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New Process Takes Energy From Coal Without Burning It

rtoz writes "Ohio State students have come up with a scaled-down version of a power plant combustion system with a unique experimental design--one that chemically converts coal to heat while capturing 99 percent of the carbon dioxide produced in the reaction. Typical coal-fired power plants burn coal to heat water to make steam, which turns the turbines that produce electricity. In chemical looping, the coal isn't burned with fire, but instead chemically combusted in a sealed chamber so that it doesn't pollute the air. This new technology, called coal-direct chemical looping, was pioneered by Liang-Shih Fan, professor of chemical and biomolecular engineering and director of Ohio State's Clean Coal Research Laboratory."

365 comments

  1. Scaling is the Key! by Irate+Engineer · · Score: 4, Insightful

    Sounds nice, except for the 'combusted in a sealed chamber' bit. How is this going to scale up so they can feed 100 tons/hr through the plant cycle? That is the question.

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    1. Re:Scaling is the Key! by Spy+Handler · · Score: 5, Interesting

      just build it bigger!

      Or if that can't be done economically, just build millions of little ones!

      Oh that's not economically feasible either because each one requires a lot of labor to build? Hmm.... *thinks*

      Ok let's just forget about the whole thing and go nuclear.

    2. Re:Scaling is the Key! by vidnet · · Score: 4, Interesting

      The part that worried me was more the fact that CO2 was still produced, it was just contained within the chamber (the benefit of their technique seemed to just be less/no air space required in the chamber).

      Sequestering CO2 is not simple, and is currently done mostly by pumping it into used oil fields. It's not certain whether these costs were factored in.

    3. Re:Scaling is the Key! by Anonymous Coward · · Score: 1, Insightful

      I don't necessarily agree with scaling anymore. At least, scaling to the size of modern power plants. I'd rather we have MANY MANY smaller power plants scattered around than the larger ones we currently integrate.

      As this is chemical, and not combustion, (yes yes, sealed chamber...) it should not take up as nearly as much land as required by current plants. Also, just think of all the job creation all those small power plants will require!!!

    4. Re:Scaling is the Key! by MBCook · · Score: 4, Interesting

      Coal is 84% carbon, 10% oxygen, 4% hydrogen, and 2% nitrogen (or so). Short of nuclear fission or fusion, you're going to get carbon and oxygen out of it no matter what you do.

      The question is how much energy you get out. If this process were twice as efficient (in terms of CO2 per MW) then it would still be a worthwhile improvement wouldn't it?

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    5. Re:Scaling is the Key! by c0lo · · Score: 0

      Oh that's not economically feasible either because each one requires a lot of labor to build? Hmm.... *thinks*

      That's a so simple one you don't need to be an engineer, even a CEO can answer to that: buy or build a plant into a lower wages country.

      (grin)

      --
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    6. Re:Scaling is the Key! by icebike · · Score: 3, Informative

      Sounds nice, except for the 'combusted in a sealed chamber' bit. How is this going to scale up so they can feed 100 tons/hr through the plant cycle? That is the question.

      The key to the technology is the use of tiny metal beads to carry oxygen to the fuel to spur the chemical reaction. For CDCL, the fuel is coal that’s been ground into a powder, and the metal beads are made of iron oxide composites. The coal particles are about 100 micrometers across—about the diameter of a human hair—and the iron beads are larger, about 1.5-2 millimeters across. Chung likened the two different sizes to talcum powder and ice cream sprinkles, though the mix is not nearly so colorful.

      The coal and iron oxide are heated to high temperatures, where the materials react with each other. Carbon from the coal binds with the oxygen from the iron oxide and creates carbon dioxide, which rises into a chamber where it is captured.

      They ran this for 9 days straight. They only stopped because they were tired. Scaling it up probably is not that much of a problem.
      The bigger problem might be obtaining both the fuel and the oxidizers in quantity economically.

      Coal powered that finely would be rather dangerous, because it has so much surface area. Exposure to air, any spark could set it
      off. Handling it would require special care never to let it flow around or accumulate around the crushers. They might have to
      make it in a slurry just for safety, then waste more heat drying it before use.

      TFA shows them handling bottles of it, and even then they are wearing masks.

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    7. Re:Scaling is the Key! by Charliemopps · · Score: 1

      This is the kind of science that will save us from Global warming. I know how grand Solar and wind seem grand, but they aren't powering shit yet. Germany is the shining start of renewable energy right now, and they have 20 old school coal fired plants scheduled to be built in the next few decades. We have a LOT of coal. If there's a clean way to use it, we sure as hell better try. It's going to get used one way or another, and 99% efficiency with easy CO2 sequester seems like a pretty smart way to do it.

    8. Re:Scaling is the Key! by toejam13 · · Score: 3, Informative

      It isn't expensive when all of the senators and representatives from coal burning states insert major tax credits (read: corporate welfare) into bills to pay for such boondoggles. Eventually, such things get passed and we all pay for it.

      You should read up on how the federal government subsidies coal liquefaction. It is a complete and total scam.

    9. Re:Scaling is the Key! by Irate+Engineer · · Score: 2

      Coal is routinely pulverized in order to get it to flow with preheated air through the burners and to provide a large surface area to volume ratio for efficient heating and combustion. 100 micrometers is 0.1 mm, small but not microscopic. This is a typical grain size produced by the pulverizer mills.

      You really don't want any sort of small powder to get in your lungs. Coal is not particularly dangerous.

      Coal contains small amounts of mercury, but not much more so than most other natural ores. The problem with mercury in coal is that we are burning coal that took millions of years to accumulate in the space of a few centuries, so it releases mercury back into the environment faster than nature can sequester it.

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    10. Re:Scaling is the Key! by Anonymous Coward · · Score: 5, Funny

      Maybe we should start burning C-level executives instead of coal.

    11. Re:Scaling is the Key! by trout007 · · Score: 4, Informative

      You are forgetting the other part of the reaction. Air is 78% Nitrogen and 21% Oxygen. In this reaction the Iron removes the Oxygen from the air before it gets into the reactor. So no Nitrogen in the reactor means NOx and no Nitrogen gas to remove from the waste stream.

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    12. Re:Scaling is the Key! by icebike · · Score: 5, Interesting

      Sequestering CO2 is not simple, and is currently done mostly by pumping it into used oil fields. It's not certain whether these costs were factored in.

      Sequestering it is a lot simpler if you can simply draw if off the top of the CLOSED chamber rather than trying to scrub it out of the stack.
      You've got half the battle won already.

      What to do with it long term is another problem. But its a problem you would have anyway, so having the CO2 handed to you all
      contained is better than where we are today.

      Besides coal ash, it appears CO2 is the only by-produce that is not recycled back into the feed-stock.

      But, hey, Clean Coal stories have to be knocked down immediately. We can't have it prove even partially successful under any
      circumstance. /rollseyes.

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    13. Re:Scaling is the Key! by gandhi_2 · · Score: 1

      Pipebomb scalability is limited only by your imagination and supplies on hand.

    14. Re:Scaling is the Key! by Anonymous Coward · · Score: 0, Flamebait

      Your hatred is a compelling argument. You are an amazing person with much to contribute to the world.

    15. Re:Scaling is the Key! by Irate+Engineer · · Score: 4, Interesting

      This is the kind of science that will save us from Global warming. I know how grand Solar and wind seem grand, but they aren't powering shit yet.

      Wind is powering all sorts of "shit" in Europe. Denmark is pushing about 28% penetration of wind into their power market and many of the surrounding countries have penetrations of 10-20%. And they are building a hell of a lot of offshore wind farms.

      Just because the U.S. is slow to get off its ass doesn't mean the rest of the world is.

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    16. Re:Scaling is the Key! by Charliemopps · · Score: 3, Informative

      Sequestering CO2 is easy. You just don't have a clue how it works. The CO2 is pumped into abandon oil fields at VERY high pressures. This actually results in a return of the field to oil production, as the CO2 forces out more oil. The hydrostatic pressure at that depth is so great that it forces the CO2 into its liquid form. It's not going to suddenly escape to the surfaces, it's miles down and under unfathomable pressure. If we had an earthquake strong enough to crack that, we'd have far more to worry about. Like the really nasty gasses getting released from natural fissures or the earth splitting asunder.

    17. Re:Scaling is the Key! by hairyfeet · · Score: 4, Insightful

      No matter how you slice it you're still left with an assload of carbon that has to go SOMEWHERE so what are you gonna do with it? Frankly that's always been the problem, what to do with all the waste that is left over. TFA I notice is awful light on the details about what EXACTLY if left after this chemical burning, is it a paste, a gel, powder, maybe i missed it but I couldn't find any clear answer on that.

      But at the end of the day that is still hundreds of tons of waste you are gonna have to put somewhere, the big question is where because as we saw with Yucca flats pretty much any place you pick is gonna have NIMBYs coming out the woodwork so what are you gonna do with it? This is why I've always supported the new nuclear reactors with reprocessing, it lets you re-use as much as possible until the waste is much smaller and has a much lower half life but no matter how you slice it the stuff left over is gonna have to be put somewhere.

      But like coal or hate it we are gonna end up having to use at least some of it because our power needs have gone nowhere but up and this at least sounds like the waste is in solid form instead of gas which will make handling and disposal easier, if not politically then at least physically.

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    18. Re:Scaling is the Key! by r0xtarninja · · Score: 2

      Sequestering = storage. That "other problem" you speak of is what gp was referring to. But pedantry aside, tech like this, gasification and other clean coal plans do solve some pieces of the clean energy puzzle and shouldn't be simply cast aside with a flippant "clean coal lol" comment.

    19. Re:Scaling is the Key! by tsotha · · Score: 4, Funny

      TFA I notice is awful light on the details about what EXACTLY if left after this chemical burning, is it a paste, a gel, powder, maybe i missed it but I couldn't find any clear answer on that.

      Maybe it's diamonds. Boy, are those Belgian airport thieves going to be pissed.

    20. Re:Scaling is the Key! by AHuxley · · Score: 1

      Re: scale up so they can feed 100 tons/hr through the plant cycle?
      Sure they can, South Africa did it http://www.netl.doe.gov/technologies/coalpower/gasification/gasifipedia/6-apps/6-3-5-1_sasol.html
      Everything old is new again- 'green' is paying out to the private sector like a state under sanctions :)
      The US has had local tech to clean coal releasing only CO2 and water at a fair market price but does seem committed to replacing its old generation capacity :(
      What is left on the grid will be very costly :) Expect cuts to supply too as regions are dropped for areas that can pay more :)

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    21. Re:Scaling is the Key! by Nethemas+the+Great · · Score: 1

      It seems to me that sequestering CO2 is exceedingly similar to spent nuclear fuel storage. It's all fine and good until something goes wrong, then it goes terribly wrong. Until we can do something useful with the CO2 I really don't see these kinds of technology doing anything miraculous for us. It's just another form of hazardous waste that can do all manner of harm should it breach containment.

      --
      Two of my imaginary friends reproduced once ... with negative results.
    22. Re:Scaling is the Key! by ATMAvatar · · Score: 5, Funny

      It wouldn't work, anyways. Bullshit has a lower energy density than coal.

      --
      "They that can give up essential liberty to obtain a little temporary safety deserve neither liberty nor safety."
    23. Re:Scaling is the Key! by dbIII · · Score: 2

      I used to think it was bullshit but it turns out it's been used as a technique to recover more oil for many years before anyone thought of using it for carbon dioxide storage.

    24. Re:Scaling is the Key! by multimediavt · · Score: 5, Informative

      Coal powered that finely would be rather dangerous, because it has so much surface area. Exposure to air, any spark could set it off.

      Uh, yoohoo, over here! They already use coal dust in existing coal burning power plants. I think they have the processing handling issues down for that bit. And, there hasn't been a major coal dust accident since 1962.

      BTW, for those that trashed my 'we need to stop burning stuff' comments regarding how we generate energy. THIS is exactly what I meant. Applause for the researchers. If this does scale and proves out, they should get a Nobel for it!

      'Nuf said.

    25. Re:Scaling is the Key! by dbIII · · Score: 1

      I know how grand Solar and wind seem grand, but they aren't powering shit yet

      China imported more windmills last year than the USA has in total. They may also be making some of their own as well. There's more to power generation than big baseload coal units and wind, solar etc is really competing against the little gas turbines and diesel generators that don't provide power as cheap per MW as coal or hydro.

    26. Re:Scaling is the Key! by jd2112 · · Score: 4, Funny

      It wouldn't work, anyways. Bullshit has a lower energy density than coal.

      But coal is a finite resource. Washington DC alone proves there is an unlimited supply of bullshit.

      --
      Any insufficiently advanced magic is indistinguishable from technology.
    27. Re:Scaling is the Key! by aaarrrgggh · · Score: 1

      Combustion in a sealed chamber of an engine piston seems to work pretty well. Kind of like an air lock...

    28. Re:Scaling is the Key! by The+Mighty+Buzzard · · Score: 0

      True but there's a nearly infinite supply of it coming from Washington alone.

      --
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    29. Re:Scaling is the Key! by hairyfeet · · Score: 3, Insightful

      You joke but there is a reason why China is gonna have 25 new nuclear reactors up and running before we get a single one out of committee and that is because no matter what you propose the NIMBYs will try to cock block. Wind? "It'll spoil our view and kill the birds!" Hydro? "It'll run the flow and hurt the fishies!" No matter what tech you use the NIMBYs will come out and try to cock block you here.

      So I doubt even being made in Ohio with Ohio coal will help, the NIMBYs will come try and cock block anything being built there. I swear listening to the NIMBYs you'd think the power fairy was gonna provide our needs, because they sure as fuck don't want a single thing built.

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    30. Re:Scaling is the Key! by Michael+Woodhams · · Score: 1

      You need to sequester the CO2, else this technology has no point. Possibly the need for suitable geology or the cost of drilling a pipe to the suitable geology might dictate large scale facilities - I don't know. Transportation of coal to the plant might also mean only a few locations with the correct geology are suitable.

      --
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    31. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      Solar is powering my home, and it was a one time cost. Well, there was a little cost in changing over to LED lights, a laptop, and other low power appliances (A refrigerator that uses cold outside air in the winter...what a concept). If every new house had to have 5% of the value of it as electrical generation and/or geo-thermal, it would go a very long way to eliminating power plants. And fewer jobs, and less taxes...so that is what the real tea party should be after. But, nope, they want their dirty energy or R&D funding and handouts to the oil and gas companies to keep people addicted to paying a monthly bill for the rest of their lives, just so they can have other people pay for it or wait until they are dead to have the big bill come due.

    32. Re:Scaling is the Key! by foniksonik · · Score: 1

      Yes but then you have to transport the coal fuel stock to all of these small plants. That could eat up a large amount of the new efficiency. Nice thought though.

      --
      A fool throws a stone into a well and a thousand sages can not remove it.
    33. Re:Scaling is the Key! by dywolf · · Score: 1

      the question is power output.
      the article didnt even touch on that little datum.

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    34. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      Better yet, household generators with an auto-feed system from a container of fuel of some kind. To be refilled much like you'd refill an oil tank in your basement for heating. This of course depends on these things not requiring THAT much fuel all that often, but if it's reasonable to do, would be quite a sweet way to put an end to blackouts caused by storms.

    35. Re:Scaling is the Key! by yincrash · · Score: 2

      Here's a PDF

      According to the process flow diagram, it's just compressed CO2 and water as the output. I assume the CO2 would be bottled and used for the various uses it is currently for.

    36. Re:Scaling is the Key! by wallsg · · Score: 1

      This will separate those who are really interested in the environment from those interested in promoting the Green Industry.

      Those who are interested in the environment would be delighted if this scales and is economical enough to replace existing coal plants. For those who are just interested in promoting Green Industry this scaling and being economical is their worst nightmare.

    37. Re:Scaling is the Key! by wonkavader · · Score: 0

      Scale up? Why?

      According to the article the reactors currently "each produce about 25 thermal kilowatts" so already they produce .. let's see... assuming they get 100% efficiency in their steam engines... they made more than $1.75 an hour.

      No need to scale up at all.

    38. Re:Scaling is the Key! by DerekLyons · · Score: 1

      As this is chemical, and not combustion, (yes yes, sealed chamber...) it should not take up as nearly as much land as required by current plants.

      Since it's the coal storage yard, the electrical switchgear, and the turbine hall that takes up most of the area - what on earth would lead you to believe that generating the same amount of energy will take up less land?
       

      Also, just think of all the job creation all those small power plants will require!!!

      Also think of all the problem's you'll create in controlling the grid. More generators to keep in sync, more plants to restart in the event of a major blackout... Not to mention more high tension power lines, more trucks or rail lines delivering the fuel...

    39. Re:Scaling is the Key! by pixelpusher220 · · Score: 2

      Pretty sure the output is the same from regular coal combustion...lots and lots of ash along with now, hopefully, contained CO2.

      The CO2 can be used as such

      --
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    40. Re:Scaling is the Key! by pixelpusher220 · · Score: 4, Insightful

      there is a reason why China is gonna have 25 new nuclear reactors up and running before we get a single one out of committee

      And that reason is quite simply, China does not care about it's people.

      --
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    41. Re:Scaling is the Key! by pixelpusher220 · · Score: 1

      Actually sequestering CO2 may be quite simple:

      CO2 into Cement

      --
      People in cars cause accidents....accidents in cars cause people :-D
    42. Re:Scaling is the Key! by pixelpusher220 · · Score: 2, Informative

      Except that stuff from down there DOES make it's way up. Nature has a funny way of moving things from high pressure areas to low pressure ones.

      Better to put the CO2 into a stable form rather than just 'another place'.

      --
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    43. Re:Scaling is the Key! by raymorris · · Score: 1

      Solar is powering my home, and it was a one time cost. Well, there was a little cost in changing over to LED lights, a laptop, and other low power appliances

      I take it you've had your new solar power system for less them three years, then? So haven't quite hint the point where you have to spend thousands of dollars replacing those lead acid batteries that provide power after sunset, on cloudy days, etc.? That's cool. I'm glad you feel good about replacing carbon dioxide with lead and acid.

