycle plants (like CCGT gas turbines) reclaim a lot of their waste heat into more power. Taking a maximum mechanical power extraction of 60% of the gas' energy up to 85% by heating steam, which is an additional 25% of the original mechanical power.

    CCGT reclamation tech is probably not practical for vehicles, so this new material is a welcome advance. Especially if the researchers get the zT from its new 1.5 high to its predicted 3.0 or so. But in fact DARPA has funded Trinh Vo at Lawrence Livermore National Labs to grow nanowires that already have a zT at 3.

    More of that kind of material research is very welcome, because at zT 3, these materials can replace freon refrigerators with the same electrical efficiency. Since freon refrigerators require lots of energy to build, and then to recycle, replacing them with a simple material that can scale to any size (including very small, as in microelectronics), means a vast sector of modern industry, including transportation, could switch. If making the material is less energy intensive, and less reliant on a limited critical resource than the freon refrigerators or the CCGT reclamation systems, global energy efficiency could take a giant leap.

    A leap that could be just around the corner, in Ohio.

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    1. Re:Themoelectrics Already Pretty Good by Ancient_Hacker · · Score: 1

      >at zT 3, these materials can replace freon refrigerators.

      Uh, how? The Freon cycle can give EERs of 15.
      An average Peltier device has an EER of under 0.4.

      The numbers don't seem to work out.

    2. Re:Themoelectrics Already Pretty Good by Doc+Ruby · · Score: 3, Informative

      "A thermoelectric material designed to replace a conventional Freon-gas refrigerator must have a ZT of at least 3."

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    3. Re:Themoelectrics Already Pretty Good by sapphire+wyvern · · Score: 1

      It would also likely have dramatic health & nutrition impacts in developing countries, as refrigeration becomes economically accessible to people who would not previously have been able to afford it.

      That might partially offset the energy savings, but since it would have direct benefits in reducing food wastage, it's still a very good thing.

    4. Re:Themoelectrics Already Pretty Good by MobyDisk · · Score: 1

      They aren't saying that this material would make a more efficient refrigerator, only that it would be a simpler/cheaper one. I am guessing that places that don't have refrigeration are that way due to a lack of a power source. I'm not sure this will help.

    5. Re:Themoelectrics Already Pretty Good by Ancient_Hacker · · Score: 1

      Well yes, a Zt of 3 would be nice, but it's not sufficent.

      In general devices that take in random energy (heat) and output very structured energy (DC) have very low efficiencies, like single digits. It's hard to corral random molecular motion into coordinated electron motion. Your typical thermocouple puts out millivolts.

    6. Re:Themoelectrics Already Pretty Good by Doc+Ruby · · Score: 2, Informative

      But this new material is already projecting a zT:3 as part of their current scope of R&D.

      A Technology Review article explains that in car engines, these zT jumps deliver efficiency from the old 6%, to the new 10%, looking at 21%. So it seems that this material does quite well at that hard job.

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    7. Re:Themoelectrics Already Pretty Good by brianerst · · Score: 1
      This is still way too expensive for developing countries - even though the refrigerator itself may cost less to build and service, the energy costs don't really improve. With few or overstressed power systems, this isn't going to help.

      What can help is "Pot-in-pot" refrigerators. Two nesting unglazed ceramic pots, separated by wet sand and covered with a wet towel, will keep the interior cold enough thru evaporative cooling to keep vegetables fresh for up to two weeks.

  16. They have decided to name it... by HitByASquirrel · · Score: 1

    unobtainium.

  17. Straight from The Core by Deltaspectre · · Score: 1

    Unobtanium anyone?

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    My UID is prime... is yours?
  18. Power Efficiency Rating? by mux2000 · · Score: 2, Insightful

    What's this power efficiency rating? How much is 1.5 in God's honest Watts per Kelvin, or a simple percentage of power in/power out?

  19. Re:The Counter: Stats, Browser Stats, OS by Anonymous Coward · · Score: 0

    15. Windows Vista 4 (0%)

    Something is especially rotten in Denmark, and that #15 score can't be correct, either. Or caaaan it?

  20. Old news by jdb2 · · Score: 1

    A while back there was an article on /. about a "quantum afterburner" : a device that could directly extract energy from a heat source, say, car exhaust, in the form of a laser beam.

    Here's a link to the cached Nature article : http://209.85.141.104/search?q=cache:RV6U7lxRqFUJ:www.nature.com/nsu%255C/nsu_pf/020128/020128-3.html+quantum+laser+heat+car+exhaust&hl=en&ct=clnk&cd=1&gl=us

    jdb2

  21. I have a cheaper way by redcaboodle · · Score: 2, Funny

    Just attach a generator to the lower jaws to my husband and his mother. The energy they produce by moaning about the heat should cool the whole of Cologne for the summer.

