"Liquid Wood" a Contender To Replace Plastic
Ostracus recommends a Christian Science Monitor piece on the 40-year quest to find a replacement for non-biodegradable plastic. One candidate, written off 20 years back but now developed to the point of practicality, is a formulation based on the lignin found in wood. And it turns out there is another strong environmental reason to put lignin to use in this way: burning it, which is its common fate today, releases the carbon dioxide that trees had sequestered. "Almost 40 years ago, American scientists took their first steps in a quest to break the world's dependence on plastics. But in those four decades, plastic products have become so cheap and durable that not even the forces of nature seem able to stop them. A soupy expanse of plastic waste — too tough for bacteria to break down — now covers an estimated 1 million square miles of the Pacific Ocean. ...[R]esearchers started hunting for a substitute for plastic's main ingredient, petroleum. They wanted something renewable, biodegradable, and abundant enough to be inexpensive."
Is like calling ethanol "liquid grain." There's a big difference between being derived from a given substance and having the properties of that substance.
Not that this isn't nice and all, but picking science fiction-ish titles for things keeps you from being taken seriously.
Will this liquid wood be able to replace the vast number of different sorts of plastic we have today? There are some plastics with some fascinating properties out there, I'd like to imagine that we won't lose those properties forever when oil runs out..
Commodore64_love: I don't comprehend people who're so frightened of death that they'll bankrupt themselves to stay alive
"The lignin itself was misunderstood completely by [leaders in the field] and the majority of people," says Simo Sarkanen, an environmental science professor at the University of Minnesota.
Does that sound like a mad scientist to anyone else? "My research has been completely misunderstood, but I will change the world! And then they'll see! They'll pay for their ignorance! MUAHAHAHAHA!"
Those who advocate genocide deserve every protection afforded by law, and none afforded by common human decency.
Mr. McGuire: I want to say one word to you. Just one word. Benjamin: Yes, sir. Mr. McGuire: Are you listening? Benjamin: Yes, I am. Mr. McGuire: Lignin. Benjamin: Exactly how do you mean? Mr. McGuire: There's a great future in lignin. Think about it. Will you think about it?
With peak oil projected to come within a decade, and with prices accompanying the decline to make last year seem cheap, this can't come soon enough. Hopefully, they'll allow the growth of hemp to supply this.
transparent aluminum.
Where is Lenny you fuckers!?
I guess transparent wood comes before transparent aluminum.
Once upon a time, when woody plants first evolved, there was nothing that could break them down. As a result, dead trees piled up hundreds of feet deep all over the world until bacteria evolved that could finally eat the stuff. This went on for long enough to leave the huge amount of coal that is still buried today.
I would hope that some form of bacteria will develop the ability to eat various forms of plastic, as that's the only way that trash island is ever going away...
Plastic is a petroleum product. Can the conversion process be reversed? At what point does that million square miles of plastic gook start to look like a mine-able resource and not simply pollution? Certainly it could be recycled into new products, too.
--- Bwah?
I find it amusing that any time someone proposes using an alternative to petroleum-based products, that proposal always gets turned down and slammed for being more expensive, etc. than using petroleum...
...then we get back to petroleum products causing issues (environmental and economic)... and the cycle renews itself.
Curse you OPEC and the lobbyists you have in our elected government.
Up, Up, Down, Down, Left, Right, Left, Right, B, A, START
For the benefit of the curious reader, here's some more information on the Great Pacific Garbage Patch that you (and the summary) mention.
Okay, so we're going to grow trees to make "lignin plastic" and then the stuff is going into landfills where it will biodegrade and will release CO2. How is this better?
I don't have a dog,
You insensitive clod!
Plastic == sequestered carbon Wood == biodegradable == CO2, water, methane == greenhouse gases kdawson == moron
I suggest you read Slashdot
Great. The German's have successfully hidden their highly secretive and potentially Earth saving formula away from the masses and academia where it could be improved for over a decade. I'm for making a buck the same as the next guy, but when you come across something as important and the potential for widespread impact such as this you would think that your better half would take over and get the word out. Imagine if this little alternative plastic company joined forces with the largest paper producer in the US which provided it with an almost limitless supply of this ligin. That would drive the cost down and provide the volume necessary to make a legitimate impact on the market.
Why not use hemp plastics? Seems like a damn good idea to me.
http://www.mindfully.org/Plastic/Ocean/Ocean-Plastic-Landfill-Algalita1nov02.htm
It already exists
Don't we already have 'liquid wood'? Some people have been wearing rayon since the 70's....
I may be going out on limb, here, but I would not be surprised to discover that hemp is pretty good renewable source of lignin...
