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Aerosol Spray to Identify Bombing Suspects

RedHanded writes "Forensic chemists at the Hebrew University of Jerusalem have developed a color-changing spray that can identify people suspected of making or planting bombs. The chemical turns from yellow to bright red when it comes into contact with urea nitrate, an explosive residue that may be left behind on the hands of someone who has handled an improvised device."

44 of 191 comments (clear)

  1. Basic hygiene by LiquidCoooled · · Score: 5, Insightful

    How many false alarms are they going to get after people don't wash their hands after visiting the bathroom?

    Maybe that is what they are looking for - poor hygiene = terrorist?

    Perhaps this chemical is the same one which makes the purple cloud of shame in the swimming pool (I know its a legend but still..)

    --
    liqbase :: faster than paper
    1. Re:Basic hygiene by Anonymous Coward · · Score: 4, Funny

      From the article:

      Spraying this substance in the air will show the farts of anyone in the room as a blue haze.

      Ha ! Finally some way to track down the lactose intolerant!

    2. Re:Basic hygiene by Upaut · · Score: 5, Interesting

      Only if this person with bad hygiene sweats nitric acid...

      I'm more worried about, well, me... I use urea nitrate in my tropical orchid mix...

      --
      3 degrees of separation from Vladimir Putin
    3. Re:Basic hygiene by Neanderthal+Ninny · · Score: 2, Interesting

      How many people in their lifetime ever actually handle urea nitrate anyways? In my previous career I used to handle explosives and most explosives your don't want to handle with your bare hands since most of them are a health hazard also, not to mention the blasting power. The nitrates in the most explosives are basal dilators so you turn bright red because all of the blood vessels in your body are opening up. You may identify people that handle explosives this way but alcohol does the same thing so don't count on it.

    4. Re:Basic hygiene by fbjon · · Score: 4, Funny

      I was thinking more like: yellow is neutral, red is enemy. So, air-burst a big bomb with this, take satellite pics, and you have an instant minimap!

      --
      True confidence comes not from realising you are as good as your peers, but that your peers are as bad as you are.
    5. Re:Basic hygiene by battery111 · · Score: 5, Interesting

      Well, not exactly. I don't know enough about how the chemical works (it will likely be found to cause cancer in the state of california at a later date), but part of manufacturing urea nitrate is indeed to distill ones urine. My guess is that it would have to be at a relatively high concentration in order to react, but that may not be the case, which would cause a large number of false positives. Another thing to keep in mind is that urea nitrate is only one of a large number of homemade explosives, and not really the most common, so while it is a promising advance, it really is not the be all end all of bombmaker detection. One also has to raise questions about its effects on personal privacy, but likely in the areas this is going to be employed, it may be a secondary consideration.

    6. Re:Basic hygiene by Kingrames · · Score: 2, Interesting

      More importantly, are there going to be people who walk around in airports spraying random people?
      This is why I stay away from certain areas of the mall.

      And more importantly, what will happen when someone yells "Security! This man is assaulting people with aerosol spray!" and the airport undergoes lockdown?

      Or more feasibly, what happens when the terrorists use the aerosol as an opportunity to walk around the airport spraying people's hands, infecting them with SARS or some other horrifying disease?

      Seriously, these people need to find an alternative way of doing this. it opens up too many scary options for abuse.

      --
      If you can read this, I forgot to post anonymously.
    7. Re:Basic hygiene by reverseengineer · · Score: 3, Informative
      Well, according this earlier abstract by the same group (the paper from two years ago where they originally propose the dye- the paper linked to the article is really just about using X-ray crystallography to study the structure of the dye/urea nitrate complex):

      Urea itself, which is the starting material for urea nitrate, does not react with p-DMAC under the same conditions. Other potential sources of false positive response e.g., common fertilizers, medications containing the urea moiety and various amines, do not produce the red pigment with p-DMAC. Exhibits collected from 10 terrorist cases have been tested with p-DMAC. The results were in full agreement with those obtained by instrumental techniques including GC/MS, XRD and IR.