    44. Re:Scaling is the Key! by ChrisCampbell47 · · Score: 1

      Heh. I'm wondering who would be the bigger fool: you for believing this, or anyone else believing you?

      CCS is a gigantic fraud, soon to be executed on an industrial scale.

    45. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      It seems to me that sequestering CO2 is exceedingly similar to spent nuclear fuel storage.

      Seems to the rest of us that you are exceedingly fucking stupid. Sure, it's really neat and radiation is not that bad for you, but there are things that you just can't do with spent nuclear fuel.

    46. Re:Scaling is the Key! by Tuqui · · Score: 4, Informative

      It's not going to suddenly escape to the surfaces, it's miles down and under unfathomable pressure. If we had an earthquake strong enough to crack that, we'd have far more to worry about.

      If you think that nothing could happen, read about Lake Nyos disaster.

    47. Re:Scaling is the Key! by fluffy99 · · Score: 3, Informative

      As this is chemical, and not combustion, (yes yes, sealed chamber...) it should not take up as nearly as much land as required by current plants. Also, just think of all the job creation all those small power plants will require!!!

      Any chemist will tell you that combustion is a chemical reaction. What's interesting about this process is that oxidized iron is used to provide oxygen to "burn" the coal instead of injecting air into the combustion chamber. Not using air lowers the overall gaseous output you need to deal with and the output is a bit cleaner as you don't have to scrub some of the crap like NOX out. You still get sulfur compounds and the heavy metals you'd see with traditional burning.

    48. Re:Scaling is the Key! by Anonymous Coward · · Score: 2, Funny

      Actually it's no longer NIMBY, it's NOPE. Not on Planet Earth.

    49. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      was this an attempt to become king of the strawmen?

    50. Re:Scaling is the Key! by TubeSteak · · Score: 2

      What to do with it long term is another problem. But its a problem you would have anyway, so having the CO2 handed to you all
      contained is better than where we are today.

      There are plenty of industrial uses for CO2 and carbon.
      Having it handed to you on a platter is great news.

      --
      [Fuck Beta]
      o0t!
    51. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      so youd rather have a chinese style government that didnt have to listen to its citizens with their petitioning of the government for a redress of grievances? or are you simply volunteering your back yard as a waste repository?
      one persons NIMBY is another persons freedom fighter.

    52. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      Why can't the energy produced just be used to electrically split the CO2 into solid carbon and pure oxygen? I suppose you could just have microrganisms convert it all to shells like Calcium carbonate, that's fairly stable.

    53. Re:Scaling is the Key! by icebike · · Score: 1

      the question is power output.
      the article didnt even touch on that little datum.

      25 thermal kilowatts continuously for 9 days straight.
      This out of a twenty foot tall cylinder about as big around as a home water heater.

      Left unsaid was the amount fuel used or any efficiency figures.

      --
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    54. Re:Scaling is the Key! by operagost · · Score: 2, Interesting

      Just like the way it subsidizes solar and wind installations, and sends billions to failing solar technology companies.

      --

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    55. Re:Scaling is the Key! by operagost · · Score: 1

      Where do you put it? It's carbon, dude. Organic. It's not toxic waste. Bury it. If you're worried about that, just dig a hole and lie in it because you can't perform any work without producing some "waste".

      --

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    56. Re:Scaling is the Key! by operagost · · Score: 1

      What part of "contained within the chamber" doesn't sound like "sequestered" to you?

      --

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    57. Re:Scaling is the Key! by DigiShaman · · Score: 2

      "Needs of the many outweigh the needs of the few" (ST reference) is the basic theme of China. It's government was forged out of Marxism, so no surprise there. But it cuts both ways. This tenet can dispense misery upon billions of people or lift billions out of poverty in unison. It's also one of the more volatile tenets to rely on vs. one of individuality and self determination. Although the US as of strange reason is locked into a culture struggle of what I like to call "coddle-fication through victimization". Simple put, our problems are manufactured as though to pay penance for some misbegotten deeds. Perhaps it's born out of judeo christian values based on a Western cultural mindset. The theories are endless really, but it's a big nasty problem for us nonetheless.

      --
      Life is not for the lazy.
    58. Re:Scaling is the Key! by dotancohen · · Score: 1

      Sequestering CO2 is easy. You just don't have a clue how it works. The CO2 is pumped into abandon oil fields at VERY high pressures.

      From where do you think comes the energy to generate those high pressures? Hint: burning things and releasing CO2.

      --
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    59. Re:Scaling is the Key! by phantomfive · · Score: 1

      NIMBYs don't think that, they know power plants have to be built.......in Nevada. Unless they live in Nevada, then don't dump that nuclear waste here!

      --
      "First they came for the slanderers and i said nothing."
    60. Re:Scaling is the Key! by sl149q · · Score: 0

      Denmark, population about 6 million... so 28% means providing power to about 2 million. Impressive... not.

    61. Re:Scaling is the Key! by sl149q · · Score: 1

      The population density of China is high enough that pretty much anywhere you plop down a windmill you can probably use the electricity it produces without carrying it long distances. This does not mean the same strategy will work elsewhere unless they go to the same densities.

    62. Re:Scaling is the Key! by AJWM · · Score: 3, Insightful

      Coal is 84% carbon, 10% oxygen, 4% hydrogen, and 2% nitrogen (or so). Short of nuclear fission or fusion, you're going to get carbon and oxygen out of it no matter what you do.

      Now there's an idea. You'd actually get more energy running the 0.0...whatever percent thorium that's in coal through a fission reactor than you do by oxidizing the carbon.

      --
      -- Alastair
    63. Re:Scaling is the Key! by tsotha · · Score: 1

      To be fair, lots of Chinese people are already looking at significantly reduced lifespans from the air quality. Even if a significant nuclear accident happens the radiation isn't going to kill them any faster than the coal already is.

    64. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      In that case, how about pumping our nuclear waste down there too, after we're done with the oil field? After all, there is much less of it. And the consequences of having the CO2 leak out are not any better than having the nuclear waste escape.

    65. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      What part of "contained within the chamber" doesn't sound like "sequestered" to you?

      All of it. None of those words sound like sequestered. None of them even rhyme with it.

    66. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      I would say, at least in this case, that China does not care about the opinions of it's stupid people.

    67. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      It's part of their plan to develop radioactive Super-Chinese.

    68. Re:Scaling is the Key! by swilver · · Score: 1

      Luckily there is no pressure to move to new forms of energy because there's an infinite supply and energy is just getting cheaper every year.

    69. Re:Scaling is the Key! by Anonymous Coward · · Score: 1

      I hope there are some Russians with their dashcams around when one of those suckers blows.

    70. Re:Scaling is the Key! by Jah-Wren+Ryel · · Score: 1

      I take it you've had your new solar power system for less them three years, then? So haven't quite hint the point where you have to spend thousands of dollars replacing those lead acid batteries that provide power after sunset, on cloudy days, etc.? That's cool. I'm glad you feel good about replacing carbon dioxide with lead and acid.

      Apparently you have not heard of grid-tied solar, where the homeowner does not have any batteries to worry about because the electric grid itself takes the place of the battery. This sort of set up is very common nowadays, I'm no expert but I wouldn't be surprised to find that ~90% of all residential solar installations are now grid-tied since not only does it eliminate the cost of batteries, it also eliminates the concern of not properly sizing the solar power system.

      Grid-tie solar won't completely scale up to the point of totally eliminating power plants because you need some source of power when the sun goes down. But the majority of electricity usage occurs at exactly the same point in the day when solar power is the most abundant so it can go a long, long way to reducing the need for power plants without the environmental cost of hundreds of millions of lead-acid batteries.

      --
      When information is power, privacy is freedom.
    71. Re:Scaling is the Key! by AmiMoJo · · Score: 3, Insightful

      In principal I have no problem with the government subsidizing energy, just as long as it subsidizes the right stuff. Efficiency improvements and clean energy are fine, gas and nuclear not so much.

      --
      const int one = 65536; (Silvermoon, Texture.cs)
      SJW, n: "Someone I don't like, and by the way I'm a fuckwit" - AC
    72. Re:Scaling is the Key! by dbIII · · Score: 1

      Obviously, but it also means that "they are powering shit". Also high voltage DC transmission is getting to the point where very long runs with little loss are being built without even the advantage of superconductors.

    73. Re:Scaling is the Key! by khallow · · Score: 1

      Sequestering it is a lot simpler if you can simply draw if off the top of the CLOSED chamber rather than trying to scrub it out of the stack.

      Why "scrub" when carbon dioxide would be one of the principle components of the exhaust from any sort of combustion? There are a variety of ways to simply separate carbon dioxide from most other combustion products based on its mass or freezing point.

      Looking at the description of the reaction, the clever part is the oxidizing of iron pellets. This is an interesting way to pull oxygen out of the atmosphere and then apply it direct to the coal.

      One gets a much cleaner reaction as a result without all the nitrogen oxides that regular coal burning produces..OTOH, one can use those nitrogen oxides for various things (such as chemical stocks, nitrogen fixing for fertilizer, etc). So it's not clear to me that there's a big advantage environmentally or economically over the usual approach for burning coal with capture of the nitrogen burn products.

    74. Re:Scaling is the Key! by pedestrian+crossing · · Score: 1

      Why can't the energy produced just be used to electrically split the CO2 into solid carbon and pure oxygen?

      In this house, we obey the laws of thermodynamics!

      - Homer Simpson

      --
      A house divided against itself cannot stand.
    75. Re:Scaling is the Key! by Bearhouse · · Score: 1

      there is a reason why China is gonna have 25 new nuclear reactors up and running before we get a single one out of committee

      And that reason is quite simply, China does not care about it's people.

      Well, that's not quite right. The ruling party is actually quite paranoid about its [sic] people, which of course is not the same thing as 'caring'. OK, projects like the Three Gorges damn show that they're quite capable of steamrolling the right of thousands of peasants if its for "the greater good". But there's rising unrest about the pollution problems that have got too bad to be ignored.

      Also, whilst they're exploring 'alternative' energy options, they know that if the growing middle class is to continue to have access to reasonably-priced electric power in the future, there is no short-term alternative to nuclear.

      Of course, given their track record of safety in things like high-speed rail, that is not necessarily comforting...

    76. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      Well ,they offer cheap electricity for their people, while you must have heated committee arguments to keep warm.

    77. Re:Scaling is the Key! by jonbryce · · Score: 1

      Which probably isn't as bad as the significantly reduced lifespans they previously had due to starvation. Britain sorted out its air pollution problems after the great smog of 1952. That I guess is where China is at in the development process now.

    78. Re:Scaling is the Key! by cryptolemur · · Score: 1

      33 or so billion metric tonnes of CO2 annually (assuming all energy comes from this here novelty) requires quite a big hole, doesn't it?

    79. Re:Scaling is the Key! by RivenAleem · · Score: 1

      The same can be said for Flour Production!

    80. Re:Scaling is the Key! by Anonymous Coward · · Score: 1

      And that reason is quite simply, China does not care about it's people.

      Oh, yes, the energy from those reactors will be used by unicorns.

    81. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      And that reason is quite simply, China does not care about it's people.

      Actually, they care more about their people than about their individuals. Where as the western world acts mostly the opposite way.
      Think about it, they built a huge hydro plant to get some good renewable energy going for their country. They did have to displace many individuals for it.

      Where as, we're not building windmills here and there, or no new nuclear plants because some individuals landscape view gets affected.

    82. Re:Scaling is the Key! by serviscope_minor · · Score: 4, Insightful

      "Needs of the many outweigh the needs of the few" (ST reference) is the basic theme of China.

      You are forgetting that most of the western world, having industrialised earlier has been through the "let's trash the environment" stage, and after decades of rivers which burn or stink so badly they make a capital city nearly uninhabitable or spills of toxic waste which cause all sorts of nasty deaths, the western countries have solwly and painfully come to the realisation that it's actually not a very good idea to do all that.

      I think this has little to do with cultural values and much to do with industrialisation being difficult and because it is easier to mess things up than not, and therefore comes earlier on in the process.

      Also, it's a product of industrialising countries nort really quite realising how much they can mess stuff up until they experience it.

      --
      SJW n. One who posts facts.
    83. Re:Scaling is the Key! by Electricity+Likes+Me · · Score: 1

      Actually wind wise, the proliferation of anti-wind power sentiment is directly correllated with the arrival of lobbyists in small towns. Suddenly people go from mild interest to terrible concern that we just don't know that wind turbines don't cause cancer.

    84. Re:Scaling is the Key! by ByteSlicer · · Score: 3, Funny

      Yeah, but it contains a lot of hot air, so you can use that to drive a turbine. Unless they sell it first.

    85. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      The thing about the Danes is that they import a whole lot of very expensive energy from Swedish hydro and nuclear power plants when the wind stops blowing. And when it's blowing too much, Denmark cannot use enough electricity, and instead exports it to Sweden. The reason this is a bad deal for them is that they actually pay money to export electricity when they have too much (yup; a negative cost), and when they need to import it's expensive.

      Wind power is only a good deal if you can store the excess energy, and one of the best ways to create a good battery is by using a water pump - pumping water into a dam to later use as a hydro power plant. The Danes don't have any dams where they can store the water since they don't have mountains.

      Wind is also pretty bad in Denmark and Sweden because during the coldest nights in the southern regions (-30C), the wind doesn't blow anymore.

    86. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      In some regions you are allowed to put back electricity into the power grid and mooch of the nuclear power plants at night. On your bill it still comes out at a net negative kWh spent, so you don't pay anything on the electricity bill (except the fee to be part of the grid).

    87. Re:Scaling is the Key! by judoguy · · Score: 1, Interesting
      Yes, I love it too when other peoples money is taken for the things I like.

      When other peoples money (mine) is taken for things I don't like - not so much.

      How about we really try to not take much of anyone's money for anything?

      --
      Peace is easy to achieve, just surrender. Liberty is much harder get/keep.
    88. Re:Scaling is the Key! by Hatta · · Score: 1

      But, hey, Clean Coal stories have to be knocked down immediately. We can't have it prove even partially successful under any circumstance. /rollseyes.

      "Clean coal" has been a lie from the start. Every proposition for clean coal has so far ignored the most important pollutant from coal, CO2. Even this one doesn't actually have a plan for what to do with all that CO2. Is skepticism not justified?

      --
      Give me Classic Slashdot or give me death!
    89. Re:Scaling is the Key! by K.+S.+Kyosuke · · Score: 1

      "Needs of the many outweigh the needs of the few" (ST reference) is the basic theme of China.

      Fascinating, captain. Judging by the living conditions of the nomenklatura compared to the living conditions of ordinary folks, they are perfectly willing to dismiss that rule whenever it inconveniences them.

      --
      Ezekiel 23:20
    90. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      No matter how you slice it you're still left with an assload of carbon that has to go SOMEWHERE so what are you gonna do with it?

      Put it back where it came from -- underground. That's what coal gassification plants are doing now.

    91. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      That's ridiculous. Drive yer pickup back to the firing range nitwit.

    92. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      The part that worried me was more the fact that CO2 was still produced, it was just contained within the chamber (the benefit of their technique seemed to just be less/no air space required in the chamber).

      Sequestering CO2 is not simple, and is currently done mostly by pumping it into used oil fields. It's not certain whether these costs were factored in.

      I find it astonishing that the ignorant, gullable sheep still consider CO2 as a threat or dangerous. Political campaign victims all of you. What do plants require for photosynthesis? Look it up and discover you are fighting to extinguish the process by which there is food for every living animal on the planet.

    93. Re:Scaling is the Key! by ArcadeMan · · Score: 1

      Ok let's just forget about the whole thing and go nuclear.

      Let's go nuclear, from orbit. It's the only way to be sure.

    94. Re:Scaling is the Key! by Muad'Dave · · Score: 1

      There are a variety of ways to simply separate carbon dioxide from most other combustion products based on its mass or freezing point.

      So you're suggesting we take screaming hot exhaust gas from coal plants and chill it to -109.3F or -78.5C to separate the CO2 as a solid?

      Here's an example of what would be required of a single coal-fired plant:

      The Scherer plant in Juliet, GA generates 25.3 million tons of CO2 annually. That 69,315 tons/day or 62.88 millon kg/day. Ignoring the energy required to take the exhaust gas from post-scrubber temps to -78.5C and just considering getting the CO2 to sublimate would take 571 kJ/kg or 35904 GJ/day. a Ton-equivalent of coal is 29.3076 GJ, so you'd be burning 1225 tons of coal a day just to take -78.5C CO2 to -78.5C dry ice.

      --
      Tiller's Rule: Never use a word in written form that you've only heard and never read. You will end up looking foolish.
    95. Re:Scaling is the Key! by ceoyoyo · · Score: 1

      No, it's CO2. Carbon (in the form of coal) is what you started with.

      CO2 is a gas at regular temperatures, which is kind of awkward for burying it. There ARE things you can do with it though, if you happen to have it concentrated and contained.

    96. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      You say "as long as it subsidizes the right stuff", but what's wrong with nuclear? Except for waste heat and the occasional Chernobyl-type event, it's clean.

    97. Re:Scaling is the Key! by interkin3tic · · Score: 3, Insightful

      Because it's not that simple. The free market chooses the cheapest route, but that ignores externalized costs. Externalized costs which are still costs to the rest of us. Right now, that cheapest route is coal, and those externalized costs are very high.

      If they raise taxes to implement whatever clean energy you prefer, but prevent climate change, a lot more people will come out ahead on that transaction than lose out. The only reason we're not already doing it is that the few would-be-losers are being astonishingly selfish and short-sighted.

    98. Re:Scaling is the Key! by MickLinux · · Score: 1

      I know! Maybe we could take CO2, and water, and split off the oxygens -- dump that into the atmosphere, of course.

      Then we could chain the carbons together, and terminate the chains with hydrogens!

      Plus, it'd give us an extra return on the oil -- so we'd have more fuel to burn.