Didn't we have this (plastic made from wood) over a century ago?
It's called cellophane.
The Christian Right is Neither (Christian nor right). See: Matthew 23, Matthew 25, Ezekiel 16:48-50
He even has a name to match. Well... at least the second part.
Dr. Sarkanen sounds much better than Dr. Simo.
He does look like he fuckin hates us all for all those wood jokes all these years, though.
Mit der Dummheit kämpfen Götter selbst vergebens
It doesn't change the fact that they are over-felling in the first place... hardwood is extremely energy inefficient and requires toxins to process into paper. While it's good that they are actually recycling one of timbers by-products, but they are still ignoring other easier and more efficient (read: harder to monopolize)hardwood substitutes.
Hardwood is 20-40% cellulose while Hemp is over 70% cellulose.
If this isn't enough, consider the lifespan of hardwood vs. hemp. Hardwood takes tens of years to mature, while the turnaround for hemp is every few months. One acre of hemp produces as much usable material as SEVEN acres of timber.
In addition to paper, hemp can also be used to make biodegradable plastic and has been done for over 50 years. Why is the government so restrictive of a plant with so many clear benefits?
"A soupy expanse of plastic waste ... now covers an estimated 1 million square miles of the Pacific Ocean"
And exactly where is this million square miles? I've never seen it in any satellite photo. What are the Google Earth coordinates? And why would all of the plastic in the oceans flow to just one square area (and why not circular)? All sounds made up scaremongering to me!
Ping Pong Balls are made of celluloid. Plastic made from wood. What is old will be new again...
Excuse me, but please get off my Pennisetum Clandestinum, eh!
1 million sq miles is 1000 miles by 1000 miles.
seems exaggerated.
just shut up about units. that's 1600 x 1600 km.
You are right when you say lots of natural gas would be burned. Other misconceptions abound. What follows is very abbreviated. The cheap way to make paper is to cook it using the Kraft process. The wood gets chopped into small chunks and cooked in a liquor stew which separates the lignin from the nice fibers used for paper. The lignin holds the cells together and make the wood hard so the tree grows tall. Coming out of the stew the glop gets washed off the fibers. The chemicals used to cook the wood are expensive so the glop containing the lignin (which is bound to some of the chemicals) gets burned. The burning gets rid of the lignin carbohydrates and a stream of chemicals (called smelt) which runs out the bottom of the furnace, goes into a tank of water, comes out in a stream called green liquor, and eventually ends up going back into the cooking cycle. The heat from burning the lignin goes, as slarabee describes, into turbines to make electricity and steam for various purposes. Now, if you don't burn the lignin, you have to use some other source of energy to make that steam and electricity. Second, and the point the article misses completely, how are you going to separate the lignin from the chemicals? Those boilers in paper mills are called recovery boilers because they recover the chemicals. It's the cheapest way to do it. How is going to a more expensive method for chemical recovery and going to a more expensive fuel a good solution for anything? Lignin in a liquid wood would be better than plastic. The value of the liquid wood using lignin, though, would have to be high enough to overcome the above costs.
Plastic is a petroleum product. Can the conversion process be reversed?
This is what Global Resource Corporation's microwave does. Right now they are fine-tuning their prototype on used tires. One 20-pound tire yields 1 gallon of diesel oil, 50 cubic feet of propane/butane, some carbon black and some steel.
The device uses a vacuum chamber to reclaim the hydrocarbons after they've been released from the solid.
Learn the rules so you know how to break them properly.
www.teslabox.com
Lignin is actually a natural "plastic" - polymer - as I learned last year. It's a polymer with a ridiculously long molecular chain; I've wondered if that is what gives it its rigidity. If we can manage to re-purpose lignin as a replacement for synthetic hard plastics, that might ease the crash that is inevitably coming as petroleum becomes increasingly scarce.
Ummm... no. Ferns don't have seed pods. Ferns produce spores, which are far smaller than most seeds (orchid seeds perhaps being an exception).
I rather doubt your statement is true, that petroleum is comprised of nothing but decomposed fern spore. Could you please cite a reasonably authoritative source?
Any article that doesn't mention overpopulation should not be allowed to present itself as any sort of solution to environmental problems.
Been there, done that, got the t-shirt.
Global warming is a leftist scam to prevent the development of liberal democracies and free markets in the 3rd world by retarding their economic and industrial growth.
The 3rd world and all of its problems represent the last possible hope for the left to remake the world into a communist dsytopia. If 3rd world countries are transformed into wealthy nations with political and economic freedom, there will be no one left to sell communism to other than wet-behind-the-ears college students, most of whom outgrow it.