      From what I know of the chemistry of aldehydes (there's a great icebreaker at parties...), this dye should react with any primary or secondary amine- like regular old urea, ammonia, amino acids, etc. What this group claims, however, is that there is a particular color change reaction for this dye which occurs for urea nitrate which does not occur for other amines.

      I think what the article's confusing picture of the dye and urea nitrate interacting is suggesting is that the hydrogen bonds between the nitrate and urea moieties remain intact even after the urea has bonded to the dye, so the nitrate moiety affects the dye complex and the color it appears. I'd still be concerned about false positives, personally, particularly from different amine salts. The color produced might be uniquely identifiable to a spectrophotometer, but for a visual test I'd be worried about anything that turns "reddish" enough to produce a false positive.

      --
      "FDA staff reviewers expressed concern about the number of patients who were left out of the study because they died."
    8. Re:Basic hygiene by Rutulian · · Score: 4, Informative

      Unless you make it yourself, I think it is unlikely you have urea nitrate in your fertilizer. You probably have urea + potassium nitrate (or ammonium nitrate). To form urea nitrate, you need a strongly acidic conditions.

      From the article, the "amazing" new molecule is just commercially available p-dimethylaminocinnamaldehyde. The chemistry involved is already well-known. It is used for, among other things, indirectly detecting biotin (by way of the urea in the molecule). Basically you mix your urea-containing compound with a strong acid (sulfuric acid works), which promotes enol tautomerization and makes the normally unreactive nitrogens of the urea reactive toward electrophiles. One of the nitrogens will react with the aldehyde to form an imine, and due to the availability of a quinoid resonance contributor, turn color (red in the case of dimethylaminocinnamaldehyde and yellow in the case of dimethylaminobenzaldehyde).

      What's special here, and why this won't result in a thousand false positives from detection of any urea-containing compound, is that urea nitrate is a stable salt and acidic enough on its own to react with dimethylaminocinnamaldehyde without the addition of acid. So a wipe test, drop it in isopropanol, add some of the aldehyde and see if it changes color. It's a fairly elegant application of old chemistry to forensic analysis.

    9. Re:Basic hygiene by rve · · Score: 3, Interesting

      The Birmingham six were convicted largely based on the result of such a test.

      http://en.wikipedia.org/wiki/Birmingham_Six/

      Indicator tests are nothing new by the way, and they're not inherently useless, as long as you realize that they tend to be non-specific, and usually react with a whole range of compounds. If you have a sample that you know may contain either substance A or B, and you know only substance B reacts with your color spray, then the reagent is a quick and reliable way to tell the difference.

      If on the other hand you start spraying it on people who may have been in contact with any number of substances, and then accuse anyone with a positive reaction of terrorism, innocent people are going to end up in jail.

    10. Re:Basic hygiene by kcelery · · Score: 3, Informative

      and catch a lot of farmers.

    11. Re:Basic hygiene by Anonymous Coward · · Score: 2, Funny
      Just don't be offended if I don't shake your hand buddy.

      He has a hand buddy? That's awesome. But yeah, I don't suggest you shake it.

    12. Re:Basic hygiene by bloobloo · · Score: 2, Funny

      Don't you think it's more likely to be used when you go through security? You don't get random people walking up to you in the airport and pulling out an x-ray machine, do you?

    13. Re:Basic hygiene by djasbestos · · Score: 2, Funny

      Damn, I knew I should not have submitted to a cavity search by an "undercover security officer".

  2. bomb makers or... by Jherico · · Score: 4, Insightful

    Bomb makers or maybe farmers who handle fertilizer? I don't envy being a false positive in Iraq.

    --

    Jherico

    What can the average user can do to ensure his security? "Nothing, you're screwed"

    1. Re:bomb makers or... by The+Living+Fractal · · Score: 2, Informative

      I believe said farmer would have to urinate on their hands after handling fertilizer, not wash, and actually probably need to vigorously rub their hands together until they were hot to generate a positive on this test.