      Some detractors might question the energy efficiency of such a plan, but that's not really the important part. As with corn-based ethanol production, as long as you have enough subsidies to make it economically feasible, and a few laws to mandate its use, then the energy equation doesn't matter, and we can say we are doing our part for the environment.

      --
      Correct Horse Battery Staple: 72 bits of entropy. Enter "Correct H" into google. When it generates the phrase, that's
    99. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      How about we really try to not take much of anyone's money for anything?

      That's seditionist talk. Report to the closest tax-funded re-enlightenment camp within 24 hours.

    100. Re:Scaling is the Key! by hairyfeet · · Score: 1

      And that is the problem in a nutshell, the activist comes to cash in on the free publicity which helps their fundraisers and turns what could have been a discussion into a war, turns what was a local tragedy like the Martin case into "an event" where millions in property destroyed from the looting and riots,

      The ability to turn anything into a cause has allowed the rise of "professional activism" which like any other profession cares more about its bottom line than it does actually getting anything done. there is a reason why many of the founders of Greepeace want nothing to do with the org and the founder of MADD actively campaigns against the org they built, and that is because they have been taken over by professional activists that care more about shit stirring for profit than in actual results.

      I mean just look at how the current leaders of MADD have come out on TV and basically said there should be zero tolerance for alcohol. Think they never heard of prohibition? Think they don't know that banning a drug only creates black markets? of course they know that but the point of the statement was NOT to get alcohol banned, its to keep shit stirred because controversy equals more press which equals more money for lectures and books. Its all bullshit and kayfabe now and they don't give a shit if the NIMBY attitude or shit stirring causes REAL harm, as long as they can get paid.

      --
      ACs don't waste your time replying, your posts are never seen by me.
    101. Re:Scaling is the Key! by operagost · · Score: 2

      Seltzer?

      --

      Gamingmuseum.com: Give your 3D accelerator a rest.
    102. Re:Scaling is the Key! by khallow · · Score: 1

      So you're suggesting we take screaming hot exhaust gas from coal plants and chill it to -109.3F or -78.5C to separate the CO2 as a solid?

      Yes. You can get it to freeze below -56 C, BTW at a pressure of about 5 atmospheres (that's roughly where the triple point is). Removing heat (especially since that is the whole reason for burning/reacting the coal in the first place) is just not that hard.

      and just considering getting the CO2 to sublimate would take 571 kJ/kg or 35904 GJ/day. a Ton-equivalent of coal is 29.3076 GJ, so you'd be burning 1225 tons of coal a day just to take -78.5C CO2 to -78.5C dry ice.

      You missed a sign there. That's an exothermic transition. Turning that dry ice back into a gas does take a lot of energy, but that can be extracted directly from the atmosphere or other normal heat reservoir rather than burning coal.

    103. Re:Scaling is the Key! by shutdown+-p+now · · Score: 2

      What's wrong with subsidizing nuclear? It is one way to clean energy.

    104. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      Oh grow a brain, you clueless twit.

    105. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      If it doesn't emit CO2 or other pollutants, then it IS green industry, you nitwit. Of course green industry promoters would promote it.

      I notice very little is being said about how the co2 is to be sequestered anyway, so the point is moot.

    106. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      It isn't expensive when all of the senators and representatives from coal burning states insert major tax credits (read: corporate welfare) [...]

      Equating tax credits with welfare is morally repugnant. In the case of tax credits, you simply have *less* money forcefully expropriated from you, which means you can invest more on production, and produce more value as a result. In the case of welfare, you receive income without having had to produce anything; you receive value that could have gone into production, but won't, simply because you "need" or "want" it.

    107. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      I don't see how it is relevant. Citing the WP article on Lake Nyos:

      "Whatever the cause, the event resulted in the rapid mixing of the supersaturated deep water with the upper layers of the lake, where the reduced pressure allowed the stored CO2 to effervesce out of solution."

    108. Re:Scaling is the Key! by Anonymous Coward · · Score: 0

      Or maybe, just maybe, it's the rampant corruption that's been taking place in a non-democratic nation. Regulations you say? WTF are those when it's the GOVERNMENT doing the polluting. The CCP, or good ole boys group patting each other on the back on how well they've been helping out their fellow comrades.

      Spare me your western centric view.

    109. Re:Scaling is the Key! by Muad'Dave · · Score: 1

      You can get it to freeze below -56 C, BTW at a pressure of about 5 atmospheres

      Even if you increase the pressure to 5 atm and 'freeze' it at -56C, are you going to store it at that pressure forever? In not, you still have to chill it to at least -78.5C so that it remains solid at 1 atm. Also, increasing the pressure by a factor of 5x also changes the temperature by the same factor (PV=nRT, isochoric process and all that), so you're fighting a losing battle by pressurizing it.

      You missed a sign there.

      I didn't miss a sign, I used the wrong word [sublimate vs deposit] and I forgot about the Coefficient of Performance for refrigerators. Let me try again:

      The Scherer plant in Juliet, GA generates 25.3 million tons of CO2 annually. That 69,315 tons/day or 62.88 millon kg/day. Ignoring the energy required to take the exhaust gas from post-scrubber temps to -78.5C and just considering getting the gaseous CO2 to deposit into solid CO2 would take 571 kJ/kg / COP or 35904 GJ/day / COP. a Ton-equivalent of coal [wikipedia.org] is 29.3076 GJ, so you'd be burning 1225 / COP tons of coal a day just to take -78.5C CO2 to -78.5C dry ice.

      --
      Tiller's Rule: Never use a word in written form that you've only heard and never read. You will end up looking foolish.
    110. Re:Scaling is the Key! by khallow · · Score: 1

      Even if you increase the pressure to 5 atm and 'freeze' it at -56C, are you going to store it at that pressure forever?

      I could chose to. Or I could chose not to. Industrial processes like this usually return the materials to standard temperature and pressure. The point isn't to store carbon dioxide at this point, but to pass your exhaust gas through this state so that carbon dioxide freezes out selectively, resulting in a mechanism that separates out carbon dioxide at cheap cost from the rest of the gases.

      I didn't miss a sign

      Again, you missed a sign. The actual energy cost of the process comes from the reduction of entropy associated with separating carbon dioxide from the other gases in your exhaust. All other energy changes are temporary and mostly recoverable. For example, the energy obtained from freezing carbon dioxide out of the exhaust stream can be put back in to vaporize the carbon dioxide.

  2. Oh Rly? by Anonymous Coward · · Score: 1, Interesting

    Well I'll let the scientists peer review this one. But cool.
    Though to debbie downer this it still doesn't bring back the virginia mountains that were destroyed for coal.

    1. Re: Oh Rly? by pollarda · · Score: 3, Funny

      What Virginia mountains? I don't know what you are talking about, I don't see any....

    2. Re: Oh Rly? by Type44Q · · Score: 1

      What Virginia mountains? I don't know what you are talking about, I don't see any....

      If you're in Virginia, you've probably been to Walmart. Seen the customers?

  3. You keep using that word... by Kenja · · Score: 3, Informative

    combust:
    Verb
    1. Consume by fire.
    2. Be consumed by fire.

    --

    "Have you ever thought about just turning off the TV, sitting down with your kids, and hitting them?"
    1. Re:You keep using that word... by icebike · · Score: 4, Informative

      A better word might have been "oxidized" but the good professor probably was trying not to confuse the journalism major
      who wrote the story with words too big for their tiny world view.

      Lots of CO2 is produced, but it is retained in the chamber and captured, and oxygen and coal are fed in continuously.
      They operated it for 9 days straight.

      --
      Sig Battery depleted. Reverting to safe mode.
    2. Re:You keep using that word... by gutnor · · Score: 1

      If you really want to be pedantic, your definition is chemically wrong (and the summary actually mentions chemical combustion). Combustion is basically, just an oxydation. Depending how strong/rapid the oxydation is, it is called fire or not.

    3. Re:You keep using that word... by MBCook · · Score: 1

      This is a university press release. They probably talked to him and and asked him questions until he put it that way, because "if we say chemically oxidized no one will know what we're talking about". I bet he doesn't use that word in the paper.

      --
      Comment forecast: Bits of genius surrounded by a sea of mediocrity.
    4. Re:You keep using that word... by c0lo · · Score: 1
      Combustion

      Combustion (pron.: /kmbs.tn/) or burning is the sequence of exothermic chemical reactions between a fuel and an oxidant accompanied by the production of heat and conversion of chemical species.

      --
      Questions raise, answers kill. Raise questions to stay alive.
    5. Re:You keep using that word... by icebike · · Score: 2

      Yeah, the writer, Pam Frost Gorder, is no dummy, but she knows who she is writing for.
       

      --
      Sig Battery depleted. Reverting to safe mode.
    6. Re:You keep using that word... by Livius · · Score: 1

      Language will catch up. It does with every other form of progress.

    7. Re:You keep using that word... by Anonymous Coward · · Score: 0

      combust:

      Verb

      1. Consume by fire.

      2. Be consumed by fire.

      You might want to try the chemical definition of combustion. http://en.wikipedia.org/wiki/Combustion

  4. Re: Bullshit by Anonymous Coward · · Score: 5, Funny

    I love reasons! Care to share?

  5. We should be doing that now by MichaelSmith · · Score: 0

    Normal coal burning plants could collect all their exhaust as well. It would cost part of their energy output, but not all

    1. Re:We should be doing that now by c0lo · · Score: 2

      Normal coal burning plants could collect all their exhaust as well. It would cost part of their energy output, but not all

      The problem is the other gasses after passing through the combustion chamber, which you may not want to pay for compressing and sequestring. The 78% nitrogen in the atmospheric air will still be there after burning and will contribute to the increased cost.

      I wonder if the extra cost of pulverizing the carbon to 0.1mm particle size is a proper offset for the CO2 separation cost from air based combustion.

      Also, since the oxygen is delivered bound to iron, the total energy generated but this process will be smaller... unless (or "even if"?) you decide to reoxidize the reduced iron by burning it again

      --
      Questions raise, answers kill. Raise questions to stay alive.
    2. Re:We should be doing that now by MichaelSmith · · Score: 1

      I wonder how you would go separating oxygen from nitrogen before combustion, then burning the coal on pure oxygen, though I suppose that is the process described in the article.

    3. Re:We should be doing that now by c0lo · · Score: 1

      I wonder how you would go separating oxygen from nitrogen before combustion, then burning the coal on pure oxygen,

      It's actually easier to separate the CO2 after the combustion.
      Liquefaction temperatures and heat capacity (how much energy to extract to lower the temperature by 1 degree at constant pressure for 1 mol of gas):
      * oxygen: –182.95 C heat cap: 29.38 J/(mol x K)
      * nitrogen: –195.79 C heat cap : 29.12 J/(mol x K)
      * carbon dioxide: – 57 C heat cap: 36.94 J/(mol x K)

      So, to separate CO2 from a mix of 78% N2 and 22 % CO2 (after burning, no oxygen) you need to cool down to – 57 C something with a (weighted) average heat capacity of 30.84 J/(mol x K).
      To separate the oxygen from a mix of 78% N2 and 22% O2 you need to cool down to –183 C something with an average heat capacity of 29.18 J/(mol x K).

      So starting from a temperature of 20C, from the same volume of gas mixture, the energy to get 22% of CO2 after combustion versus to one get 22% of oxygen before combustion is in a ratio of approx 4/10.

      --
      Questions raise, answers kill. Raise questions to stay alive.
    4. Re:We should be doing that now by MichaelSmith · · Score: 1

      I also wondered if the CO2 could be used directly by filtering the particles out and feeding the exhaust has through greenhouses. You would need hundreds of kilometres of greenhouse obviously.

    5. Re:We should be doing that now by c0lo · · Score: 1

      I also wondered if the CO2 could be used directly by filtering the particles out and feeding the exhaust has through greenhouses. You would need hundreds of kilometres of greenhouse obviously.

      Better still: algae ponds - being more primitive (with lower specialized morphology), the rate of conversion to biomass higher. Additional minor advantage: even if only slightly, CO2 dissolves in water - easier to contain than in a pure greenhouse.

      As one effect of the introduction of carbon tax in Australia: such projects become viable.

      Long time though until such projects would become mainstream, even if (quoted from the last link):

      CSIRO suggests 100 square kilometres of algal ponds could provide all of Australia’s fuel needs

      (100 sq.km = a square 10 km on the side. The size of the brown coal deposit being mined in open pit fashion in Latrobe valley: 50 km long, between 8 and 16 km wide > 400 sq km)

      --
      Questions raise, answers kill. Raise questions to stay alive.
    6. Re:We should be doing that now by MichaelSmith · · Score: 1

      CSIRO suggests 100 square kilometres of algal ponds

      A tiny fraction of our existing stock of algae lakes, algae rivers, etc.

    7. Re:We should be doing that now by c0lo · · Score: 1

      CSIRO suggests 100 square kilometres of algal ponds

      A tiny fraction of our existing stock of algae lakes, algae rivers, etc.

      Count this river out, though

      --
      Questions raise, answers kill. Raise questions to stay alive.
  6. huge costs by Anonymous Coward · · Score: 2, Insightful

    "New technologies that use fossil fuels should not raise the cost of electricity more than 35 percent, while still capturing more than 90 percent of the resulting carbon dioxide. Based on the current tests with the research-scale plants, Fan and his team believe that they can meet or exceed that requirement"

    good luck selling that

    1. Re:huge costs by im_thatoneguy · · Score: 1

      "New technologies that use fossil fuels should not raise the cost of electricity more than 35 percent, while still capturing more than 90 percent of the resulting carbon dioxide. Based on the current tests with the research-scale plants, Fan and his team believe that they can meet or exceed that requirement"

      good luck selling that

      Yeah. You have to be pretty desperate to keep people in coal mines in order to advocate a technology that costs even more than Wind.

  7. Um, WHY? by russotto · · Score: 0

    The basic idea is to burn coal with rust in an oven, then capture the CO2. Why not just burn coal and air in an oven and capture the CO2? The hard part is surely the CO2 capture, not the burning.

    1. Re:Um, WHY? by foniksonik · · Score: 4, Informative

      There is no burning. Apparently that is the key innovation. The chemical reaction between the coal dust and the rust pellets releases the CO2 in a very controlled manner with the CO2 being separated cleanly rather than mixed up with smoke aka carbon molecules. That must make the CO2 capture much much easier.

      --
      A fool throws a stone into a well and a thousand sages can not remove it.
    2. Re:Um, WHY? by russotto · · Score: 2, Informative

      There is no burning. Apparently that is the key innovation.

      Coal is oxidized to produce CO2 and heat. That's "burning", regardless of whether you use air or iron oxides as the oxidizer.

    3. Re:Um, WHY? by Anonymous Coward · · Score: 5, Informative

      Why not just burn coal and air in an oven and capture the CO2

      Because only part of the air gets converted to CO2. Most of the air is nitrogen, and only ~21% is oxygen. Even if you have complete conversion of the oxygen to CO2 (not going to happen), you'd end up with exhaust gas that's mostly nitrogen with some carbon dioxide mixed in. This nitrogen/carbon dioxide mix is difficult to deal with. To do anything with the CO2 you'd have to separate it from the nitrogen and residual oxygen, which gets complicated and expensive.

      The hard part is surely the CO2 capture, not the burning.

      Exactly. This new method attempts solve that by separating the CO2 generation stage from the air-using stage. If you could effectively separate them, you'll get a pure CO2 stream in one half of the reactor (which if you can keep closed you can pump off into storage tanks) and you'll keep the nitrogen/depleted-oxygen mix in the other half of the reactor, away from your pure CO2.

      The way it works is to use iron oxide as an oxygen shuttle. The iron oxide pellets grab oxygen from the air half of the reactor, and are then transferred as a relatively gas-free solid to the coal half of the reactor, where they give up their oxygen to produce a relatively pure stream of CO2. The pellets are then separated from the coal ash and transferred as a relatively gas-free solid back to the air half of the reactor, where they are recharged with oxygen. If you engineer it right, you could conceivably make it a continuous feed operation, where you shuttle the iron oxide beads back and forth through airlocks, keeping most of the CO2 in the sealed reactor where it can be pumped off as a comparatively pure gas.

    4. Re:Um, WHY? by trout007 · · Score: 2

      I think it is because when you burn in air (Mostly Nitrogen) you create NOx compounds. When you burn your exhaust gas contains lots of nitrogen which you have to remove the CO2 from to process. It seems they are using rust as a way to take the oxygen out of the air first so when it reactions with the carbon you get pure CO2 which can easily be compressed without having to deal with Nitrogen and it's oxides.

      --
      I love Jesus, except for his foreign policy.
    5. Re:Um, WHY? by Anonymous Coward · · Score: 0

      The smart part is that they don't have to deal with the 79% non-combustible part of air - nitrogen etc. in the enclosed chamber.
      Carbon dioxide can be compress easily for storage (vs nitrogen)

    6. Re:Um, WHY? by Cramer · · Score: 1

      Mostly because air is only partly oxygen. Those other parts lead to other combustion products that should be dealt with (plus the coal isn't 100% carbon) and the vast majority of the air comes right back out. The point is maintain near perfect control over the combustion and it's output (both gas, ash, and heat.)

      Note: I would point out... replace the carbon (coal) with aluminium, and you've got thermite.

    7. Re:Um, WHY? by multimediavt · · Score: 4, Informative

      There is no burning. Apparently that is the key innovation.

      Coal is oxidized to produce CO2 and heat. That's "burning", regardless of whether you use air or iron oxides as the oxidizer.

      Ummm, sorry, I'm gonna have to go with the Ph.D. in Chemistry on this one buddy, and he says it's NOT burning. I would not call your comment, Informative. Uninformed, but not informative. Ooo, that's a t-shirt right there...

    8. Re:Um, WHY? by aaarrrgggh · · Score: 1

      Bulk CO2 capture is a cryogenic process. Flue gas temperature is likely around ~300-500C. If you wanted to remove 90% of the CO2 you would need to cool the flue gas to about 10K, that is a lot of energy. Only the non CO2 portion of the (now cryogenic) flue gas can be used to pre-cool the hot flue gas.