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    -- Put crudely, the world is an extremely large problem instance. (Russel/Norvig Artificial Intelligence)
  22. What is the %Efficiency of a 1.5 zT? by Doc+Ruby · · Score: 1

    This advance's benefits are all described in terms of an increased zT now up to 1.5, predicted to go up to 3 or so in the really perfected version of the material. But what does "zT" mean in actual efficiency?

    In real terms, let's say that a car engine today consumes about 300KW total contained in its gasoline flow, converting about 20% of that into 60KW for forward motion, and about 60% of that into about 180KW of heat (out the exhaust, and heating the engine/radiator, car and road). If the zT 1.5 material were used at maximum effectiveness in capturing some of that 60%/180KW waste heat as electricity, how many KW of electricity would it put out, into, say, a battery?

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    1. Re:What is the %Efficiency of a 1.5 zT? by florescent_beige · · Score: 2, Interesting

      z is related to the Seebeck coeff (which tells you how much voltage a given delta-temp gives you in a material), the resistivity and thermal conductivity. It is multiplied by T (the average temp at which the performance is measured) to give a non-dimensional number.

      zT doesn't tell you the efficiency because that would depend on the delta T (next para), but it is roughly proportional to it for given operating conditions. zT = 1 materials have efficiency maybe around 5% under best conditions, for zt = 3 you might be around 20%. Notice that if you know S and delta T you know the voltage: you can do some simple circuit calcs with a matched impedance and get the power it will generate. Compare that to the heat energy you get from the delta T and the thermal conductivity and you can get an efficiency, but instead of that lets just throw out some round numbers.

      Remember efficiency depends on the delta T due to the 2nd law of thermodyamics. The smaller delta T is the lower the max theoretical efficiency is. If the engine exhaust is at lets say 500F the max efficiency any device could get would be 1 - (492 + 72)/(492 + 500) = 43%. So that would be 78kW of your 180kW for a thermodynamically perfect device.

      So if you can get maybe 20% out of thermoelectrics under the best conditions, the low-temp engine exhaust scenario would probably mean you could get at best 10%. So 20kW or so I'd guess. Once you design an actual system it would probably be more like 5 or 10kW.

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      Equine Mammals Are Considerably Smaller
  23. Use the paint by TheCastro · · Score: 1

    Remember a few days ago there was an article about paint being able to help absorb sunlight for use on solar panels, well combining the two could actually work with absorbing light and heat energy from the sun.

  24. Nuclear Reactors by Sibko · · Score: 1

    I wonder what this kind of technology, once sufficiently advanced enough to absorb the high levels of heat, could do to change nuclear reactor designs.

  25. Imagine a Geothermal Cluster of This Stuff by Doc+Ruby · · Score: 1

    If this stuff can efficiently convert heat to electricity with very little energy input to manufacture it (compared to, say, steam engines), and can withstand high temperatures without being destroyed, what would it do to geothermal electric production?

    Would it not only increase the efficiency of the plants, but perhaps also make accessible lots of geothermal that is expensive to reach with today's bulky mechanical probes? Could we just drill to hot depths, then snake cables down it, and "plug into the ground"?

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    1. Re:Imagine a Geothermal Cluster of This Stuff by famebait · · Score: 1

      I think there is still a loong way to go to compete with modern land-based thermal plants. Even modern ships stretch their diesel impressively far.

      But for applications where you can't lug around industrial-scale heavy machinery, all improvements in heat reclamation are welcome, even though it's all in a different ballpark for the foreseeable future.

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    2. Re:Imagine a Geothermal Cluster of This Stuff by Doc+Ruby · · Score: 1

      I think increasing the efficiency of thermoelectric materials will be welcome in all thermal plants, whether stationary on land or otherwise. There is no need for competition in these technologies, they're complementary. I'd love to see geothermal efficiency jump by 20%.

      But there's also probably lots of places that can't support a full geothermal plant. But which could support some dinky infrastructure about as heavy as an old-West windmill. If it were made of this stuff, that could mean quite a lot of power. Especially in remote locations, a combination of wind/solar/geothermal with storage could add a geothermal "trickle charge" to the statistical average wind/solar recharge blasts, and guarantee full power at constant duty.

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    3. Re:Imagine a Geothermal Cluster of This Stuff by famebait · · Score: 1

      By thermal I meant all electric plants powered by heat (coal, oil, gas, nuclear, geothermal, solar-thermal). They don't use thermoelectric conversion because top-end mechanical conversion is much more efficient, and probably still will be even with this new step in thermoelectric converters.
      Waste heat is better used for heating, and in any case don't delver the sort of temperature gradient you need for efficient thermoelectric.