      --
      I do not respond to cowards. Especially anonymous ones.
    2. Re:bomb makers or... by Osty · · Score: 4, Funny

      Washing them when you go is disgusting.

      No it's not. It's multi-tasking!

  3. great by Anonymous Coward · · Score: 2, Insightful

    zillion dollar spray defeated by less than a cent disposable rubber gloves.

  4. It's a good thing... by Anonymous Coward · · Score: 4, Insightful

    It's a good thing that terrorists never wash their hands.

  5. First silly string, now spray paint? by damn_registrars · · Score: 3, Funny

    I recall that troops in Iraq had already started using silly string to detect IED's. Now we're going to spray paint people to try to find who made the bombs? I'm waiting to see what 7-11 product shows up on the battlefeild next...

    --
    Damn_registrars has no butt-hole. Damn_registrars has no use for a butt-hole.
    1. Re:First silly string, now spray paint? by bishop32x · · Score: 2, Informative

      the silly string hangs of the trip wires, allowing them to bee seen easily without putting nough pressure on the wire to cause it to go off.

    2. Re:First silly string, now spray paint? by pintpusher · · Score: 5, Informative

      I believe it is used to detect tripwires. Silly string sprayed ahead of you will drape over tripwires without being heavy enough to trip them. makes sense to me anyway.

      --
      man, I feel like mold.
  6. Congratulation! by Daimanta · · Score: 5, Insightful

    Terrorists will now use gloves to make bombs. Innocent people will be falsely identified as being a terrorist.

    Mission accomplished!

    --
    Knowledge is power. Knowledge shared is power lost.
    1. Re:Congratulation! by sumdumass · · Score: 2, Insightful

      It will be on their shirts, or clothing from attempting to conceal it. Gloves won't hide the stuff either. If anything it would hid the person manufacturing it but then again a shower would do as much as gloves do.

      As for false positives, it isn't likely to be a problem. The stuff shows who the likely people are not who the person is. If you have a legitimate reason for the chemicals on you, you get to go. If you don't, then they look to see why you have it.

      It sounds like your pissed because they have found a way to track the people down after the fact and in some cases before the fact. Is that a bad thing for your or something? Would you prefer to just let them blow up innocent civilians unchallenged? Cause that's what happens, they kill more innocent civilians then military personnel.

    2. Re:Congratulation! by DaedalusHKX · · Score: 2, Insightful

      You don't think it will be used on American civilians sooner or later? Kicking doors in and oppressive military tactics have come back to roost, look at abusive SWAT and cops... tazer usage is going out of hand, being used in the western work to nail kids (when I was a kid we used to get our ears boxed, not blasted with a tazer, and it worked better).

      If you're an American, and you hang out at the range, and the local scumbags decide to make that illegal, suddenly, having gone plinking or hunting is a crime... and suddenly, practicing your own rights for your own pleasure, without harming a single other man or woman, can get you shot or raided by the local jack booted thugs, all because some spray sells you out.

      I can guarantee they won't catch a single damn terrorist. Terrorists aren't the targets. They spent too much money training the real ones to kill them now.

      --
      " What luck for rulers that men do not think" - Adolf Hitler
    3. Re:Congratulation! by sumdumass · · Score: 2, Insightful
      Don't you think you are blowing things out of portion?

      Swat doesn't get called unless there is a barricade, ongoing threat of life or hostage situation. Cities don't have swat teams on standby to assist at traffic stops. They have cops on patrol that come off patrol when the swat team is called. Sometimes they go back and get their gear and sometimes their gear is loaded on a truck waiting for them on the scene. Swat forces havn't been abused in over 50 years so what makes you all the suddent think they will now.

      And as for the tasering of kids, These are stupid untrained cops and yes, they need to be dealt with, but they aren't a big problem. You can name 3 or 4 instances out of how many police forces and university forces in the last 3 years where this shit has happened. It isn't a major problem, it isn't like all the cops all around the country are doing it. There are more unjustified police shootings then taserings going on in a year. What makes you think it is a big problem now?