    9. Re:Um, WHY? by El+Puerco+Loco · · Score: 1

      Yeah but you're not like, burning it with FIRE, man, you're burning it with iron! And the iron is recyclable, unlike fire.

    10. Re:Um, WHY? by foniksonik · · Score: 1

      My understanding was that burning involves fire aka heat and light radiation so a more intense reaction. The description in TFA was that of chemical combustion but with only heat radiation confined to the oxidized iron pellets. "Burning" is probably just an imprecise term whether used by laymen or by experts.

      --
      A fool throws a stone into a well and a thousand sages can not remove it.
    11. Re:Um, WHY? by Anonymous Coward · · Score: 0

      That link is not even relevant to the discussion. An appeal to authority is still a logical fallacy. What if he said that water was flammable if you stare at it long enough? Would that be true too? After all he is an authority so it must be.

      This is the attitude that impeded science in the dark ages. It must be pointed out and ridiculed in every instance, not modded +4 informative.

    12. Re:Um, WHY? by chihowa · · Score: 1

      Glucose is oxidized in your body to produce carbon dioxide and heat. We typically don't refer to that as "burning". It's a very similar concept.

      --
      If you want a vision of the future, imagine a youtube comments section scrolling - forever.
    13. Re:Um, WHY? by Anonymous Coward · · Score: 0

      you're arguing over fucking semantics man, who cares what you call it, the chemical reaction sure doesn't.

    14. Re:Um, WHY? by Anonymous Coward · · Score: 0

      "Combustion (pron.: /kmbs.tn/) or burning is the sequence of exothermic chemical reactions between a fuel and an oxidant accompanied by the production of heat and conversion of chemical species. The release of heat can produce light in the form of either glowing or a flame. Fuels of interest often include organic compounds (especially hydrocarbons) in the gas, liquid or solid phase."

      By the definition of "Combustion" or "Burning" I will call BS on "this is not burning." The process described here oxidizes coal. He's breaking the initial chemical bonds of coal and adding an oxygen molecule to the carbon atom. For you non-scientific types, oxidation == burning.

      This article suggests he's doing it more efficiently and creating less byproducts, such as CO, NOx, etc and making more CO2, which is then captured. It is still "burning" coal.

      This process still doesn't address what material has the highest energy/density ratio. That is an exercise for the reader.

    15. Re:Um, WHY? by Anonymous Coward · · Score: 0

      Glucose is oxidized in your body to produce carbon dioxide and heat. We typically don't refer to that as "burning".

      Can't speak for you, but here in the US we certainly refer to it as burning. "Burning calories" is a completely normal American English idiom, widely used and understood.

    16. Re:Um, WHY? by Anonymous Coward · · Score: 0

      Mr Ph.D. in Chemistry says,

      "We carefully control the chemical reaction so that the coal never burns—it is consumed chemically, and the carbon dioxide is entirely contained inside the reactor."

      Ok, what's the difference between being "consumed chemically" and being burned? I'm pretty sure you don't need a PhD in Chemistry to explain this. I think professor Liang-Shih Fan is using the coloquial definition of "burn" as in violent reaction producing light and heat, and venting directly into the atmosphere, And in this sense, yes, he's right. His reactor doesn't do this. but the chemistry is virtually the same as conventional burning, just in a much more controlled setting.

    17. Re:Um, WHY? by ceoyoyo · · Score: 1

      When you burn stuff you get a lot of stray heat, random bits of stuff going up with all the hot air, etc.

      This controlled oxidization process gives you fairly pure CO2 rising off the top and most of the heat concentrated in the iron beads, which you can then remove from the reactor and suck the heat out of. The CO2 without all the crud in it is easier to capture. Plus the reactor is sealed, except for the gas removal. You don't need to be spraying air (which is mostly nitrogen) into it, which makes capturing the CO2 much simpler.

    18. Re:Um, WHY? by pngai · · Score: 1

      I wonder how easy it is to separate the iron pellets from the coal ash at the scale of a large power plant, which is about one million pounds of coal per hour.

    19. Re:Um, WHY? by multimediavt · · Score: 1

      That link is not even relevant to the discussion. An appeal to authority is still a logical fallacy. What if he said that water was flammable if you stare at it long enough? Would that be true too? After all he is an authority so it must be.

      This is the attitude that impeded science in the dark ages. It must be pointed out and ridiculed in every instance, not modded +4 informative.

      So, in your world every chemical reaction is burning? Interesting place. And, saying something is a logical fallacy and then using one to support your argument is both an argument from ignorance and a self-refuting idea.

      Thanks for playing, though.

    20. Re:Um, WHY? by multimediavt · · Score: 1

      you're arguing over fucking semantics man, who cares what you call it, the chemical reaction sure doesn't.

      I don't think you know what the definition of semantics is, or you are using the same other-world dictionary that the commenter above used to define a chemical reaction, i.e., it's all burning.

    21. Re:Um, WHY? by multimediavt · · Score: 1

      "Combustion (pron.: /kmbs.tn/) or burning is the sequence of exothermic chemical reactions between a fuel and an oxidant accompanied by the production of heat and conversion of chemical species. The release of heat can produce light in the form of either glowing or a flame. Fuels of interest often include organic compounds (especially hydrocarbons) in the gas, liquid or solid phase."

      By the definition of "Combustion" or "Burning" I will call BS on "this is not burning." The process described here oxidizes coal. He's breaking the initial chemical bonds of coal and adding an oxygen molecule to the carbon atom. For you non-scientific types, oxidation == burning.

      This article suggests he's doing it more efficiently and creating less byproducts, such as CO, NOx, etc and making more CO2, which is then captured. It is still "burning" coal.

      This process still doesn't address what material has the highest energy/density ratio. That is an exercise for the reader.

      Well, an understanding of a chemical reaction would be necessary for you to call BS on my statement, or that of the researchers in question. Not all chemical reactions are combustion/burning. As in, not all rectangles are squares.

    22. Re:Um, WHY? by multimediavt · · Score: 1

      Oh, and here's an example oxidation that's not burning, Einstein.

  8. Like healthy citarettes by jamesl · · Score: 0, Troll

    Al Gore said ...

    The coal and oil companies have spent in the United States alone a half a billion dollars in the first eight months of this year promoting a lie that there is such a thing as "clean coal." Clean coal's like healthy cigarettes -- it does not exist. It could theoretically exist. The only demonstration plant was canceled. How many, how many such plants are there? Zero. How many blueprints? Zero.
    http://thinkprogress.org/climate/2008/09/28/172379/gore-clean-coal-cigarettes/?mobile=nc

    1. Re:Like healthy citarettes by Bill,+Shooter+of+Bul · · Score: 4, Insightful

      We already burn a crap load of coal for our electricity. Wouldn't it be great if we worked to make it clean-er ( at least in terms of soot and mercury released into the air)? There isn't much on the horizon that could replace coal over night. We should try to find something will all due haste, but it wouldn't hurt to get the low hanging fruit. Its pretty much what Obama is doing now and its a sensible approach.

      --
      Well.. maybe. Or Maybe not. But Definitely not sort of.
    2. Re:Like healthy citarettes by mark-t · · Score: 1

      This wasn't your main point, I know, but I know more than one person who claims that so-called "electric cigarettes" are not unhealthy at all.

    3. Re:Like healthy citarettes by Anonymous Coward · · Score: 0

      Ok, Barack Obama is metrosexual. Maybe he's even had a couple bisexual experiences. But he's not a fruit.

    4. Re:Like healthy citarettes by toejam13 · · Score: 2

      Except that the United States has the benefit of cheap methane (CNG). Regionally, you also have cheap hydro in the NW and TV, cheap wind in the upper prairie states and cheap solar in the sun belt.

      Coal is only cheap when you exclude the environmental and related health costs. The heavy and radioactive metals expelled as particulate matter are a major source of cancer. The nitrogen oxides expelled are a major contributor to acid rain. People are sorta forgetting those issues in the whole CO2 debate. Last I checked, chemotherapy wasn't cheap.

      And many areas in the US have restrictions on wood burning. Unless you're talking about a pellet stove with catalytic converter which is fairly darn clean as far as burnin' wood goes as is often exempt from burn restrictions.

    5. Re:Like healthy citarettes by sdguero · · Score: 1

      We already burn a crap load of coal for our electricity. Wouldn't it be great if we worked to make it clean-er ( at least in terms of soot and mercury released into the air)?

      I'm no expert on coal power plants but I'm pretty sure we already do that with scrubbers.

      There isn't much on the horizon that could replace coal over night. We should try to find something will all due haste, but it wouldn't hurt to get the low hanging fruit.

      Maybe not on the horizon but there is certainly something that has been around for 50+ years that could replace coal overnight. It's called nuclear power.

      Its pretty much what Obama is doing now and its a sensible approach.

      Is he? I feel like its more about politics than actually solving anything. Instead of pumping money into "green" start-up companies that inevitably spread the wealth among their executives and then disappear in a puff of smoke, the federal government could subsidize the building of a smelter capable for manufacturing a reactor vessel. Last I read, the only country with the facilities to manufacture those is Japan and they currently have years of back orders. I also haven't heard anything about solving the nuclear waste storage problem out of this administration. Getting the waste problem sorted out, subsidizing the construction of a facility with the ability to make containment vessels, squashing all the red tape involved with new plant construction, and decommissioning some of the older nuclear power plants is the most sensible approach to getting us away from oil and coal in my eyes.

    6. Re:Like healthy citarettes by Mashiki · · Score: 1

      You realize that a decade ago, europe had access to cheap CNG too. And now it doesn't. And many places in Europe also have restrictions on wood burning as well, and it's now gotten to the point where local governments are no longer enforcing laws on it because the options are 'let people freeze to death' or 'let them illegally cut wood.' Just keep those ideas right going along, never mind that there's a million people in Germany that can't afford electricity because of green energy projects either. Or that people in Greece are clear cutting forests for basic fuel so they can keep warm, and cook dinner now.

      Things are just peachy!

      --
      Om, nomnomnom...
    7. Re:Like healthy citarettes by toejam13 · · Score: 1

      I'm no expert on coal power plants but I'm pretty sure we already do that with scrubbers.

      Scrubbers are typically only required for new plants. Existing plants have very liberal grandfather policies that exempt them. So many companies will simply upgrade existing facilities to keep the grandfather clause. It isn't unlike tearing down a house, save for one wall, then building a new house and then saying it is a 100 year-old house.

       

      Maybe not on the horizon but there is certainly something that has been around for 50+ years that could replace coal overnight. It's called nuclear power.

      Traditional nuclear power facilities are expensive. Not to mention that you have to build them in the Styx to appease the NIMBY folks, so you suffer a lot of transmission losses. Thorium reactors might offer a solution. Same with micro reactors that can use a sealed fuel container shipped from a factory. But GE and Westinghouse are still pushing for their latest super-sized traditional reactors.

    8. Re:Like healthy citarettes by gargleblast · · Score: 1

      I'm not sure I follow your reasoning so let me paraphrase: There were no clean coal plants in 2008, therefore these folks shouldn't even try.

      I get it that the old gasification and flue cleaning efforts are proving to be duds. But Ohio State's effort is not so much an ill-conceived megaproject trumpeted by vested interests, than it is good basic science.

    9. Re:Like healthy citarettes by dbIII · · Score: 0

      I'm no expert on coal power plants but I'm pretty sure we already do that with scrubbers.

      Shh! That bit of reality pokes holes in the "coal releases more radiation than a nuclear plant" stupidity and will get the nuclear fanboys foaming at the mouth.

    10. Re:Like healthy citarettes by dbIII · · Score: 1
      "New" meaning after Nixon, so I'm not sure where you'd find an old one in the USA.
      Because scrubbers are widely used in the USA you can look at Beijing's crappy air and smirk, instead of dealing with something worse at home due to a higher coal sulphur content.

      Thorium reactors might offer a solution

      The US nuclear lobby ate it's young and will keep on doing it, so you are going to have to wait to see what India does with Thorium unless you can get people with a vested interest in Uranium to stop interfering.

    11. Re:Like healthy citarettes by dbIII · · Score: 1

      Did Siri learn to be rude or did a human being just fail the Turing test?

    12. Re:Like healthy citarettes by drnb · · Score: 1

      You realize that a decade ago, europe had access to cheap CNG too. And now it doesn't.

      Access to natural gas in Russia? Not access to natural gas within EU borders? That is hardly comparable to the quantities of natural gas that the US has within its US borders.

    13. Re:Like healthy citarettes by Mashiki · · Score: 1

      Access to natural gas in Russia? Not access to natural gas within EU borders? That is hardly comparable to the quantities of natural gas that the US has within its US borders.

      How's those lack of drilling permits, and cockblocking of things like Keystone XL working out for you guys these days anyway? Oh right...enjoy those soaring energy prices.

      --
      Om, nomnomnom...
    14. Re:Like healthy citarettes by apcullen · · Score: 1

      Good thought. But sadly, this won't replace those dirty coal plants over night either. Power companies will have to make large investments to either build new plants or convert existing plants to this technology. And the only thing big companies like to spend money on is their shareholders.

    15. Re:Like healthy citarettes by Electricity+Likes+Me · · Score: 1

      Access to natural gas in Russia? Not access to natural gas within EU borders? That is hardly comparable to the quantities of natural gas that the US has within its US borders.

      How's those lack of drilling permits, and cockblocking of things like Keystone XL working out for you guys these days anyway? Oh right...enjoy those soaring energy prices.

      The US populace has no idea about what drives its energy costs. Keystone won't solve shit - it will however make a bunch of oil execs very rich, at the possible expense of thousands of kilometers of natural water resources. Oil is fungible - it makes no difference if it's refined in Canada or the US - the pipeline is purely about American oil interests getting to refine Canadian crude, as opposed to canadians, europeans, arabs or the chinese.

      Demand is going up because demand is going up - keystone won't make a dent. But it might just end a bunch of important ecosystems.

    16. Re:Like healthy citarettes by Hatta · · Score: 1

      Soot and mercury are irrelevant. If we don't control CO2 emissions nothing else matters.

      --
      Give me Classic Slashdot or give me death!
    17. Re:Like healthy citarettes by Bill,+Shooter+of+Bul · · Score: 1

      That's kind of crazy.

      http://www.psr.org/news-events/press-releases/coal-pollution-damages-human-health.html

      Coal pollution negatively affects lungs, heart, and nervous system of the human body. That matters. What you are proposing is akin to saying that the police shouldn't investigate any robberies at all, because there are murders to solve.

      --
      Well.. maybe. Or Maybe not. But Definitely not sort of.
    18. Re:Like healthy citarettes by Hatta · · Score: 1

      No, what I'm saying is that the murder problem is so bad if we don't focus on it we're all going to be dead anyway. All the coal pollution in the world doesn't mean shit next to world wide war for arable land.

      --
      Give me Classic Slashdot or give me death!
    19. Re:Like healthy citarettes by Bill,+Shooter+of+Bul · · Score: 1

      Yeah, what I'm saying is that even in a bad area like Detroit the majority of the population isn't killed despite the rampant murders. Global warming is bad, but not that bad. Even if it were, as I said in my first post we cannot eliminate our dependance on coal within the next 10 years. So, lets try and reduce its impact as much as possible while working as much as possible to make sure we do go off coal in 10 years. We can do both.

      Also, there is no war. There is no credible threat of war. You sound as crazy as the yk2 doomsday folk. If I didn't understand the science, and based my opinion of global warming based off of your ramblings I would think it was all crap.

      In summary, YOU ARE NOT HELPING. Please return to reality.

      --
      Well.. maybe. Or Maybe not. But Definitely not sort of.
    20. Re:Like healthy citarettes by Hatta · · Score: 1

      You really think we can relocate millions of people in a time when resources of all types, but especially arable land, will be dwindling without precipitating a major conflict? You're the one who needs to return to reality.

      --
      Give me Classic Slashdot or give me death!
    21. Re:Like healthy citarettes by Mashiki · · Score: 1

      ... at the possible expense of thousands of kilometers of natural water resources.

      And we have someone sucking right at the talking points of whatever they want. Useful tip, there are so many pipelines crossing that aquifer now, and some of them are nearly 50 years old. More personal research vs reading what someone tells you would do you good.

      Never mind that it's cheaper to refine crude when it's nearby compared to shipping it across the Atlantic. And safer, or that we have a larger strategic oil reserve than unfriendly countries you buy from now. Yep, full on smrt with that one.

      --
      Om, nomnomnom...
    22. Re:Like healthy citarettes by drnb · · Score: 1

      Access to natural gas in Russia? Not access to natural gas within EU borders? That is hardly comparable to the quantities of natural gas that the US has within its US borders.

      How's those lack of drilling permits, and cockblocking of things like Keystone XL working out for you guys these days anyway? Oh right...enjoy those soaring energy prices.

      Natural gas prices in the US were pretty low, and inventories pretty high, last I heard.

      As for the permits and such ... there is quite a difference between being dependent upon your own government, which you can change, compared to a foreign government that you can not change and are at the mercy of. Plus you've moved the goal posts a bit since much of what you refer to is not natural gas.

  9. Other factors to consider by SketchOfNight · · Score: 5, Interesting

    How does the lack of pollution from the process compare against that generated from the acquisition of the coal?
      Is it possible/practical to convert an existing coal power plant?
      Is there an appreciable energy/pollution cost to produce the fine powder coal used in the process?
      How much energy is consumed or how much pollution is produced in transporting the coal to the reactor?
      Is the process itself efficient in regards to the energy output when compared against the total energy costs?

    I'm sure there's a lot of other things that don't spring to mind instantly, but I'm certainly not an expert on any of this. Doubts notwithstanding, this is pretty cool.