The swindle of global warming is a scam to keep people in impoverished countries poor.
It's all about making the world safe for communism.
Muslim community leaders warn of backlash from tomorrow morning's terrorist attack.
WTH? Why can't people come up with something we haven't tried already? pffft...
It would take all the trees in the world to replace plastic. but thanks for thinking of the environment. Asshole
As the article carefully states, even Arboform uses only 50% lignin (yes, I *did* RTFA). The rest is made up of rather expensive "additives" - one crucial ingredient being Ecoflex, a synthetic (= oil-based) polymer which is needed to reduce the extreme brittleness of genuine lignin.
Two hopes spelled out in the articles will never materialize:
- it will never be as cheap as oil-based plastics are today, and
- it will never be able to replace most of the current oil-based plastics due to it's poor mechanical properties (unless we reduce the lignin content even further).
You know it's time for the next revolution when your rulers' names end with roman numerals.
A soupy expanse of plastic waste â" too tough for bacteria to break down
Eh! Give them time. Some bacterium will evolve in time and will be able to eat the thing, and you'll really know the meaning of population explosion. Or, just as likely, God knew beforehand that plastics were in our future and surely preordained some strains of bacteria to be able to eat them. They are just too well-mannered to start eating before the rest do, or something.
In the early days - 7 plants were named and shown to be excellent oil sources.
And these oil sources can be combined with a hardener to become a "plastic"
Soy oil was one of the first.
George Overley was the chemist working for Henry Ford to create many plant based components for Ford cars and trucks. Around 30 different components were plant based until Henry Ford was kicked out of the company he started.
The most famous is the Soy plastic bumpers that are mostly mistaken as Hemp Plastic by Jack Herrer in
"The Emperor Wears No Cloths"
Synthetic Genomics aims to replace the petrochemical industry. Next goal: replace the plastic industry? Or at least "eat" our old plastic waste problem and turn it into something useful.
Although lingin-based plastics may be something new, bioplastics are by no means new.
By pure and honest coincidence, I have a disposable cup made out of a plant-based bioplastic sitting on my desk that I got from a restaurant along with some take-out earlier today.
It's virtually indistinguishable from a normal plastic cup, and actually looks a bit nicer than your typical disposable drinkware -- the crystal-clear bioplastic is sturdy and has a nice 'shine' to it. It's biodegradable, and contains no oil-based inputs, although you'd never guess it by looking at it or handling it.
The manufacturers of the biopolymer claim that it can be adapted to all sorts of other products, at what seem to be fairly reasonable prices (~$1/kg). What's not to love?
-- If you try to fail and succeed, which have you done? - Uli's moose
This is a report on that area, and what's exactly what they mean by this "garbage patch" thing. It's scary, and it makes sense.
Just breed a bacteria capable of eating all the plastic, it probably won't backfire on us!
Pyrolysis.
You pyrolyse the crap and bury the resulting char in your fields.
It's just cheaper to bury it. However the oil's running out so that'll all change.
Deleted
The rest of the world has to buy US dollars in order to buy oil. America is paid for every barrel of oil which is sold across the world. (Ask the Saudis exactly why that might be the case)
That is why the status quo isn't changing any time soon.
Deleted
Isn't there already biodegradeable plastics made from hemp seed oil? Using hemp seed oil would be a drastic improvement over using wood considering yeild per acre.
Time makes more converts than reason
Or at least were. During the Devonian period these plants spread rapidly across the land and created the first forests.
However I don't know of any source that claims that these seed pods are the primary constituent of coal.
First of all the largest bulk of ancient coal deposits were laid down during the Carboniferous period, which followed the Devonian. These periods are all 10's of millions of years long and certainly bacteria evolved to eat lignin on a shorter time scale than that. In fact it is actually fungus that do most of the eating of wood anyway.
It is also not true that coal was only formed in one or a few specific geological periods. There are coal deposits which formed in every period from the Devonian on through to relatively recent periods in the Cenozoic Era. LOTS of coal formed in the Carboniferous and a lot of it is now high quality coal.
And anyone that has seen what sorts of stuff is in coal deposits will know that the vast majority of it was all sorts of different plant materials. There are leaves, trunks, roots, branches, etc all in the coal and in some places there are whole FORESTS turned to coal where all this stuff is still quite plainly visible. So maybe fern seed pods are a decent part of that, I don't know, but it is a lot more complex than that and even a modern forest could turn to coal in the right conditions.
"Malo periculosam, libertatem quam quietam servitutem." -- Jefferson
It's safe for the environment. This deserves some advanced research just on that point alone.