      If you're an American, and you hang out at the range, and the local scumbags decide to make that illegal, suddenly, having gone plinking or hunting is a crime... and suddenly, practicing your own rights for your own pleasure, without harming a single other man or woman, can get you shot or raided by the local jack booted thugs, all because some spray sells you out.
      Listen to what you are saying. If you do something and they make it illegal, and then commit that illegal act, suddenly you can get hassled by the cops. So what, your doing something illegal. Now there are ways to contest unjust laws and unconstitutional laws. If you think the answer is to just violate the law instead of taking care of it properly, then you deserve what you get.

      I don't see this coming around as something like you describe either. Lie detector tests have been around for a while, you don't see people getting pulled over randomly to see if they broke a law and then attempt to pull which law out of them. You have DNA that can link people to a crime, I don't see people being DNA samples manditorily in case you ever commit a crime. In fact, there are a lot of things that could be used in much the same manor as you describe now that isn't being used in that way. So tell me, what makes you think this is any different?

      I can guarantee they won't catch a single damn terrorist. Terrorists aren't the targets. They spent too much money training the real ones to kill them now.
      Ok, Now I understand the problem. Well, wake up alice, this isn't wonderland. You live in the real world. And if what you just said is even remotely true, do you understand the amount of people that would have to be lieing to you in order to keep it secrete enough to be effective? I mean you would have to have everyone in the program keeping it a secrete, anyone in the government or military who comes across them keeping it a secrete, what would happen if just one of them told? The jig would be up. So maybe they kill them so they cannot tell, where are all the missing bodies? Why are the soldiers killing them right now and dieing from it too.

      You need to wake up and just take a small breath of common sense. It is practically impossible for your lala land to exist.
    4. Re:Congratulation! by sumdumass · · Score: 2, Insightful

      1 in 10,000 isn't that bad for a false positive rate. But the false positive isn't conclusive evidence to anything. It is just one more way or reason to look at someone. I would be more worried about what it missed and no one looked at because it didn't go off then I would about having someone delayed an extra 20 minutes for whatever reason.

      You do realize that your 1 in 10,000 rate would only be one or two false positives a day in an airport that sees 10s f thousands of people. But I don't think this is the target audience for the stuff so it shouldn't matter. It is going to be when they suspect someone, they could spray him just before letting them go. If it is a match, well, you know what that means, if it doesn't turn red, then they aren't going to go any further.

      The real application I think this might have, seeing how it works on guns being fired too, is that in a firefight situation where the suspects run into a building and ditch the guns to act like they don't know what it going on. In this case, a few squirts, and you have a number of people who would probably know more about it. Now, you see three people standing in the vicinity of a road side bomb that goes off when the first vehicle in your convoy goes by, You can pursue these people and squirt, squirt, you might find someone of interest.

      I don't think anyone it thinking this is a cure all. It is just one more tool in the box for detecting wrong doers before or after the fact. It may be used to strengthen other evidence or to justify letting someone go. I don't doubt that it can be abused, but I doubt it would be wide spread in the abuse. Especially when people eventually go free and complain.

  7. Hopefully, it is not a by davidsyes · · Score: 3, Funny

    piss-poor detector...

    (captcha: enrage)

    --
    Previously: "Linux... Toward the Sunrise..." Now: "Linux... Toward the-- No, now, part of Every Sunrise"
  8. That is why... by j.+andrew+rogers · · Score: 4, Insightful

    ...smart terrorists only use peroxide-based explosives (like the London subway bombing et al), oxidized halide based explosives (e.g. chlorate), and various other dirt cheap and ubiquitous explosives. While many of the most famous explosive chemistries might be subject to nitrate tests, the range of explosive chemistries that have been used at various times is far more diverse than nitrates. First World War mortar explosives are as dangerous today as they were back then, even if some of them do not contain nitrates.