    1. Re:Other factors to consider by LoRdTAW · · Score: 2

      I'll bite...
          "How does the lack of pollution from the process compare against that generated from the acquisition of the coal?"
      In many places, coal is mined using giant shovels that are electrically powered. Underground mines also tend to use electric shovels and other machinery, though not all. From the mine pit or shafts, its either directly loaded into train cars or haul trucks to trains cars. So its pretty much the same.

      "Is it possible/practical to convert an existing coal power plant?"
      Impossible? No. Impracticle, yes. It all comes down to cost. I once toured the Poletti Power plant in Long Island City, New York City. The entire plant was mostly boiler, a big multistory boiler. We first walked past the generator (875MW) which was tiny compared to the boiler. So you are looking at removing a major portion of the plant to fit it with the new boiler. My bet is it's more costly to upgrade than to demolish an existing plant and start from scratch.

      "Is there an appreciable energy/pollution cost to produce the fine powder coal used in the process?"
      They already use coal dust in boilers. They use coal mills to pulverize it and blow it into the boiler where its burned like a jet of gas/air. See: http://en.wikipedia.org/wiki/Pulverized_coal-fired_boiler

      "How much energy is consumed or how much pollution is produced in transporting the coal to the reactor?"
      Again, the same method used today, train. If trains were electrified (difficult, given the geography they need to cover) then they would be much cleaner. But today's locomotives are pretty damn efficient. We went from needing 5000-6000HP to 4000-4500HP. And it goes without saying, trains are pretty clean when you take into account the amount of weight moved vs. fuel burned. They mentioned burning syngas which is used as feed gas for the Fischer-Tropsch process which converts feed gas into liquid fuels like diesel and gasoline using a nickel/iron catalyst and heat. H2, CO and CO2 are the components of syngas and it looks like they could make plenty on-site which could be used to generate clean diesel for the trains delivering the coal.

      "Is the process itself efficient in regards to the energy output when compared against the total energy costs?
      I would assume if they get the same efficiency as coal plant then they are already ahead of the game. The infrastructure is already there, we just need to build the plants. Hopefully this is a real development that could be put into commercial use.

      To take power stations a step further: they generate plenty of waste heat that can be used for Fischer-Tropsch process reactors to produce fuels. If the plants were located in rural or low density areas, how difficult would it be to pump some of that flue gas CO2 into large algae farms to produce bio fuels? There are plenty of things we could do to boost power plant efficiency. And if you are wondering why power plants produce waste heat, the steam can not condense inside the turbine otherwise water could destroy the blades. The steam is super heated, often to over 1000 degrees F by passing it through tubes inside the boiler. So the steam is well over 212F/100C when it exits the turbine into condensers. Though, there are super-critical steam generators that don't boil water. Rather the water is put under such high pressure that it does not boil and its allowed to expand directly into steam just before entering the turbine housing.

    2. Re:Other factors to consider by garyoa1 · · Score: 1

      Couple of things. Those giant electric shovels require giant diesel engines to power the generators.
      Trains aren't diesel powered. They are electric. They require huge diesel engines to power the generators.

      --
      Wuddooeyeno? IITYWYBMAD? Like nuts? eclecticallyincorrect.com
    3. Re:Other factors to consider by Reziac · · Score: 1

      I'm wondering if it might work just as well on any other burnable organic matter, such as ordinary newspaper and similar trash.

      --
      ~REZ~ #43301. Who'd fake being me anyway?
    4. Re:Other factors to consider by LoRdTAW · · Score: 1

      The giant shovels are powered directly by electricity. They have a high voltage umbilical cable which is around 13.8kV that runs from a substation. If it were to house its own diesel generators, they would be too big to be practical. See: http://en.wikipedia.org/wiki/Big_Muskie. Bucket wheel excavators also are directly plugged into the power grid. So if they ran on clean coal, the mining operation would be very clean.

      I also said the trains were diesel-electric, but they could run off synthetic/bio diesel created on site by power stations.

  10. No emission-less by OzPeter · · Score: 5, Informative

    Its not emission-less. If you read his presentation from 2008 you'll see that the C02 is the byproduct of the reaction that is is used to transfer heat to the steam boiler. The C02 still gets generated as before, just now it can be more readily sequestered - assuming that you want to spend the money on that part of the equation.

    Coal Direct Chemical Looping Retrofit for Pulverized Coal-fired Power Plants with In-Situ CO2 Capture (PDF - but why the hell in this day and age do I need t tell you that? Can't you just look at the link?)

    --
    I am Slashdot. Are you Slashdot as well?
    1. Re:No emission-less by Anonymous Coward · · Score: 0

      Who said it was emission less? The hyperlink phrase, you know the underlined part, even says that the process captures 99% of the CO2 produced. That means it 1) produces CO2, 2) captures 99% of the CO2 produced, and 3) allows 1% to escape. No where does the article claim that it is emission less.

      Coal Direct Chemical Looping Retrofit for Pulverized Coal-fired Power Plants with In-Situ CO2 Capture (PDF - but why the hell in this day and age do I need t tell you that? Can't you just look at the link?)

      Apparently some of us can't.

    2. Re:No emission-less by Raptoer · · Score: 4, Insightful

      Even if you don't sequester the carbon and just put it out a smoke stack you're still at an advantage over normal coal burning. One of the major problems with coal burning is not the CO2, but the fly ash that contains heavy metals and causes respiratory problems. This process allows for those heavy metals to be contained in the coal ash which is kept within the plant. Depending on the concentration of metals in the ash it may be economical to mine the ash.

      Additionally since the CO2 is pure it can be used industrially without having to distill out the nitrogen that you would if you got it from regular burning.

    3. Re:No emission-less by Anonymous Coward · · Score: 0

      The ash is sold to make masonry products. This is one of the reasons why bricks often have a slightly higher radiation signature than background.

    4. Re:No emission-less by rahvin112 · · Score: 1, Interesting

      The Sulfur in coal burning is readily scrubbed and sold as sulfuric acid, in fact all the heavy metals are scrubbed and sold for industrial uses. This has been true since the EPA forced the installation of the initial scrubbers and the big coal users found out the scrubbers paid for themselves in the chemicals they extracted.

      The fly ash itself is also highly valuable in the cement products industry. In fact it's so valuable as a pozzolan that they make fly ash directly (not as a byproduct) to meet the fly ash demand as current coal burning doesn't produce enough. Almost every byproduct of coal burning except the CO2 is a viable commodity these days.

    5. Re:No emission-less by hrvatska · · Score: 1

      Even if you don't sequester the carbon and just put it out a smoke stack you're still at an advantage over normal coal burning. One of the major problems with coal burning is not the CO2, but the fly ash that contains heavy metals and causes respiratory problems. This process allows for those heavy metals to be contained in the coal ash which is kept within the plant. Depending on the concentration of metals in the ash it may be economical to mine the ash.

      The fly ash will stay within the plant unless it's containment pond has a catastrophic spill.

    6. Re:No emission-less by dbIII · · Score: 1

      Still lower than granite though so nobody cares.

    7. Re:No emission-less by Anonymous Coward · · Score: 0

      Yep, that was my point. It isn't a danger to use and thus is a profit center for coal power plants while being a required agent for other industries. There really is little worry about ash.

    8. Re:No emission-less by TubeSteak · · Score: 2

      Almost every byproduct of coal burning except the CO2 is a viable commodity these days.

      Then why are there so many multi-million gallon fly ash ponds that can be seen from space?

      --
      [Fuck Beta]
      o0t!
    9. Re:No emission-less by drinkypoo · · Score: 1

      The C02 still gets generated as before, just now it can be more readily sequestered - assuming that you want to spend the money on that part of the equation.

      It would be ideal for using technology our tax dollars paid to develop in the 1980s for turning carbon into algae. But, you know, HAHAHAHAHA

      --
      "You're right," Fisheye says. "I should have set it on 'whip' or 'chop.'"
    10. Re:No emission-less by Electricity+Likes+Me · · Score: 1

      Tell that to denizens of Shanghai. 2 micron scale particles are surprisingly toxic to the respiratory system, and that's what choking Shanghai from their coal plants.

    11. Re:No emission-less by dbIII · · Score: 1

      Which has exactly what to do with the ash that never makes it out of the stack and is used in masonry products?
      Also it's not just the size, but the morphology (shape) and material (look up the mechanism behind why asbestos causes problems) that you have to worry about with airbourne dust. If you consider those and post in a thread about that actual topic you may come across as being insightful and relevant instead of your post looking silly where it is here.

  11. Sounds like rubbish by Gorobei · · Score: 2

    So it captured 99% of the CO2 in a vessel. Great! Now what does it do with it? Vent it to the atmosphere for zero gain?

    Or use some magic zero energy cost process to convert it to chalk or something? Guess the article was missing that.

    This is like Sasha Cohen's Hoverboard invention - it's a plank that real scientists can figure out how to levitate. Can I have venture capital?

    1. Re:Sounds like rubbish by foniksonik · · Score: 2

      99% of the CO2 as a pure gas. That pure CO2 can be converted to methanol (at what cost?) ala:

      http://www.scientificamerican.com/article.cfm?id=turning-carbon-dioxide-back-into-fuel

      If not commercially viable as fuel stock it could be used for a variety of applications that adulterated CO2 can not.

      --
      A fool throws a stone into a well and a thousand sages can not remove it.
    2. Re:Sounds like rubbish by Gorobei · · Score: 2

      Spend energy to convert CO2 to another fuel. Great. That has nothing to do with the article unless "unadulterated CO2" is something important. Unfortunately, "unadulterated CO2" is not exciting: it's cheap and hardly more useful than adulterated CO2.

      Thanks for playing.

    3. Re:Sounds like rubbish by toejam13 · · Score: 1

      You could use it as feed for algae or other CO2 consuming organisms. Except that currently, the costs for such recapture systems are prohibitive. And in the end, the carbon still ends up in the atmosphere - you just get another fuel cycle out of it.

    4. Re:Sounds like rubbish by Anonymous Coward · · Score: 0

      Boy for that level of snark you'd think you would have something more like a point.

    5. Re:Sounds like rubbish by gandhi_2 · · Score: 1

      Pump it into algae tubes to make fuel out of.

      Like the Redhawk powerplant does.

    6. Re:Sounds like rubbish by Anonymous Coward · · Score: 0

      So that you can sell the technology to China so that they can have cleaner air and .... profit?

    7. Re:Sounds like rubbish by Nethemas+the+Great · · Score: 1

      One of the inherent problems that seems to keep getting overlooked in fuel/power production is the consumption of fresh water. It's a scarce and increasingly so resource. Unless these technologies can be made to work with saline water, or we find a dirt cheap means of desalination we'll only be addressing one problem to compound another.

      --
      Two of my imaginary friends reproduced once ... with negative results.
    8. Re:Sounds like rubbish by jfdavis668 · · Score: 1

      Pump it back into coal mines. I'm sure it will stay there.

    9. Re:Sounds like rubbish by j-beda · · Score: 1

      Pump it into algae tubes to make fuel out of.

      Like the Redhawk powerplant does.

      Then when that fuel gets burned it gets released into the atmosphere. Sure, this may be marginally better than direct release, but it still is a net atmospheric gain of CO2

    10. Re:Sounds like rubbish by Anonymous Coward · · Score: 0

      You pump it into old oil wells, new oil comes up and the CO2 stays down forever. Yes it's true. They've been doing it for years, for the oil. The CO2 sequestration is/was incidental. Now they'll simply have a new source of CO2.

    11. Re:Sounds like rubbish by gandhi_2 · · Score: 1

      Only if you define "net gain" as "a change over a time period which best suits my argument".

      The co2 in the coal was atmospheric once before, and it will be again.

      Turning it into biodiesel basically uses the CO2 as a carier for energy captured from the sun by photosynthesis.

    12. Re:Sounds like rubbish by j-beda · · Score: 1

      Only if you define "net gain" as "a change over a time period which best suits my argument".

      Most people involved in the conversation about human caused increases in atmospheric levels of CO2 define "net gain" as anything that increases the CO2 level compared to not doing the action. Pumping CO2 exhaust past algae to be used as later combustion material does increase the atmospheric CO2 when that material is later burned.

      Of course using biodiesel is merely a carrier of solar energy, but if you are using "newly" created CO2 for its growth, you are not having a significant positive impact on atmospheric carbon levels.

      If you don't care about atmospheric carbon levels, since "The co2 in the coal was atmospheric once before, and it will be again.", then why bother with the algae cycle at all? Just burn more coal, we've got quite a bit of it.

    13. Re:Sounds like rubbish by GameboyRMH · · Score: 1

      You're right, the problem is that the part where the CO2 gets back into the ground happens on a timescale way too slow for human civilizations.

      --
      "When information is power, privacy is freedom" - Jah-Wren Ryel
    14. Re:Sounds like rubbish by Anonymous Coward · · Score: 0

      Red herring from a denier shill. Piss off you fascist arse licker.

  12. What happens to the carbon dioxide? by kasperd · · Score: 2, Insightful

    Maybe they can capture the carbon dioxide, but what are they going to do with it afterwards? Put it in a container and bury it underground? The carbon dioxide will still be there, and the only way to get rid of that is through another reaction, which most likely needs energy to happen.

    Another important question is the efficiency. Are they able to produce the same amount of electrical energy from each ton of coal as traditional methods? If their efficiency is worse, then I am very unimpressed. If their efficiency is better, then that may be a more interesting story than that of capturing the carbon dioxide.

    --

    Do you care about the security of your wireless mouse?
    1. Re:What happens to the carbon dioxide? by Anonymous Coward · · Score: 1

      New potential way to use CO2 to produce semiconductors and additional energy at the same time! ---> http://phys.org/news/2012-05-lemons-lemonade-reaction-carbon-dioxide.html

    2. Re:What happens to the carbon dioxide? by hackingbear · · Score: 1

      The CO2 can be fed to algae tanks to continue another energy production process. It would be easier than doing the same with traditional coal plant if the CO2 is clean and not mixed with ash etc.

    3. Re:What happens to the carbon dioxide? by Anonymous Coward · · Score: 0

      Maybe they can capture the carbon dioxide, but what are they going to do with it afterwards?

      Well, off the top of my head: carbonated beverages. Or fire extinguishers. (I get that the CO2 will eventually be released from these applications, but they are already in addition to coal-fired plants.)

    4. Re:What happens to the carbon dioxide? by Anonymous Coward · · Score: 0

      They can store that CO2 in dell under ground wells. That way when we turn on the tap we'll get free seltzer water.
                                  In all seriousness what is the solid effluent like and does it clean up easily? The idea sounds wonderful but we need a lot more information. I also wonder if a similar process could not be applied to leaves, scrap wood and lawn trimmings or perhaps plastic waste.

    5. Re:What happens to the carbon dioxide? by DieByWire · · Score: 2

      The CO2 can be fed to algae tanks to continue another energy production process. It would be easier than doing the same with traditional coal plant if the CO2 is clean and not mixed with ash etc.

      And when you burn the oil you got from the algae that formerly fossil CO2 is now in our atmosphere. So maybe you got more energy per ton of CO2 out of it than we normally would. You're still filling the atmosphere with fossil carbon.

      'Clean coal' is marketing, pure and simple.

      --
      Never shake hands with a man you meet in a fertility clinic.
    6. Re:What happens to the carbon dioxide? by jafac · · Score: 0

      well, they could set up a bunch of PV panels to capture sunlight into electricity, and split the CO2 into carbon and oxygen using catalyzed electrolysis. Release the oxygen into the atmosphere, and just dump the carbon into the ground or something.

      --

      These are my friends, See how they glisten. See this one shine, how he smiles in the light.
    7. Re:What happens to the carbon dioxide? by Nethemas+the+Great · · Score: 1

      Mod parent up. If the research pans out, that's pretty damn interesting.

      --
      Two of my imaginary friends reproduced once ... with negative results.
    8. Re:What happens to the carbon dioxide? by j-beda · · Score: 2

      well, they could set up a bunch of PV panels to capture sunlight into electricity, and split the CO2 into carbon and oxygen using catalyzed electrolysis. Release the oxygen into the atmosphere, and just dump the carbon into the ground or something.

      Or they could scrap the whole coal part of stuff and just use the PV to move those electrons around directly. Adding the PV to the coal system would be less efficient since you are basically using the PV system to reverse the coal system anyway. If the coal system produces X amount of electrical energy releasing Y tonnes of CO2, it is going to take a lot more than X amount of PV electrical energy (I would guess at least 5X being very conservative) in order to turn those Y tonnes of CO2 back into carbon and oxygen. It would be much more efficient to just use that 5X of PV electrical power without touching the coal at all.

    9. Re:What happens to the carbon dioxide? by Anonymous Coward · · Score: 0

      Actually, if you turned the Carbon Monoxide this thing produces through Fischer Trope process, you could make plastic much easier than current refining of petroleum. You don't really have to worry about putting carbon into the atmosphere, as you will instead be putting it into cars and construction material and such.

      Imagine a world where carbon fiber is cheaper then steel, and you can buy epoxy for 5$ a gallon. Even in a world of nothing but Nuclear + renewables, this would still be incredibly useful just for the Organic Chemistry perspective.

    10. Re:What happens to the carbon dioxide? by Anonymous Coward · · Score: 0

      You're still filling the atmosphere with fossil carbon.

      That's alright. The rainforest and sperm whales will suck that right up out of the atmosphere... absolutely no problemo. Now we just gotta stop the tree burning and whale killing.

    11. Re:What happens to the carbon dioxide? by Anonymous Coward · · Score: 0

      You're right, they could do that. Or they could be even more efficient, and simply cut out the coal power plant from the equation, and use only the solar panels. To split up CO2, you need as much solar power as what you gained when oxidizing the coal in the first place.

    12. Re:What happens to the carbon dioxide? by Anonymous Coward · · Score: 0

      Maybe they can capture the carbon dioxide, but what are they going to do with it afterwards?

      They'll just have a 400km tall chimney at the top of the container. Easy!

    13. Re:What happens to the carbon dioxide? by Anonymous Coward · · Score: 0

      Pump it into a big plastic dome and invite all of the world's global warming deniers to live in it. They are so sure it's not a pollutant after all. This would be an excellent way to deal with them.