      I agree that small-scale stuff is probably nearer in time as a viable application, since small-scale mechanical engines are less efficient (although a good sterling engine is still pretty impressive). Heating remains the best application for small-scale geothermal remains heating, though.

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  26. Pity it sounds pretty poisonous by D4C5CE · · Score: 4, Insightful

    thallium-doped lead telluride

    An achievement made up of toxic elements, the first being rat poison, the last being the rarest there is. Chances are this won't be cheap to make nor to dispose of, and I wonder what hazards it would pose to the environment if released (vehicles do crash or get abandoned from time to time).

    1. Re:Pity it sounds pretty poisonous by ceoyoyo · · Score: 1

      Not even close to the rarest there is. Tellurium is a little more common than gold or platinum. We already use platinum in catalytic converters. As you say, thallium is something that can be found in the average garage or basement already.

    2. Re:Pity it sounds pretty poisonous by Anonymous Coward · · Score: 0

      We already use platinum in catalytic converters.

      That hasn't been done for decades now. Palladium is used instead and it's use had driving the price up substantially.

  27. Peltier devices work both ways by EmbeddedJanitor · · Score: 2, Informative

    Use power to shift heat or generate power from heat flow.

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  28. Link to paper by jdb2 · · Score: 1

    Here's a link to the pre-print :

    http://xxx.lanl.gov/abs/quant-ph/0105135

    jdb2

  29. Re:foad, nazi scumbag by VillageDolt · · Score: 1

    Take your Zyprexa, please!

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  30. Correction by Anonymous Coward · · Score: 0

    That should be THE Ohio State University in the original posting. They get PO'ed without the definite article.

  31. Sweet, sweet, sweet by Runaway1956 · · Score: 1

    Sweet. Without actually researching further than a couple links, it looks as if this doo-hickey thing-a-ma-bob will be able to replace alternators (or in some few cases, generators) on vehicles. Sweet. It wonÂt wear out, since there are no moving parts. ItÂll last the lifetime of most vehicles, reducing upkeep expenses, it should weigh considerably less than an alternator, which will help fuel efficiency. I like it. Heck, you canÂt HELP liking it!! Hope it makes itÂs way to market soon!

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    "Windows is like the faint smell of piss in a subway: it's there, and there's nothing you can do about it." - Charlie Br
  32. But how does it compare to the JTEC? by WindBourne · · Score: 2, Informative

    Johnson Thermoelectric Energy Conversion System? Seriously, this one is being developed to operate at lower temps. I wonder if this new one will work better or not? But it sure would be useful to add one (or both) of these to say power plants to absorb some of the heat and continue generating more electricity.

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  33. cars? by Pictish+Prince · · Score: 1

    Where's my thermoelectric flying car, goddam it!

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  34. Re:foad, nazi scumbag by Anonymous Coward · · Score: 0

    I love Slashdot!

  35. Re:Yeah, frying ants with a parabolic is cool and by Sandbags · · Score: 1

    Who about this: www.dotyenergy.com

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  36. Don't get too excited by Kupfernigk · · Score: 1
    Most boat owners could really do with a cheap generator that produces not more than around 25-50 watts (which will drive your central heating system in colder climates and your refrigerator in hot ones - you don't really want a big Diesel running for hours a day and big batteries for when it is not running.)

    A few years ago I investigated thermoelectric generators and contacted the suppliers. The unit is basically a thermoelectric generator, air-cooled, with a propane heater providing the hot side. Which at first sight looks very simple. The conversation went something like this.

    "You don't want this, it's not economic."
    "Nor is spending $10000 on a new generator just to produce an average 50 watts."
    "It still isn't economic."
    "Perhaps I'm an eccentric millionaire?"
    "Still not worth it."

    In fact, they flatly refused even to quote. Which suggests that current thermoelectric technology, with all the peripherals, is hugely expensive. So how is it suddenly going to be easy and cheap to stick this in a car exhaust?

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    From scarped cliff or quarried stone she cries "A thousand types are gone, I care for nothing, no not one."
  37. 2x Efficiency of SECOND best? by owslystnly · · Score: 1

    "The invention, thallium-doped lead telluride, is twice as efficient as the second most efficient material used in thermoelectric power." Erm, how much more efficient is it than the FIRST most efficient material?

    1. Re:2x Efficiency of SECOND best? by zippthorne · · Score: 1

      Even after reading the article, you can't think if *anything* that might be more efficient than the second most efficient material?