    The fixation on the detection of nitrate and related chemistry is a bit of a blind spot in explosive detection technology.

  9. More Griess Test Nonsense by Anonymous Coward · · Score: 5, Informative

    In the UK, the Birmingham Six were falsely imprisoned for 16 years (one chap died in prison) largely because of the Griess test. The trouble is, anything nitrated will give a positive. The playing cards the men had been using on the train when they were arrested were probably what set it off. Ping pong balls certainly would. Imagine Forrest Gump in the Twenty First Century, "And then I met the President again, then they tasered me, then I went to prison for life." The Griess test is now completely discredited. Its re-introduction would be on a par with admitting polygraphs, or examining chickens' giblets as evidence, whether it's packaged as an aerosol or anything else.

  10. I am against this... by feepness · · Score: 5, Funny

    I think labeling people as terrorists because of their color is just wrong.

  11. Alternative use: Detecting IEDs themselves. by Ungrounded+Lightning · · Score: 4, Insightful

    I recall that troops in Iraq had already started using silly string to detect IED's.

    I wonder if a light spray of this stuff would make a hidden IED stand out as a bright red spot?

    And perhaps with red trails marking how it arrived and where the people who delivered it went when they left?

    --
    Bantam Dominique roosters crow a four-note song. Once you've heard it as "Happy BIRTHday" you can't NOT hear it that way
  12. You Know You've Read Slashdot Too Long... by Looshi · · Score: 5, Funny

    ...when your first thought is the effect on the rights of the bomb makers.

    1. Re:You Know You've Read Slashdot Too Long... by SMS_Design · · Score: 4, Insightful

      Sure, I'm concerned about the rights of bomb-makers. I, myself, made a few good ones when I was growing up out in the country. Mainly, though, I'm concerned about the rights of EVERY OTHER CITIZEN who will be needlessly harassed because of some bullshit test that will have 1000+ false positives for every actual bomb prevented.

  13. marking spin by drDugan · · Score: 3, Insightful

    someone got the marketing spin engine revving to 50K RPM today:

    "that can identify people suspected of making or planting bombs."

    Bullshit. Using the spray may detect a chemical, (not people) which then people may use to suspect one another.
    Big difference.

    1. Re:marking spin by E++99 · · Score: 2, Insightful

      "that can identify people suspected of making or planting bombs."

      Why would you even need a spray to identify people suspected of making or planting bombs? If they're already suspected, then surely you know which people you suspect! Why is precise writing so hard for professional writers??? How about this -- It identifies people who have been in recent contact with certain types of possible explosives residue.

  14. I like their other test... by argent · · Score: 2, Insightful

    The test for iron to tell if someone has handled a gun, or a grenade, or ... a wrench, or a wrought-iron railing, no?

  15. Re:ever since oklahoma city anyway by the+Jim+Bloke · · Score: 3, Informative

    Quote "When was the last time anyone heard about an ANFO bomb going off somewhere anyway?" Depending on the minesite, from once a week to twice a day. Ammonium Nitrate(urea) and Fuel Oil explosives are the backbone of the industrial explosives. There are legitimate uses for explosives, and legitimate uses for ammonium nitrate. A chemical sensor that detects firearm propellants would be more useful for finding criminals - except we are talking about the USA and its miltiary adventures anyway. Just because I work around explosives, and have a beard, does not make me a bomb hurling radical.

    --
    Big Brother watching us has got to be better than us having to watch Big Brother
  16. I'm just waiting by kiehlster · · Score: 2, Funny

    *sprays person's hands*
    Is it red? Is it red?
    Is it- BOOM!