      You could offer to pay them a million bucks a year to live there. Since they would survive less than an hour of exposure to this "harmless gas that is essential to life" this means you could get rid of them for about a hundred bucks a head. Added bonus, this would also stop them doing other stupid stuff like driving hummers and voting Republican.

  13. weasel words by Anonymous Coward · · Score: 0

    Old process (burning):
    Inputs: coal, oxygen
    Outputs: heat, CO2

    New process:
    Inputs: coal, oxygen
    Outputs: heat, CO2

    So they found a fancy way of oxidizing coal and producing heat from that (with a reaction that sounds a bit like on in a steel mill). Probably great and highly efficient but one of the end products is still CO2 (like with good old fashioned, non-fancy, burning). This is not a closed loop, not 'green' in the sustainable sense, only in the (possibly) more efficient sense.

    1. Re:weasel words by viperidaenz · · Score: 2

      Old process (burning):
      Inputs: coal, air
      Outputs: heat, CO2, N2, N2O

      FTFY.

    2. Re:weasel words by GameboyRMH · · Score: 1

      The big difference here is that in the new process the CO2 is conveniently separated which takes a lot of the difficulty out of sequestration.

      --
      "When information is power, privacy is freedom" - Jah-Wren Ryel
  14. Efficiency is the key flaw by Anonymous Coward · · Score: 0

    This process is basically iron refining from oxide then (to be implemented) using the pellets of hot iron to boil water. Not what I would call thermodynamically efficent. It also looks likely to suffer from the jamming issues that have plagued pebble bed reactors. Note that, critically, they have not shifted the heat to a medium that would allow electricity generation. Iron pellets aren't going to power turbines any time this century.

    1. Re:Efficiency is the key flaw by viperidaenz · · Score: 5, Informative

      It's 2.5% less efficient than a normal coat power station.
      Normal plant: 36.43%
      This thing: 33.93%

      It actually produces 10% more power from the turbine, but the supporting pumps, fans and compressors need to be powered.

  15. Re: Bullshit by Anonymous Coward · · Score: 1

    Me too. Reasons are the best.

    Of course I'm skeptical of anything that's "new & improved" because everything from soap to breakfast cereal has been labeled as such. But there is always hope ... and change ... oh well, that ruins that.

  16. RTFA-ing is the Key! by TubeSteak · · Score: 4, Informative

    The researchers are about to take their technology to the next level: a larger-scale pilot plant is under construction at the U.S. Department of Energy's National Carbon Capture Center in Wilsonville, AL. Set to begin operations in late 2013, that plant will produce 250 thermal kilowatts using syngas.

    From 25 kw to 250kw
    Sounds like they're scaling it up.

    --
    [Fuck Beta]
    o0t!
    1. Re:RTFA-ing is the Key! by the+eric+conspiracy · · Score: 1

      Not sure where this process generates syngas. I think you are confusing two different technologies.

    2. Re:RTFA-ing is the Key! by Nethemas+the+Great · · Score: 5, Informative

      RTFA, the process is designed to work with two of the already commonly available forms of fuel to power companies, crushed coal and coal derived syngas.

      --
      Two of my imaginary friends reproduced once ... with negative results.
    3. Re:RTFA-ing is the Key! by the+eric+conspiracy · · Score: 1

      I did read the article. Perhaps you should read one on the subject of syngas.

      Syngas is a mixture of hydrogen, carbon monoxide and carbon dioxide. Syngas is not generally produced starting from coal, with is the topic of this story.

      In other words the pilot facility they are describing would not be testing the coal process.

    4. Re:RTFA-ing is the Key! by rubycodez · · Score: 0, Flamebait

      a quarter of a megawatt. whoop-de-fucking doo. instead of pissing away money on this popcorn popper, why don't we invest in something that can drive progress and civilization forward, like thoruim reactors?

    5. Re:RTFA-ing is the Key! by balsy2001 · · Score: 1

      The city I live in has about 60K people. It is entirely powered by 90+Mwe from a small series of hydro plants. After the efficiency conversion of about 1/3 the electrical output from the 250 Mwt would be about enough to do it. Not to shabby to be able to power a 50K person city. I love nuclear but if this is for real it shouldn't be trivialized.

      --
      GENERATION 27: The first time you see this, copy it into your sig on any forum and add 1 to the generation.
    6. Re:RTFA-ing is the Key! by TubeSteak · · Score: 1

      a quarter of a megawatt. whoop-de-fucking doo. instead of pissing away money on this popcorn popper, why don't we invest in something that can drive progress and civilization forward, like thoruim reactors?

      I'm sure there was some asshole who said the exact same thing about nuclear power as you're saying about this coal power technology.
      Or do you think gigawatt nuclear reactors sprung fully formed from Zeus' head?

      --
      [Fuck Beta]
      o0t!
    7. Re:RTFA-ing is the Key! by Dahan · · Score: 1

      Syngas is not generally produced starting from coal, with is the topic of this story.

      In what sense is it not generally produced from coal? Coal gasification is being done on a commercial scale right now (and has been done for decades). While it may not be the most common way to generate syngas, it's certainly not a new or unknown idea. I'm sure if there's more demand for syngas made from coal, more plants will be built. And no, generating syngas from coal is not the topic of this story.

      Not sure where this process generates syngas.

      Not sure why you think this process has anything to do with generating syngas. The point of this is to burn certain carbon-containing materials, e.g., coal or syngas, in a way that the generated CO2 can be almost completely captured. This research plant generates 25kW from coal. The upcoming one will generate 250kW from syngas.

    8. Re:RTFA-ing is the Key! by semi-extrinsic · · Score: 1

      You're off by a factor of 1000. So it would provide power for roughly 60 people.

      --
      for i in `facebook friends "=bday" 2>/dev/null | cut -d " " -f 3-`; do facebook wallpost $i "Happy birthday!"; done
    9. Re:RTFA-ing is the Key! by rubycodez · · Score: 1

      let's see how the 2nd electrical producing reactor did, to compare to this 2nd proposed coal energy plant. We'd be talking about the next electricity producing reactor after the ERB-I (100 KW), which was the USSR's Obninsk Nuclear Power Plant at 5 MW which was connected to a power grid. Going on to the next one, the first commercial reactor Calder Hall in Windscale, England, was opened in 1956 with 50 MW and was later upgraded to 200 MW. So as I said, this article is about a proposed "popcorn popper", which by the way is slang joke used by those of us who worked in nuclear power industry to refer to small fossil plant that come online during peak demand.

  17. Great! by no-body · · Score: 1

    So the CO2 san be safely captured and preserved for future generations on this planet.

    1. Re:Great! by Anonymous Coward · · Score: 1

      pure CO2 has uses. Normal you have to clean the CO2 for other uses (there are uses of CO2 in the real world). This gas is pure CO2. So they can make money of other uses of it. All the CO2 they been pumping into the ground would cost to much to clean. That is why it is being pumped into the ground.

  18. Sloth Pit anyone? by PenguinJeff · · Score: 1

    In the early 90's I remember reading a Poular Mechanics or maybe Scientific America talking about cheapest ways of getting hydrogen for fuel cells. One method mentioned was using coal in a Sloth Pit. Something about adding water with it and shacking it to release hydrogen gas or something.

  19. I think I figured it out by trout007 · · Score: 2

    Reading between the lines the difference is you aren't getting air into the reactor. So you don't have to heat and separate the Nitrogen. It says the iron pebbles are exposed to air in the reactor but I don't think that is entirely accurate. I think they are exposed after they give up their oxygen to the carbon and are still hot but outside of the actual reactor. This would provide an easy way to chemical way to separate the oxygen from the nitrogen. So the only gaseous byproduct is pure CO2 not CO2 mixed with Nitrogen which is harder to process.

    I could be wrong.

    --
    I love Jesus, except for his foreign policy.
    1. Re:I think I figured it out by Animats · · Score: 1

      I could be wrong.

      You're pretty much right. This type of process produces separate N2 and CO2 streams, and very little NOx. That's useful; the N2 is harmless, oxides of nitrogen are pollutants, and there are uses for reasonably pure CO2.

    2. Re:I think I figured it out by dkf · · Score: 1

      the N2 is harmless

      Technically not, since you could suffocate in it when it is a pure stream. But mixing it back into the air is absolutely no problem at all.

      --
      "Little does he know, but there is no 'I' in 'Idiot'!"
    3. Re:I think I figured it out by trout007 · · Score: 1

      The problem with the N2 mixed with CO2 is you have to somehow separate them to sequester the CO2.

      --
      I love Jesus, except for his foreign policy.
    4. Re:I think I figured it out by Anonymous Coward · · Score: 0

      Ah, that must be the 'loop' that they're talking about - the iron. goes in as rust with the carbon dust, comes out as hot iron particles into air where it will rust again and then you can feed it back in. One engineering problem is probably keeping the temperature from getting too hot, or else your iron dust will turn into an iron blob. I could be completely mistaken.

    5. Re:I think I figured it out by pngai · · Score: 1

      CO2 is easily liquified at room temperature with moderate pressure. Once liquified, just open a valve at the bottom of the tank to drain out the liquid CO2, closing the valve afterwards.

  20. While interesting the chem method creates GHG by WillAffleckUW · · Score: 1

    The Iron Oxide beads are mined and processed, using coke and various other carbon-creating materials.

    To adequately measure the GHG (or climate change gasses) we have to consider the cradle to grave carbon impacts of all the constituent components, from mining to use to final process to usage.

    This might be useful in crowded Chinese cities, where the source pollution is high at point of use (e.g. home and industrial heating and power usage), but does nothing per se to alter the total environmental impact of the use of coal itself.

    Kind of like how electric cars, if run off of coal or oil power plants, do nothing to reduce emissions, except at point of vehicular usage.

    The problem we all face, both in China and the rest of the industrialized world, is that we are overloading our GLOBAL systems with too much carbon or fossil fuel emissions. It doesn't matter if we do it in the coal regions of the US or China, it still puts too much energy into the climate systems, and accelerates extreme weather conditions worldwide, such as massive storms, dust bowls growing to TX CA and FL, and things like that.

    Nice try. Good for a polluted Chinese city choking on its own pollution, but not good enough to deal with the source PROBLEM.

    (caveat - based on my reading of the various papers by Chinese scientists in peer-reviewed journals and their own internal numbers, which we all know they fudged)

    --
    -- Tigger warning: This post may contain tiggers! --
    1. Re:While interesting the chem method creates GHG by viperidaenz · · Score: 2

      The iron is not a consumable. It is just used to carry oxygen and is re-used.

      The problem I see is its much more expensive and reduces the amount of usable energy in the coal. More coal is consumed. You've captured all the CO2 but you still also need to spend more money to deal with it long term.

    2. Re:While interesting the chem method creates GHG by WillAffleckUW · · Score: 1

      Good points. But it goes back to the whole system energy usage, and where that energy comes from.

      I'm far more impressed by a recent soon to be published article on Chinese usage of windows - they lose a lot of energy in heating due to their usage of non-optimal window pane design.

      --
      -- Tigger warning: This post may contain tiggers! --
    3. Re:While interesting the chem method creates GHG by dbIII · · Score: 1

      The Iron Oxide beads are mined and processed, using coke and various other carbon-creating materials.

      It's probably not a huge step to move to an iron ore or a mineral sand since you can find all forms of iron oxide naturally in large quantities. I've got no idea where you've got the coke idea from since it's that and limestone that you use to get iron out of an oxide and the objective here is the oxide and not the metal. It would of course take energy to process rock into whatever's required but it's not as if you need to make metal out of it.

      Of course "zero emissions" is always PR bullshit so all you can do is aim for low impact.

  21. WON'T WORK by Anonymous Coward · · Score: 0

    Expensive system that does not scale to commercial power size at all.

    And right there.. first word... expensive... means we won't do it.

    money > all

    Polluted air is cheap. (for the power companies direct profits) They only do what they are forced to do.

    Theres dozens of ways to make coal burning 100% clean. BUT they all have the same problem.
    More expensive than doing it the plain ol burning way. And we won't do any of them at all outside of lab table examples.

    What we NEED to invent is a new human who gives a fuck about more than profit right now at the cost of everything else long term.
    And replace all of our politcians and ceos with them.

    Good luck with that tho. That'll take a few hundred years to even get going.

    1. Re:WON'T WORK by viperidaenz · · Score: 2

      Not only does the system cost a lot of money, it also produces less power per unit of coal.\

      There's also the cost of dealing with the captured CO2 as well. If you don't want to spend even more money storing it somewhere you'll have to let it go. There's also more CO2 to get rid of, because it's a less efficient system.

  22. Re:Bullshit by Anonymous Coward · · Score: 0

    This is bullshit because of reasons. Also, "clean coal" lol.

    It seems there are deniers on both sides of the environmental debate. Sorry if science and engineering trump your politics.

  23. Pure oxygen.. by Anonymous Coward · · Score: 1

    The principle is similar to that of using pure oxygen to combust coal - the CO2 produced is nearly 100% - which simplifies carbon capture compared to the 20%CO2 / 80% N2 mixture typically got from burning in air. (see also ie google "pure oxygen carbon capture")

    Instead of using pure O2 they use iron(III)oxide as the oxidant. The reduced iron(III)oxide (as Fe(II)oxide or Fe) can be re-oxidised by air in a separate chamber.

    The actual process seems to have been very poorly communicated to the journalist (and in general) -possibly because english is the inventor's second language?

    As others above I would doubt the overall efficiency would be as good as current methods - the system is complex - and seems to need energy extraction from both gaseous extracts from both the "reducer" and "oxidiser" chambers (eg see "Process Flow Diagram" in http://www.netl.doe.gov/publications/proceedings/09/CO2/pdfs/5289%20Ohio%20State%20chemical%20looping%20(Li)%20mar09.pdf ) - not my problem thankfully.

    1. Re:Pure oxygen.. by trout007 · · Score: 1

      Thanks for the link. That is exactly what I thought was going on but the journalist didn't understand. It is basically putting the oxygen plant at the power plant.

      I'm not a chemist but will the combuster portion where they burn the iron to make iron oxide create NOx?

      --
      I love Jesus, except for his foreign policy.
    2. Re:Pure oxygen.. by Anonymous Coward · · Score: 0

      NOx compounds are generally produced when oxidation takes place in the presence of N2 at high temps - according to the pdf their combustor chamber is at just under 1000C. (~1800F)

      I had to look it up but it seems that NOx formation isn't a big deal at that temp. - though it depends on a lot of factors other than the temperature. My guess is a fairly solid "no"

    3. Re:Pure oxygen.. by trout007 · · Score: 4, Informative

      I emailed the authors after I wrote that and they emailed me back quickly. They said the only NOx comes from the Nitrogen in the Coal. None is produced in the combustion of Iron.

      This would significantly lower the scrubbing requirements and cost.

      --
      I love Jesus, except for his foreign policy.
    4. Re:Pure oxygen.. by AbrasiveCat · · Score: 1

      There is a fair amount of nitrogen compounds in coal. At the lower combustion temperatures of chemical looping most of this will not be converted to NOx, but will still need to be removed from the combustion gas stream if your planing on a CO2 sequestration pipeline. Turns out the nitrogen does not compress to a dense phase as well as CO2, so you will probably need to remove it. This is another problem of the proposed oxy-fuel combustion systems.

    5. Re:Pure oxygen.. by Anonymous Coward · · Score: 0

      I should correct myself on 'seems to need energy extraction from both gaseous extracts from both the "reducer" and "oxidiser" chambers' - apparently the oxidisation of coal with iron oxide is endothermic, and can be driven using waste gases from the exothermic oxidation of iron reaction - which makes the process make more sense.

      There's a suprisingly informative article "Chemical looping combustion" on wikipedia about just this. Apologies for my ignorance, especally to the inventor

  24. CO2 has industrial uses by Anonymous Coward · · Score: 0

    Carbon Dioxide has lots of industrial uses. It makes a good solvent. This sounds like it will lend itself to easy cleaning of sulfur and metals rich coal. If this process becomes a cheap way of making industrial CO2, I will consider it successful.

    1. Re:CO2 has industrial uses by Anonymous Coward · · Score: 0

      If these uses include releasing it into the atmosphere, then we can consider this all an exersize in futility.

    2. Re:CO2 has industrial uses by Ginger+Unicorn · · Score: 1

      Just think it through for a few seconds and you'll realise that two sources of CO2 have been reduced to one.

      In the first instance, 50 tons of CO2 comes out of the coal and goes up the stack. Then another 50 tons of CO2 comes out of some other source and is released into the atmosphere by the other industrial process. Total CO2 released into the atmosphere: 100 tons.

      In the second instance, the 50 tons of CO2 that would have gone up the stack is held back, then released later by the other industrial purpose. Total CO2 released into the atmosphere: 50 tons.

      --
      (1.21 gigawatts) / (88 miles per hour) = 30 757 874 newtons
  25. I love the quote in the article by viperidaenz · · Score: 1, Insightful

    “Unfortunately, it also produces carbon dioxide, which is difficult to capture and bad for the environment"
    Without carbon dioxide, the carbon cycle wouldn't exist and all plants and animals would die.

    1. Re:I love the quote in the article by dbIII · · Score: 1

      Similarly water is good for you until it's deep enough that you can't get air into your lungs.

    2. Re:I love the quote in the article by Anonymous Coward · · Score: 1

      Without carbon dioxide, the carbon cycle wouldn't exist and all plants and animals would die.

      We are speaking about a professor of chemical and biomolecular engineering who is working on improving how coal is used for energy. As such, I think a reasonable person should conclude that the professor is quite aware of that fact already. This would suggest that the good professor means something more by the statement than the surface interpretation gives us. Therefore, it follows that by applying good inferential comprehension and reasoning skills that the professor probably means something closer to "the production of carbon dioxide at the levels we have been doing so over the years through coal-burning power plants has been shown to be unsustainable and is proving to be harmful for the environment if we desire to maintain a relatively stable and acceptable habitat for humankind." Yet, to say all of that would be a mouthful when it can be communicated in the brevity of a few words.

