Graphene Membranes Superpermeable to Water
Dr Max writes "Not only is graphene the strongest, thinnest and best conducting material known to man, it is now shown to have superpermeability with respect to water as well. This allows a membrane made with graphene to pass water right through it (PDF), while another atom or molecule (even helium) gets blocked. 'The properties are so unusual that it is hard to imagine that they cannot find some use in the design of filtration, separation or barrier membranes and for selective removal of water,' said one of the researchers."
...you don't need a pressure source like you do for reverse osmosis?
Would be quite expensive, but letting water go thru and nothing else would save millons in remediation.
Possibly a new way to collect oil spills no? Interesting potential.
Now we know what the water receptacles in Dune were made of.
Press and squeeze a hydraulic press of water through a few layers of graphene = no more salty water?
So you could pass thru i.e. ocean or contaminated water and get fresh, drinkable, pure water on the other side? If that could scale could be great.
But can it be used as a dessert topping?
http://alternatives.rzero.com/
It's not mentioned in the opener, but the article says it lets water "evaporate" through it.
So it's not like you can just pour water on it, and let it drip through.
I wonder if this just means steam can pass through it, or if it has to evaporate on the graphene for it to get through?
If it was the former, then why are they wording it so complicated?
The material they used was NOT graphene. It was graphene oxide.
graphene-based membranes are impermeable to all gases and liquids (vacuum-tight). However, water evaporates through them as quickly as if the membranes were not there at all.
Thanks for clarifying that. Anyway, this is a very amazing material.
that is all
Something bad is coming when people are suddenly anxious to tell the truth.
"Like wearing nothing at all"...
Lets all the delicious moisture through, blocks the stuff you want blocked???
Super still anybody :) ? I can see it now: BATF busts graphene lab in remote Kentucky hills. Moonshine operation shutdown.
I am writing patent applications for this material as we speak. Remember that thanks to our wise politicians it's who files first that counts, not who actually spent time and money inventing it.
What about the Water Memory? Does this membrane erase all this information or is a there a mechanism to determine which information to be deleted? Would be an invaluable Material for all that homeopathy stuff...
hey, this material is good to make a boat!
If it blocks Helium this has very important applications.
Helium molecules are very small. It is difficult to contain Helium gas in cylinders.
There are even far more important applications for the global economy. It may finally be possible to make Helium balloons that don't leak the tiny molecules so quickly.
I'll see your senator, and I'll raise you two judges.
So if people can make exotic materials like graphene, why can't my doctor make my low back pain go away?
Sorry, but gray text on gray background is making my eyes bleed.
My kids' diapers.
Have gnu, will travel.
Last pdf page:
The fact that the water fills the 2D channel even under a negative pressure in the left reservoir indicates [...]
I understand that sometime negative pressure means lower pressure than global/ambiant pressure.
But here in this 2D atomistic simulation I don't know what they mean.
From TFA:
However, Professor Geim adds ‘The properties are so unusual that it is hard to imagine that they cannot find some use in the design of filtration, separation or barrier membranes and for selective removal of water’.
Now we have the perfect material with which to make stillsuits! Frank Herbert would shed a tear if he were alive.
OK, they have a bottle of vodka, and it's sealed with this. As the days go by, it gets stronger and stronger.
But when a water molecule leaves the bottle, the number of molecules in the bottle gets smaller, and thus the pressure in the bottle decreases. Why would the next molecule leave? There's pressure pushing it back in.
If things worked the way they said, they would have to either keep opening the bottle, over and over during the day, or they heated the bottle, or there is something passing back into the bottle to replace the lost water molecules.
What am I missing?
If this process were used in bootlegging, it would eliminate the still's heat signature. It would eliminate the still's distinctive sound. It might make it economical for many people to have their home stills in their garages. I see governmental regulation soon.
I don't really know, but I'd suspect that it has something to do with like,electrical charge or something, not size - e.g. they're both small enough to fit through, but the helium experiences some sort of repulsive force which the water does not as it passes through the field created by the graphene.
Chlorine prevents pathogens from setting up shop in your tap water. Fluoride keeps your teeth from falling out. They wouldn't spend $$$ putting additives in the water if they didn't have a good reason. Besides, last I checked, the bigwigs in DC drink the same water.
Is this useful for cooling my superfast graphene processors?
http://www.bbc.co.uk/news/science-environment-16747208 - at least the beeb has a better use - ...
Miracle material graphene can distil booze, says study
who where what when now?
Exactly ...
I recall a warning I saw last year about giving infants water instead of formula - especially purified water. They referred to it as water poisoning (which would seem to me a misleading term, but I don't get to choose these things).
So it is a valid consideration for those who never eat food ...