  17. Re:Just another excuse by intothenight55 · · Score: 2, Interesting

    You have got to be kidding me!!! Laws are not made to oppress, but because we, I say WE have seen in the past where someone or something infringed on someone else's rights and caused harm to innocents... Laws are placed for that not to happen... In the free society you speak of I would be allowed to come over there and kick the hell out of you and expect no consequences, or purchase the high explosives that I want and create a crater of glass around you!! I'm not even saying you are wrong but the utopian society you speak of will never exist we need laws to keep control of the idiots down the road and prevent future crimes... I do however have a problem with you thinking that it is a miniscule threat, PEOPLE dieing is not very miniscule... the false positives are worth it... if it saves 15 or 20 American's lives it will be worth it.. You call this a "witch hunt" it's not a witch hunt it is a serious problem.

    Touchy subjects I know but worth a thought... Would you like to know that every postman could get their hands on high explosives? Could you imagine what would have happened if the kids in Columbine could have gotten their hands on high explosives?

  18. Heart medication by phorm · · Score: 2, Interesting

    I remember somebody I know telling me about how she was stopped and searched, etc at the airport because she had traces of nitro on her hands and in her purse. Now why would she have that? Well her husband used it as a medication for his bad heart.

    You'd be surprised at the rather harmless (explosion-wise anyways) uses many of these chemicals have, and I'm sure the airport guards may be as well. I've heard many cases of funky medications giving weird results in various situations. Did you know that taking a breathalizer test shortly after pumping ventalin (for asthma) will often result in a false positive?

    My friend heard this and decided to test it with a police officer (first by passing the test, then by puffing and taking it again). They were both quite surprised at how much it skewed the reading. The officer basically stated he'd never heard of such a thing, but he'd definitely keep it in mind and pass it along to others for future reference as in a situation where he had not watched her puff and taken the earlier reading my friend would have been on her way down to the station on DUI charges.

  19. Having RTFA, I'd worry anyway by Moraelin · · Score: 2, Informative

    Now before I get started, bear in mind that not only I'm not a chemist, but Chemistry is one of the things I understand the least. So major talking out the arse follows. If anyone who knows chemistry better wants to correct me, please do, it's very much appreciated.

    That said, looking at the illustration of the mollecules interacting in TFA, it looks to me like their dye binds to just the nitrate anion, and there is no trace of urea to be seen at all there. I.e., what is so funnily coloured is their mollecule after stealing a nitrate anion from _any_ nitrate whatsoever.

    It could be that other mollecules don't give their nitrate as gladly as urea nitrate, or whatever. Again, I don't know enough chemistry to rule that out.

    But unless I forgot chemistry completely, _any_ salt will split into a number of ions in a solution. Heck, even water doesn't stay H2O, a number of mollectules split into HO- and H3O+ ions. Ph 7 is basically just the equilibrium point for that mix.

    So basically even if you handled potassium nitrate for your orchids, or made a sandwich with ham cured with that (preservative E252 _is_ potassium nitrate), or just are a chain smoker (tobacco is quite commonly treated with it too), or made a model rocket recently, etc, etc, etc... you'll have plenty of nitrate anions on your skin for this thing to bind to. Heck, it's increasingly used in toothpaste too.

    And that's just one nitrate. Another common one that comes to mind is ammonium nitrate. Ok, so that one _can_ be used for an ANFO bomb, but is also used by the ton by farmers and even by miners.

    So I'm, you know, _curious_ what their miracle aerosol does in the presence of those. Did they spray it on a slice of cured ham and it _didn't_ turn purple, for example? Did they check it on ammonium nitrate too? On a pingpong ball? Basically which nitrates _does_ it react with, and which not? Because again, my uninformed interpretation of their drawing is that it would react with any nitrate whatsoever.

    --
    A polar bear is a cartesian bear after a coordinate transform.
  20. Now you don't need a bomb to cause disruption by Richard.D · · Score: 2, Insightful

    Go down to your local airport. Pick something that lots of people will handle, say the luggage trollies, or the paper towels in a bathroom, and sprinkle with urea nitrate. Leave before the avalanche of false positives at the security checks.

  21. Red Handed by morphiussys · · Score: 2, Funny

    ...And yet I have not heard anyone say anything about being caught red handed. :p

    (Although on that note, I did not scroll through ALL the responses for this story)