      To sum up my post in one word: Inference.

    3. Re:I love the quote in the article by Anonymous Coward · · Score: 0

      Similarly water is good for you until it's deep enough that you can't get air into your lungs.

      Thats just greenie propaganda, if people drowned in water we would all be drowning where we stand, 57% of out body weight is water, if it wasn't for the water in your lungs your body would not be able to absorb the oxygen in the air.

    4. Re:I love the quote in the article by Anonymous Coward · · Score: 0

      You fucking retard, this is talking about coal. This is carbon that has until now been *outside* the carbon cycle, deep underground for millions of years. Introducing more carbon into the "carbon cycle" is most definitely bad for the environment, and is killing plants and animals at a rate consistent with a mass extinction event.

    5. Re:I love the quote in the article by Anonymous Coward · · Score: 0

      CO2 is bad for the environment if there is too much of it, as there is now. Just like salt is bad for you if you're eating too much of it, but good for you in smaller does. In fact, when we say something is bad, it must almost always be interpreted in context of the current environment. So if you have a problem with that statement, you should be having problems with pretty much any statement about something being good or bad for the environment.

  26. Nice! by fustakrakich · · Score: 1

    Will it restore the ground where it was extracted from? Or even better, it would save a step or two to just extract the heat from the coal that's already burning..

    --
    “He’s not deformed, he’s just drunk!”
  27. Without "Burning" but it's "combusted" ? by Anonymous Coward · · Score: 2, Interesting

    Last I checked, burning is combustion.

    Nor do I understand what the hell is advantageous about it. They admit to oxidiation of the hydrocarbons (ie, burning), heating it to high temperature, and the release of CO2 gas. So exactly what is so great about it?

  28. Re:Bullshit by hedwards · · Score: 4, Insightful

    Coal isn't clean though. This would clean up the side of the equation where you're burning it. But, it would do absolutely nothing for the mining aspect of it. Which is a huge mess as it stands. If you want to burn things for energy, you're better off starting with something like trees which are mostly carbon neutral as it is.

    Sure, it's technically clean if you ignore the incredible damage that it reeks on the landscape, but it's definitely not clean in a practical sense.

  29. More like the nicotine patch ... by Anonymous Coward · · Score: 0

    Coal is only cheap when you exclude the environmental and related health costs. The heavy and radioactive metals expelled as particulate matter are a major source of cancer. The nitrogen oxides expelled are a major contributor to acid rain. People are sorta forgetting those issues in the whole CO2 debate.

    And other people are sort of ignoring that the excitement over this potential new process is in part based on the claim that it will not expel the radioactive metals and the nitrogen oxides.

    You are offering denier logic. You merely deny the possibilities of science and engineering to hold onto a different set of political beliefs.

  30. This I would call "clean coal". by Anonymous Coward · · Score: 0

    All else is BS.

  31. Winds light and variable by tepples · · Score: 1

    In an electric power market that substantially depends on wind, what happens during periods when winds are calm? Does the instantaneous price of electric power double?

    1. Re:Winds light and variable by foniksonik · · Score: 1

      It's always windy somewhere. So plenty of redundancy seems to be the solution.

      --
      A fool throws a stone into a well and a thousand sages can not remove it.
    2. Re:Winds light and variable by Anonymous Coward · · Score: 0

      What happens when a poster suffers a spectacular lack of imagination and or ability to use a search engine? Does the metaphoric light bulb of humanity's intellect dim momentarily?

      Search terms. Hmmm, how about: energy storage wind

      There are virtually unlimited ways to convert excess wind generated electricity to work that stores it as potential kinetic energy, or directly in chemical reactions that store it as chemical energy, and then reconvert to electricity during lulls in wind, or peak demand periods.

      Sorry if I sound harsh, but either you're a troll, or you've never contemplated the wide subject of renewable energy ever in your life. Or been aware of the hydroelectric power that has greened the desert since the New Deal. Get thee to a library!

    3. Re:Winds light and variable by tepples · · Score: 1

      energy storage wind

      Thank you. A lot of Slashdot users have tended to stop at "just Google it", appearing too lazy to actually suggest keywords and belittling me for sharing the keywords that I had tried and found ineffective.

      or directly in chemical reactions that store it as chemical energy

      In other words a battery. Google energy storage wind, as you suggested, brought me to this article, which speaks of proprietary batteries incorporating tellurium. Not being familiar with this element, I looked it up on Wikipedia, and Wikipedia describes it as as rare as platinum, or about a thousand times more rare than the lanthanides, the elements commonly called "rare earths". This poses doubts in my mind as to whether it can scale. Even if flywheels and pumped storage fill in for it, with the whup-whup-whup and flashing sunlight creating the appearance of a health risk, I fully expect NIMBYs to erect barriers at every step.

  32. Re: Bullshit by Anonymous Coward · · Score: 1

    mmm, oatmeal reason cookies.

  33. Combustion is exothermic oxidation by tepples · · Score: 0

    "Conversion of chemical species" is just another term for "reaction", and "production of heat" through a reaction is the same thing as "exothermic", and a shorter term for "chemical reactions between a fuel and an oxidant" is "oxidation". Thus to put it even shorter: combustion is exothermic oxidation.

    1. Re:Combustion is exothermic oxidation by c0lo · · Score: 2

      "Conversion of chemical species" is just another term for "reaction", and "production of heat" through a reaction is the same thing as "exothermic", and a shorter term for "chemical reactions between a fuel and an oxidant" is "oxidation". Thus to put it even shorter: combustion is exothermic oxidation.

      Chill mate.
      My point in reply to PP: "combustion does not require fire"

      (as I'm growing old, I don't feel the same geekish urge to be absolutely exact - sometime I don't feel the need of being right)

      .

      --
      Questions raise, answers kill. Raise questions to stay alive.
  34. Re:Bullshit by dbIII · · Score: 2

    But, it would do absolutely nothing for the mining aspect of it

    Maybe it will. I haven't read the article but there have already been trials where coal is burnt in-situ via using horizontal drilling and air injection. Apparently that works so long as you have full control of all the air getting in.
    Also, (as I keep telling the fanboys here of 1970's nuclear who don't have the merest clue about developments since), there is not really such a thing as a "clean" industrial process - that's just stupid PR. All you can do is aim for less impact so you get a net benefit.

  35. To avoid being misinterpreted by dbIII · · Score: 1

    Those trials were about burning coal underground (yes, scares me too) and nothing to do with this process BUT we shouldn't rule out the possibility of this new idea having the reaction happen underground if it's better in the long run than digging it up.

  36. What happens to produced CO2 by manu0601 · · Score: 2

    This is nice, we have the opportunity to capture all produced CO2. But what are we going to do with it?

    1. Re:What happens to produced CO2 by Anonymous Coward · · Score: 0

      This is nice, we have the opportunity to capture all produced CO2. But what are we going to do with it?

      Pipe it into water to fertilize algae or other aquaponics in a closed system, making food, or wood?

      Add calcium and make (the dead skeletal parts of) coral reefs?

      Halve the net pollution of our cheapest energy source while we bring down cleaner tech's price?

      Hell, even if we only delayed a couple years worth of pollution from it with no change at all long term, that's two years more before we kill the planet, if things are that dire. I'm young and healthy - I'll take two more years of non-post-apocalypitic life, yessiree!

    2. Re:What happens to produced CO2 by Anonymous Coward · · Score: 0

      Pump it underground into empty oil/gas sites.

    3. Re:What happens to produced CO2 by manu0601 · · Score: 1

      Will it remain there?

    4. Re:What happens to produced CO2 by Anonymous Coward · · Score: 0

      CO2 is already used by pumping it down oil wells to push up more oil, and yes from what I've heard* it does stay there.

      * This means do your own research if you want a definitive answer because I didn't check it, however in sites where we had to expend energy to bring up oil and natural gas, I don't see why the CO2 wouldn't stay down there.

  37. Won't someone think of the sloths? by tepples · · Score: 1

    One method mentioned was using coal in a Sloth Pit.

    I wonder what the World Wildlife Fund and other organizations would say about that, given that two species of sloth (Bradypus pygmaeus and B. torquatus) are on IUCN's Red List as endangered.

  38. Know how I know you didn't read the article? by Weaselmancer · · Score: 4, Interesting

    From TFA:

    No other lab has continuously operated a coal-direct chemical looping unit as long as the Ohio State lab did last September. But as doctoral student Elena Chung explained, the experiment could have continued.

    “We voluntarily chose to stop the unit. We actually could have run longer, but honestly, it was a mutual decision by Dr. Fan and the students. It was a long and tiring week where we all shared shifts,” she said.

    Fan agreed that the nine-day experiment was a success. “In the two years we’ve been running the sub-pilot plants, our CDCL and SCL units have achieved a combined 830 operating hours, which clearly demonstrates the reliability and operability of our design,” he said.

    His entire staff of grad students manned the thing and kept feeding it coal for a week and it ran nonstop the whole time, and could have kept going. So this appears to be a solved problem.

    --
    Weaselmancer
    rediculous.
    1. Re:Know how I know you didn't read the article? by jklovanc · · Score: 1

      If it was a tiring week for two doctors and their grad students to deal with one small reactor that indicates that it required quite a bit of babysitting. How much babysitting would a much bigger reactor need?

      Sure on a small scale where fixing a small blockage means poking it with a metal rod. Try to scale that up to where one is dealing with tons of material rather than ounces. Get a major blockage and things can go very bad.

    2. Re:Know how I know you didn't read the article? by pixelpusher220 · · Score: 2

      How much babysitting would a much bigger reactor need?

      No more than the automated machinery that is currently used in coal plants can already provide. The industrial revolution isn't exactly new, this is just a refinement of an existing tech.

      --
      People in cars cause accidents....accidents in cars cause people :-D
    3. Re:Know how I know you didn't read the article? by jklovanc · · Score: 0

      You might want to look up the term assumption. It may be much more complex than you think.

    4. Re:Know how I know you didn't read the article? by Anonymous Coward · · Score: 0

      In the old days, the engineering crews of steam ships and locomotives had to shovel coal by hand. Eventually, they automated it using mechanical stokers. Not to say that they were foolproof, but it was a good enough solution until better technologies (oil/diesel) came along.

    5. Re:Know how I know you didn't read the article? by Electricity+Likes+Me · · Score: 1

      But it was a research scale reactor. It would've been built out of on hand components, and costs cut where necessary - automated systems for new technology aren't easy to develop even if they're all understood principles. Far easier to have someone sleep next to the thing with an alarm clock and test the actual new technology.

    6. Re:Know how I know you didn't read the article? by Weaselmancer · · Score: 1

      Exactly. Why go through all the trouble to make an automated control system for something that might not even work? Making any control system would almost certainly have taken longer than a week. Why not just have grad students babysit the thing? More efficient use of time.

      This was an experiment. The only point was to answer the question "Is this worth pursuing?" Now that we know it's possible a control system would make sense, but certainly not before.

      Oh, and this is what grad students do. They are grunts for professors. Coffee and tedium are in the job description.

      --
      Weaselmancer
      rediculous.
    7. Re:Know how I know you didn't read the article? by deadweight · · Score: 1

      All other issues aside, I am ROFLMAO at some blue collar guy working his balls off to send his kids off to college so they could work with their minds instead of their hands and then finding his grad student kids shoveling coal for a living!

    8. Re:Know how I know you didn't read the article? by ceoyoyo · · Score: 1

      Grad students frequently describe themselves as sweat shop workers or early industrial revolution coal shovellers working at the furnaces, but these guys actually do!

    9. Re:Know how I know you didn't read the article? by jklovanc · · Score: 1

      There is a huge difference between shoveling coal onto one end of a furnace then removing the ash and the complex process needed to keep the closed reactor running. The first thing being that handling powdered coal is very different that chunk coal. The most important thing being that powdered coal is highly explosive. A small spark will ignite it and blow the place to smithereens.

    10. Re:Know how I know you didn't read the article? by Electricity+Likes+Me · · Score: 1

      But, we've been doing it for a while with big powerplants anyway. It's not like it's unsolvable. Well, who knows - maybe it is. But if you're studying combustion, you study combustion - not coal-dust handling apparatus.

  39. The Cronies Will Fight It by Anonymous Coward · · Score: 0

    Damn!

    Now President Obama's "green" campaign contributors won't have a piggy morally-bankrupt to draw from.

  40. Hairy balls by tepples · · Score: 1

    It's always windy somewhere.

    True, you can't comb the hair on a coconut. But one problem with relying on wind elsewhere involves transporting the power across hundreds of km or miles and across state and national borders.

    1. Re:Hairy balls by RatherBeAnonymous · · Score: 1

      How is that different than what is done now?

      In any case, it tends to be sunny when it's not windy. Between rooftops and parking lots there are tremendous stretches of flat surfaces that could be productive small-scale solar power plants. That would distribute power generation, taking strain off of the overloaded high tension power distribution grid. What power solar can't provide can be generated by wind, hydro, geothermal, and nuclear. We have the technology to get off fossil fuels almost entirely. What we lack is the will.

      The only country I can think of that has the capacity and will to go carbon neutral is China. I'm convinced that in about 20 years, China will announce a green-energy program and they will convert entirely in about a decade.

    2. Re:Hairy balls by tepples · · Score: 1

      In any case, it tends to be sunny when it's not windy.

      So what fills in during nights or cloudy days when the winds are still calm? Or in northern or southern places like Canada that don't get quite as much insolation per square kilometer?

      Between rooftops and parking lots there are tremendous stretches of flat surfaces that could be productive small-scale solar power plants.

      But who would pay for mining the raw materials, manufacturing PV panels, and installing them?

  41. A great day... by malv · · Score: 1

    A great day for white ethnically-curious females everywhere.

  42. Actually capturing is the key by gargleblast · · Score: 4, Informative

    Actually capturing is the key. A carbon capturing plant is always going to be less efficient than a non-capturing plant. Try looking at it this way:

    36.43% Non-capturing plant
    29.14% Post-combustion capturing plant (36.43/1.25)
    33.93% This thing

    1. Re:Actually capturing is the key by ToddInSF · · Score: 1

      The other factor is the purity of the carbon. Industry does use CO2; cheaper CO2 is an amazingly useful thing. Who currently sells CO2, and why would they not want this competition, and what kind of lobbying are they willing to do to prevent it from widespread adoption, despite the significant economical advantage, and changes to markets it's adoption would entail ? What people don't do, because most lack a comprehensive understanding of how things are vs. theoretical ideals that are not based upon reality, is FOLLOW THE MONEY. The most crucial thing anyone could do politically and intellectually is be aware and involved in industry, and strive to be knowledgeable about what is done now, and how it's done, what it costs to do it, who's doing it, and how they spend the their profits to keep doing it. It's sounds complicated because it it; there's an interdependence that industry relies on, and it's naive to think that important discoveries and new processes are going to result in anything revolutionary anytime soon, particularly when most people are stuck in a la la land of ideals disassociated from reality. CO2 isn't a bad thing. It's actually an awesome thing. Stick that CO2 in a proper usable form where it's needed and amazing things happen. You can grow plants in a greenhouse twice as fast without ANY need for pesticides, for instance. You can manufacture things cheaper and more efficiently. The question begging to be answered is in who's best interest is it to prevent the inevitable for as long as possible, and why...

  43. Re:Bullshit by wonkavader · · Score: 2

    It only cleans up the burning side if we have something to do with all that CO2 that this process produces.

  44. Wait... by wonkavader · · Score: 1

    Does that mean we can use all our produced CO2 for FRACKING?

    1. Re:Wait... by pixelpusher220 · · Score: 1

      The problem is with Fracking, we've now CRACKED everything and so putting CO2 down there means it has lots of new cracks to find it's way out...

      --
      People in cars cause accidents....accidents in cars cause people :-D
  45. Coal is an amazing source of power by Grayhand · · Score: 4, Interesting

    For a fuel that requires little or no processing it's extremely energy dense. Ultimately the problem wouldn't be with the process but the budget minded power companies. There's a reason "clean coal" is like bigfoot, largely a myth. Clean coal would cost more money reducing profits. It's the reason the industry doesn't remove mercury and coal dust from the exhaust, reduced profits. They even had a government mandate and the still waited until the deadline and are now saying it's too hard. The process can trap 99% of the CO2, the trick is keeping the power companies from not releasing it into the atmosphere to save money. White Diesel is a great source of fuel and second only to natural gas for being a clean fossil fuel but it involves stripping of the CO2 and you are faced with the same problem. Sequestration isn't as simple as it sounds. Compressing huge amounts of CO2 gas takes energy and the underground storage areas don't tend to be near power plants. When you start burning more coal just to store the CO2 from the last batch the efficiency goes way down. If the existing plants had been positioned and built with all this in mind we wouldn't have all these problems. Now there are no cheap and easy solutions. Personally I prefer using algae or greenhouses to store the CO2. Try this approach, pump the CO2 into large cheap greenhouses that grow Kenaf, it's related to hemp but totally legal and interchangeable with industrial hemp. Use as much as industry needs for fiber and seed oil then turn the rest into biochar, a good one to read up on if you aren't familiar. The char can be mixed with farmland improving the soil and it'll absorb the excess fertilizer reducing run off and reducing the amount needed to grow food. The carbon is stored for thousands of years, if not millions. The power companies get to make extra money off the Kenaf and they greatly reduce the CO2 and mercury released. The Mercury will get trapped in the char and the CO2 will be stored as solid carbon. These days they try to solve everything with technology when mother nature has been doing it for billions of years.

    1. Re:Coal is an amazing source of power by Inda · · Score: 0

      Sorry dude, coal requires a lot of processing.

      While it's stored, it has a tendancy to self combust and must be compacted all day, every day.

      Grinding it up into power takes time and energy. At this point, it has a tendancy to explode.

      Moving it in powdered form is dangerous and expensive. Blowing it into the boiler is a risky exercise.