In Ring TFA, it only allows water molecules to evaporate - the research says nothing about h20 in liquid state.
One of the problems with a "hydrogen economy" is storage as hydrogen leaks out of pretty much everything.
Wonder how well this blocks it.
When Fascism comes to America, it will call itself Anti-Fascism, and tell you to give up your guns.
Ah, graphene. Is there anything it CAN'T do? (other than pass a spell checker)
Gaseous helium difuses through pretty much everything. These graphene membranes should have truly amazing properties.
Armies of physicists will work years to explain such remarkable phenomenons. Neutrinos light than faster like just.
the articles, including the scientific abstract in the original paper on arXiv, are grossly misleading.
first, they are not talking about permeation through a membrane, if you consider a membrane as a single sheet. they are talking about multiple staggered, overlapping layers of separate sheets.
second, as another poster noted, it is graphene oxide, not graphene.
it works like this: water wets graphene oxide. stacked sheets of graphene oxide permit water to intercalate and transport along the sheet planes, as if they were capillaries. stuff that is not sufficiently polar and hydrogen bonding (helium, etc) does not do this. the water travels parallel to the planes, and if the planes are staggered plates, the net direction of the water may be perpendicular to the planes (the water travels along the planes till it finds an edge it can go around). see FIG 1C in the arxiv PDF linked in the summary.
this is still pretty cool observation, just terrible presentation.
I swear, if I didn't know better I'd be willing to call graphene an elaborate prank at this point. Groups of scientists trying to one up each other over what this thing can do. Two months before it can transmute gold? :P
by Anonymous Coward: I, for one, welcome the shift from car analogies to pizza analogies. um.. overlords?
I can see the next Discovery Channel Moonshiners show now:
Tickle!!! Get the graphene filter ready for this mash!!!
You're right, but details are needed.
Water intoxication can happen with either tap water or ultrapure water.
If you add hydration you need to add electrolytes or your system goes out of balance. Your body can handle only so much imbalance. As it goes too far out of whack, that's effectively water intoxication.
Drinking a glass of ultrapure probably won't hurt you, nor a glass of tap. But have a bunch of either in a short period and you will have a problem. Read the Wikipedia water intoxication article's "notable cases" section to get an idea of how much humans can handle.
Hm... When hydrogens separate from oxygens, do they always take their original electron back? Or are we getting a random one out of the, say, two valence electrons the molecule was using previously? If we're possibly getting a different electron, isn't there a constant swap going on in the universe, for perhaps all covalent molecular configuration changes?
That is, atoms reform constantly?
So, the hydrogen and oxygen atoms that make up water could themselves be relatively fresh.
Well this is all nice and fine but.. Garphene is just one atom thick. Can you actualy prodeuce any larger quamtity today for filters or is it to brittle for any application outside a lab?
This could be the solution for the world's freshwater problems and they frame it as a new distillery technique. Bottoms up, U Manchester!
Or maybe the super polypro. I'm looking forward to my first pair of graphene underwear.
using the World Community Grid virtual super computer. www.worldcommunitygrid.org
... to Maxwell's Demon.
I think I have the solution for 'why water can pass through but helium [smaller] not': the water is not passing through at all. It's graphene hydroxide/oxide, after all... the hydroxyl radical from the membrane steals a H 'cation' from a water molecule, an electron from graphene proper and deattaches itself, forming a new molecule. The 'old' water molecule, now a OH radical, attaches itself at the graphene yielding an electron in the way.
The thing is, the 'new' molecule has 50% odds of being at any side of the graphene layer. If you have lots of water in one side but none in the other, it'll looks like the water is passing through.
This would explain why helium cannot pass - it's smaller than a water molecule, but far, FAR BIGGER than a H (H = a proton alone). The OH radical attached to the membrane can rearrange itself to either side of the membrane easily, since it's bonded to the layer, allowing the process to continue.
TL; DR: The water isn't passing through, it's being broken and recombined at the other side.
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eventually one side will heat up relative to the other and at some critical temperature the pump/motor will "run backwards"..
i believe richard feynman discusses such a machine; the one he describes is basically a ratchet attached to lever in turn attached to a vane. as the random motion on the vane winds the ratchet it heats up transferring energy from the heat of the gasses jostling the vane into rotational motion, but eventually the ratchet heats up so much that the tooth stopping it from winding backwards jumps often enough than it actually goes backwards due to the momentum of the peg hitting the toothed wheel of the ratchet.
fascinating. feynman also mentioned this would apply to any "equivalent" apparatus.
Please pardon my stupidity, but isn't the size of H2O molecule larger than that of Helium?
Muchas Gracias, Señor Edward Snowden !