I don't suppose you would mind me dousing the interior of your car with gasoline? It's fuel, right?
Idiot.
What's wrong with aluminum? I like aluminum.
Hate to say this out loud. Last I looked in an industrial chemistry book I have here, lignin looked like a long chain of toluene and xylene with a few side branches. My first thought was 108 octane fuel so I could run higher compression in my car and get better efficiency -- carbon neutral at that since the carbon in the lignin came out of the air in the first place. Split up that puppy and all sorts of handy semi-orgainic chemicals come out, plastic precursors just being a single one of them. The deal would be to find buyers for all of them so no waste accumulates at your plant, as is fairly common in the chemical business. Just that no one is doing this with lignin. Burning it as is is a nightmare, as this molecule as is doesn't burn clean at all.
I've seen this soup in Bali. It's millions of plastic bags used to hold tea that are then disposed of in the gutter, then flushed out of the drains in wet season. Fully disgusting. What better method of disposal will solve that problem... a bin? Don't assume this is plastic coming from the developed world where developed world solutions can be applied.
My orange juice comes in plastic-like bottles made of corn. Who needs this shite?
Hemp is a great source of lignin. Needs no pesticide, no fertilizer, and grows faster than almost any other plant.
No need to chop any further trees for paper or anything else besides wood beams.
The Evolution of Biodegradable Plastic
Biodegradable plastic is plastic that biodegrades into humus when disposed of, due to the action of the micro-organisms that turn dead plant life into humus, the organic part of soil. The result is a rich and fertile soil.
There have been three generatons of biodegradable plastic. The first was starch based plastic, PLA, almost always made out of corn. The second generation was oxo-biodegradable conventional plastic, and the third, the current generation, is biodegradable conventional plastic.
PLA, or corn-based plastic
PLA, or corn-based plastic, was the first generation of biodegradable plastic. It is still made and promoted by corporate giants that have huge financial and political power, such as the Dow Chemical Company, Cargill, Inc., and Archer Daniel Midlands, but it has many drawbacks.
It is billed as 'sustainable,' as it is based on food sources, primarily corn. However, if all of the disposable plastic products in the world were made out of corn, 150,000,000 tons of corn would be used to make plastic. Prices for corn would rise dramatically, and third world hunger would increase even more dramatically. There are currently 850,000,000 hungry people in the third world. If we imagine that condition worsening greatly, the result could only be a humanitarian catastrophe of appalling proportions. That is the real ramification of 'sustainability' in today's world.
Furthermore, PLA isn't a very good plastic. It imparts an off taste to water when used for water bottles, it melts when used as soup spoons, it's weak, and therefore items made of it are heavy, it has a short shelf life, and it often starts to decay before use, while still on the shelf. What's more, almost no recyclers accept it for recycling. In fact, recyclers dislike PLA and are trying to ban it, because it gets confused with more conventional plastics, and ruins their recycled plastic batches.
The state of California is promoting this product by limiting the use of the term biodegradable, and all synonyms for biodegradablilty to PLA, which decays within 120 days in commercial (not home) composting facilities. Unfortunately PLA decays so fast in an oxygen-free (anaerobic) environment (typical of landfills,) that it generates methane in landfills before they are capped to tap the methane. Generating methane quickly in landfills is undesirable because it is a potent greenhouse gas. If it is generated before the landfill is capped, it outgasses into the atmosphere, promoting global warming. (Click to see video about using methane from landfills.)
Oxo-Biodegradable Plastic, the Second Generation of Biodegradable Plastic
The second generation plastic oxo-biodegradable plastic was very different than the the previous generation of biodegradable plastic called PLA, starch-based plastic, or 'spudware. Oxo-biodegradable plastic had many advantages over PLA-It was invulnerable to water, one might adjust it to the desired biodegradation rate, some products could contain recycled content, it could be recycled, it didn't diminish the grain supply, it was stronger, less expensive, and was made from an otherwise useless industrial byproduct, naphtha.
This second-generation biodegradable plastic is little known in the US, but is is well established and widely used in Europe. Tesco and Carrefours, the largest grocery chains in the world, and in France, respectively, package their customers' groceries in oxo-biodegradable 't-shirt' bags. In fact, the largest bakers in Mexico and South Africa package bread in oxo-biodegradable bags, and oxo-biodegradable plastic is becoming common in India and China. The US is so far behind the curve on this, that it is a little embarassing.
Oxo-biodegradable plastic doesn't biodegrade when deeply buried in landfills, because it requires an initial phase of degeneration which required certain environmental factors-oxygen and one of the following three circumstances-heat, UV light, or mechanical stress-and because the subsequent biode