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      Can you be Even More Awesome?!
  38. Nothing new about it by Anonymous Coward · · Score: 0

    The damn peace & freedom loving French ( I hate them ;-) )did it up in the Pyrenees back in the 70's
    http://www.time.com/time/magazine/article/0,9171,909204,00.html

    This is where it is http://en.wikipedia.org/wiki/Odeillo

  39. Typo by Anonymous Coward · · Score: 0

    Excuse me, shouldn't it be THE Ohio State University?

  40. I used to work with thallium by wurp · · Score: 1

    I was a lab grunt for Dr. Shams (not sure of spelling, Pakistani guy) and Dr. Sheng at the University of Arkansas on the superconductivity lab. Dr. Sheng actually held the world record on high temperature superconductors for about 5-8 years, for Tl2Ca2Cu3Ox (a thallium based ceramic superconductor).

    Our only precautions were to put on a mask and latex gloves before opening the thallium bottle and to clean up any spills. I had been told that about 4 grams was enough to kill me, and it accumulates as it's a heavy metal.

    I'm fine and apparently quite fertile, since I have three kids and we only meant to have two :-) All are perfectly healthy.

    This is *not* intended as an anecdote to convince you that handling thallium is safe. I just thought it was interesting that we didn't have more safety features in place. I hope they do now!

  41. Gradient by vainov · · Score: 1

    Meny have pointed out that such a device is useless w/o a temperature gradient. However, when such a gradient exists, there is a solution that is much more potent, commercially available and suitable for use in most environments that I can think of right now. I'm of course talking about the Stirling engine!
    During extremely favourable conditions such a device, combined with a generator, can turn as much as 30% of the energy in the gradient into electrical power!!! That, my friends, is a lot!
    A more polite and probable outcome, like 10%, is still excellent when there is a source of heat that would otherwise go to waste. This new device may fill some nische, but once enegry prices have risen enough the Sterling enginge will be king!

  42. Re:Yeah, frying ants with a parabolic is cool and by zippthorne · · Score: 1

    That's neat and all, but the carnot efficiency of your wind generator is very low, so you have to use *much* greater area than with a traditional solar-thermal generator.

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  43. Vacation from Thermodynamics by CustomDesigned · · Score: 1

    Actually, there are temporary vacations from Thermodynamics happening all the time at the nano-scale level. The "laws" of thermodynamics are "laws" of averages over astronomical (standard units being 6.023x10^23 molecules) numbers. There is no law that says your room temperature glass of water can't suddenly begin to boil while sporting ice cubes. It is just astronomically improbable (but not improbable enough to power a starship). For that matter, resurrection from the dead is not impossible - just astronomically improbable (the same can be said for abiogenesis).

  44. The trick is... by CustomDesigned · · Score: 1

    for the 90 day holiday to apply to each car independently. *Obviously* you don't want everything going on gravity vacation at once.

  45. Re:Yeah, frying ants with a parabolic is cool and by iminplaya · · Score: 1

    That may be the price of avoiding extreme temperatures and pressures. The relative safety and reliability seems worth it to me. Efficiency isn't the only game in town. "Efficient" batteries in cell phones and laptops are a case in point.

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  46. Nature abhors a gradient by rumblin'rabbit · · Score: 1

    He obviously meant temperature, not heat.

    With this correction, he's right. Nature obhors a gradient, and thus from a gradient one can extract work. Heat, in and of itself, is not free energy.

    1. Re:Nature abhors a gradient by BlackPignouf · · Score: 1

      Well, with your definition of "being right", I suppose Bush's government could deserve both peace and physics Nobel prize.

  47. Re:Yeah, frying ants with a parabolic is cool and by zippthorne · · Score: 1

    Perhaps. But you're talking about orders of magnitude more land area for plants of the same output, and the same "fuel source" And not only that, but "traditional" solar plants only need polished aluminum in any abundance. The materials which must withstand extreme temperatures are much better utilized in a concentrated location.

    I'm not sure where your analogy was going, though. Both laptop and cell phone batteries are efficient* and compact *at least as compared to other mass-produced batteries. The solar tower you boost is neither.

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    Can you be Even More Awesome?!
  48. Re:Yeah, frying ants with a parabolic is cool and by iminplaya · · Score: 1

    I'm not talking about portable installations. I'm going with the idea that the mad craving for efficiency can lead to dangerous machinery. Using the batteries as the example. Small efficient batteries can't dissipate the heat so well. We have plenty of empty land. In fact most of it is empty. Very unsuitable for human habitat, or agriculture. I'm more inclined to go with simplicity and serviceability and the use of cheap, possibly locally available materials. Without the extreme temps, these machines seem more likely to fulfill these goals.

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