      Pulverised Fuel Ash (PFA) often contains unburnt material. This must be reprocessed and reburnt. The amount of PFA is huge and this must be disposed of too.

      Electrostatic precipitators (ESP) remove harmful sulphur. Expensive again.

      You need to read up on modern carbon capture too. It's no longer seen a hard job. No longer needs compressing underground. It's a chemical process.

      --
      This post contains benzene, nitrosamines, formaldehyde and hydrogen cyanide.
  46. No-go by h8sg8s · · Score: 0

    Obama won't like it because it's not made of fairy dust and rainbows. He wants a magical solution where the only output is spring water and sunshine.

    --
    Organization? You must be joking..
    1. Re:No-go by GameboyRMH · · Score: 1

      If we could find a way to convert bitterness and butthurt into fairy dust and rainbows, you could single-handedly save the planet!

      --
      "When information is power, privacy is freedom" - Jah-Wren Ryel
  47. Re:Bullshit by pixelpusher220 · · Score: 1
    --
    People in cars cause accidents....accidents in cars cause people :-D
  48. It'd be just like standard power plants by raymorris · · Score: 1

    If the CO2 were accidentally released, that'd be a lot like the other option - power plants that release it on purpose. You know, the way we've been doing it since the discovery of fire.

    There is one similarity with nuclear waste, though. You're probably aware that nuclear plants generate dangerous waste. You're probably also aware that nuclear plants generate a significant amount of waste. What they didn't tell you is that it's two different kinds of waste! Nuclear does NOT generate much dangerous waste. There's a few pounds of dangerous stuff which can be easily encased in heavy steel and buried two miles deep, and then there's a bunch of low level waste you could earth for breakfast. (It'd be safer than what RMS eats, anyway.) So nuclear waste is purely a POLITICAL problem, a made up issue. There's no technical problem at all. In that sense, it's the same as sequestered CO2 - a political problem, not a safety problem.

    1. Re:It'd be just like standard power plants by Anonymous Coward · · Score: 0

      https://en.wikipedia.org/wiki/Limnic_eruption is why a sudden CO2 release can be catastrophic.

      At least with nuclear waste, the spread of radioactive material in the case of a breach is mostly limited to nearby groundwater, and probably at a relatively slow rate of leakage (only the groundwater that comes in contact). Worst case, it might poison a few thousand people, but if it happens once in hundred years that's tiny compared to other types of natural and man-made disasters, or for example toxicity caused by dirty processes like coal mining.

      On the other hand, CO2 being a gas means that within a few days or weeks it'll end up in the upper atmosphere with no way to contain it. A sudden large-scale release of CO2 could alter the climate drastically within a short period of time, to the point where there wouldn't be enough time to deploy emergency countermeasures such as reflective aerosols.

      So CO2 sequestration needs to be done in a manner where it's not possible for some trigger event (earthquakes, ocean warming, etc) to cause containment failure for multiple sites simultaneously, and we can't put too much CO2 in a single place.

  49. Re:Bullshit by balsy2001 · · Score: 2

    Clean depends on the definition. There is a waste product associated with every kind of industrial process and every kind of energy production. But the forms of the waste are not all the same nor are they equivalent. Many time people equate the term clean to the quantity of carbon produced during the energy production. If this new technology is viable and it actually contains 99% of the carbon that is a HUGE development. The mining process could be improved and much of the eye sore can be avoided if you don't strip mine. I think there is a town in Pennsylvania that has been "on-fire" since the 50s or 60s because an underground coal fire was not contained.

    --
    GENERATION 27: The first time you see this, copy it into your sig on any forum and add 1 to the generation.
  50. Chemically converting coal to heat, creating CO2.. by Bartles · · Score: 1

    is called combustion. Just because it is in a box, does not mean it happens magically.

  51. Re:Bullshit by Anonymous Coward · · Score: 0

    I've always been confused by "Carbon Neutral" propaganda. For example, we have always had the same amount of carbon in the environment. Just over the years it's been sequestered into oil/coal/etc. However, now if it's been out of commission for thousands of years and it's somehow out of the equation. So burning oil/coal/etc is just normalizing the balance.
    Additionally, if we are truly talking about "zero carbon balance" why is the largest contributor to global warming from cow emissions bad? Carbon in = carbon out. This is as "Carbon Neutral" you can get but 'OMG, methane from cows is bad.'

  52. Re:Bullshit by dbIII · · Score: 2

    Clean depends on the definition

    Hence PR bullshit and a barrier to communication instead of normal language. Just treat such statements as a red flag to indicate that you cannot take the speaker at their word and need a second opinion - the word "clean" is only ever in there to mislead, if it wasn't you'd see "less pollution than X" instead of misleading bullshit.
    Of course things can be improved but whenever you see "clean" the objective is to improve the perception instead of the reality. One of the places I visited for work was a power station where water was injected into the exhaust to give it a nice fluffy white "clean" look to impress the people in a nearby town, but the place was no less polluting than more remote power stations that didn't bother. In a truly comical stuffup that trick combined with a scrubber failure one night produced nitric acid fog that condensed on hundreds of cars in the town and cost the power authority a fortune in costs to get them all repainted.

  53. Re:Bullshit by hedwards · · Score: 2

    The problem is that the system has changed since the carbon was taken out of the system. Reintroducing it in such massive quantities over such a short period of time changes things too rapidly for species to adapt to.

    Methane emissions are a very serious problem as well, but that has fuck all to do with power generation. You can use methane to produce power, but that's got nothing to do with being carbon neutral.

  54. Re:Bullshit by Anonymous Coward · · Score: 1

    Coal mining is one of the worst in that respect. Coal is so common in parts of the world, that it's economically feesible to just tear out the entire mountain, rather than dig through it to find coal, because most of the mountain is coal.

  55. Oxygen carrier issues by AbrasiveCat · · Score: 1

    There are many labs working on chemical looping combustion. Most have not gotten to "burning" coal yet. They are starting with natural gas to prove the process. Usually they will use two to three fluidized bed beds reactors to convert the fuel and oxygen (from the air) to CO2 and water. The trick, as I see it, is to find/develop, the oxygen carrier. Most so far have been Fe, Mn, or Cu based. Raw minerals have been tried for the carrier but they break down, both from attrition and from the chemical conversion of adding and losing the oxygen. You might get 20 loops out the material before you lose the material in the cyclone separators. They have also tried the putting the oxygen carrier on ceramic carriers. This seems to survive longer, but the cost is higher. The models I have seen suggest that if you need to sequester CO2 and you are burning coal this has real economic advantages over oxy-fuel combustion or integrated gasification combined cycle power systems. Then if you are going to move the CO2 any distance you will still need to clean up and dry the CO2 stream if you are going to pipeline it, but while we continue to use fossil fuels we need to be smart how we use it.

  56. Re:Bullshit by Anonymous Coward · · Score: 3, Interesting

    I've always been confused by "Carbon Neutral" propaganda. For example, we have always had the same amount of carbon in the environment. Just over the years it's been sequestered into oil/coal/etc. However, now if it's been out of commission for thousands of years and it's somehow out of the equation. So burning oil/coal/etc is just normalizing the balance.

    No, no, no! You missed the biggest sink for carbon. The one that is orders of magnitude greater than all the others put together: limestone (60 million gigatons vs the 720 gigatons in the atmosphere and the 38,000 gigatons in the oceans). If you think that normalizing the balance with all of the carbon that has been taken out of the environment is a good thing, then you must be from Venus.

  57. What's in a name? by Krigl · · Score: 1
    From Wikipedia:

    Fire is the rapid oxidation of a material in the exothermic chemical process of combustion

    Regardless of possible merits, my bull-Shih detector screams bloody murder. Does the good prof possess also some degree in biomolecular linguistics or is he just so good at marketing?

    --
    Troll 2.0 Fear my asocial networking!
  58. They still burn the coal by Neil+Boekend · · Score: 3, Interesting

    They just burn it with pure oxygen instead of with air. The innovation, and it is an innovation IMHO, is that they used iron to capture and transfer the oxygen. This prevents the forming of NOx, which is a good thing.
    This means they can burn the coal hotter without emitting dangerous amounts of NOx.
    1. They let iron pellets rust. Or they buy rust in the first place.
    2. They put the rust pellets into the chamber with coal dust.
    3. They ignite the mixture (this requires a bit more heat than usual burning. At least 1566 ÂC or 2850.8 F)
    4. The coal dust pulls the oxygen out of the rust and binds it with the carbon into quite pure CO2.
    5. Heat (a lot of it)
    6. Use the heat in a default thermoelectric power plant.
    7. The pellets can rust again, to capture oxygen.
    8. ...
    9. Profit.

    If they would combine it with an iron smelting plant then the energy required in step 4 to pull the oxygen out of the rust would not be wasted. Then the iron pellets are one of the end results. Of course, then you'd have to emit step 7.

    To me this seems familiar. If I am correct this is the way Thermite works, just with aluminium powder instead of coal dust.

    --
    Well, I might have a way, but it only works on a semi spherical planet in a vacuum.
    1. Re:They still burn the coal by Anonymous Coward · · Score: 0

      You do realized that rusting: Iron + carbon acid (CO2+water) -> iron oxide + hydrogen. Technically the whole cycle can be one CO2 catching, H2 producing, electricity generating plant.

    2. Re:They still burn the coal by Neil+Boekend · · Score: 1

      No, I didn't realize that. Where does the carbon go to?
      Fe + CO2 + H2O -> Fe2O3 + H2 + C ?
      My high school chemistry isn't advanced enough to analise the feasibility of that, but I do seem to remember that producing pure hydrogen and carbon does take a lot of energy. Is the oxidization of iron enough for that?

      --
      Well, I might have a way, but it only works on a semi spherical planet in a vacuum.
  59. Diamonds? by cyberzephyr · · Score: 1

    Can they take the waste and make Diamond/Zircon out of it?

    Just wondering.

    --
    I'm here for the experience, not the Hyperbole.
    1. Re:Diamonds? by ceoyoyo · · Score: 1

      No. Diamonds are made from what you start with - carbon.

  60. This is a black day for pyromaniacs.... by Foske · · Score: 1

    n/t

  61. Re:Bullshit by balsy2001 · · Score: 1

    Agreed, but even "less pollution than X" can be misleading. It is difficult to compare different types of pollution on an apples to apples basis. For example, how much carbon released into the atmosphere given a certain amount of cyanide that seeps into the ground from cyanide heap leaching? But at least that discussion would get the facts on the table. I would argue that the word "clean" isn't always used with a negative motive, but it is likely that the person using it doesn't have an in-depth enough knowledge of the subject to say anything else (in which case maybe they shouldn't be talking). Remember Hanlon's razor, "Never attribute to malice that which is adequately explained by stupidity."

    --
    GENERATION 27: The first time you see this, copy it into your sig on any forum and add 1 to the generation.
  62. Re:Bullshit by dbIII · · Score: 1

    That's a point, but clean as in "clean coal" and nuclear have most definitely been applied frequently with intended malice.

  63. re by Anonymous Coward · · Score: 0

    Sounds nice! But can it be put into use on a large scale?

  64. Re:Bullshit by balsy2001 · · Score: 1

    I agree that it happens and by people who do know better.

    --
    GENERATION 27: The first time you see this, copy it into your sig on any forum and add 1 to the generation.
  65. A little late Liberal @ssholes. by Anonymous Coward · · Score: 1

    It's too bad the Sand N|gger in Chief closed all the coal mines in the USA.

  66. The waste is... by Anonymous Coward · · Score: 0

    TFA I notice is awful light on the details about what EXACTLY if left after this chemical burning, is it a paste, a gel, powder?

    The coal and iron oxide are heated to high temperatures, where the materials react with each other. Carbon from the coal binds with the oxygen from the iron oxide and creates carbon dioxide, which rises into a chamber where it is captured. Hot iron and coal ash are left behind. Because the iron beads are so much bigger than the coal ash, they are easily separated out of the ash, and delivered to a chamber where the heat energy would normally be harnessed for electricity. The coal ash is removed from the system.

  67. Re:Bullshit by Joce640k · · Score: 1

    Coal isn't clean though. This would clean up the side of the equation where you're burning it. But, it would do absolutely nothing for the mining aspect of it. Which is a huge mess as it stands.

    It also produces a huge amount of ash and CO2 that used to go up the chimney. Probably some other byproducts, too. What are we going to do with that?

    --
    No sig today...
  68. Coal chemistry by rossdee · · Score: 1

    The cleanest coal would be pure carbon. To extract the chemical energy from it youcombine it with Oxygen and produce CO2
    Whether you call that process 'burning' or not (like is putting hydrogen into a fuel cell to extract its chemical energy called burning? no, but you get the same result)

    So what do you do with the Carbon Dioxide? The cheapest (in both economicas and energy terms) is just to release it into the atmosphere. but that will lead to global warming.
    You could compress it and store it underground, but that uses up a lot of the energy that you got in the first place..
    You could disolve it in the oceans (and end up with acidic oceans with no fish.

    We need to find a place to put all that CO2

  69. Re: Bullshit by Anonymous Coward · · Score: 0

    I love reasons! Care to share?

    samzenpus

  70. Re:Bullshit by Ginger+Unicorn · · Score: 1

    Wreaks Reeks. Although I'm sure both apply :p

    --
    (1.21 gigawatts) / (88 miles per hour) = 30 757 874 newtons
  71. You have no clue on scale by Anonymous Coward · · Score: 0

    1) There is too much CO2 by coal plants produced in the US to be used that way
    2) even for the few megatons used that way today , what guarantee do we have that we are not setting us up for the same tragedy as lake Nyos down the line ? In 100 Year down the line ?

  72. Dirty coal is more expensive than natural gas. by 140Mandak262Jamuna · · Score: 1
    First For all that talk about clean coal and pandering to the coal producing states by the government, the basic fact is this: Dirty coal, mined by companies exploiting every available safety loophole, and creating more loop holes by buying judges, politicians and bureaucrats, is still more expensive than natural gas. Especially after the Marcellus Shale and fracking extraction methods. So no matter how efficient this clean coal process is, it is not going to be competitive. Of course we could make it competitive by some big government subsidies like Solyndra or by tilting the marketplace by laws like we did for ethanol. But without serious and continuous government subsidies, coal will be uncompetitive and it will die eventually. All the decent coal mining companies have exited the business. Leaving it to the vulture capitalists to pick the bones. Eventually there will be nothing to pick. As the famous saying goes, stone age did not end because we ran out of stone. Coal age will end with most of the remaining coal left in the ground.

    Second The particulate oxidation using rust balls and powdered coal still happens at high temperatures and it still produces gaseous carbon dioxide. We might as well burn them using atmospheric oxygen for all that trouble. The carbon sequestration process requires carbon dioxide to be captured and sequestered using the same procedures. This process of taking atmospheric oxygen, creating rust balls, reducing them (reduce = (! oxidize)), is too much of work with too little to gain.

    --
    sed -e 's/Chuck Norris/Rajnikant/g' joke > fact
  73. Re: Bullshit by Anonymous Coward · · Score: 0

    Centralia pa, i think it's still burning

  74. Charging EV with coal just became a clean alter... by fredan · · Score: 1

    Charging EV with coal just became a clean alternative.

    Oups.

  75. Wind == Ugly by Anonymous Coward · · Score: 0

    Wind? "It'll spoil our view and kill the birds!"

    I have to give it to the detractors on this one, wind turbines are unsightly and noisy. Sure, when it's only three stark white turbines on a hilltop in the distance there is a grace and novelty that makes it somewhat attractive.

    But when it's a field of turbines such as this it's VERY ugly. Also, with each turbine putting out ~50dB(A) or more at 100 meters, that becomes quite the cacophony

    I'm all for wind, but NIMBY. You're welcome to snuggle up to a wind farm if you wish, though.

  76. Don't call Stockholm Yet by Anonymous Coward · · Score: 0

    This idea has been around for a long time.

    http://repository.icse.utah.edu/dspace/bitstream/123456789/9946/1/Lewis%20Gilliland%202665972.pdf

    That prof didn't "pioneer" chemical looping.

  77. Re:Bullshit by kryliss · · Score: 1

    Centralia Pennsylvania

    http://en.wikipedia.org/wiki/Centralia,_Pennsylvania

    --
    --- If the bible proves the existence of God, then Superman comics prove the existence of Superman.
  78. Re:Bullshit by avandesande · · Score: 1

    Nothing has been said about the radionuclides and mercury that won't be released by this process.

    --
    love is just extroverted narcissism
  79. Other resources by phorm · · Score: 1

    Well, I'm fairly sure that other resources (petroleum, uranium, etc) are also fairly environmentally damaging to mine. Coal isn't going away any time soon, so this at least cleans up part of the equation.

  80. Most electricity used when people aren't home? by raymorris · · Score: 1

    > But the majority of electricity usage occurs at exactly the same point in the day when solar power is the most abundant That's very interesting. I would have thought that around noon, when the solar power is most abundant, most people would be at work or school, so they wouldn't be using electricity at home. In my house, we use electricity early in the morning getting ready for work and around dinner time. So roughly around sunrise and sunset, when solar is pretty much useless.

    1. Re:Most electricity used when people aren't home? by Jah-Wren+Ryel · · Score: 1

      Yes, because most electricity is used by business. Just look at any power company that has time of use billing schedules, peak rates are generally from 10am to 5pm.

      --
      When information is power, privacy is freedom.
    2. Re:Most electricity used when people aren't home? by VanessaE · · Score: 1

      Not to mention that the whole point of grid-tied solar (et.al) is that you sell the power back to the electric co when you aren't using it - which includes times when your solar panels are cranking out the watts while you're at work.

  81. Re:Bullshit by Anonymous Coward · · Score: 0

    I think there is a town in Pennsylvania that has been "on-fire" since the 50s or 60s because an underground coal fire was not contained.

    The town is "centralia, Penn. There are others too.

    http://en.wikipedia.org/wiki/Centralia,_Pennsylvania

  82. Coal Direct Process Needs Iron Oxide by Anonymous Coward · · Score: 0

    Where does the huge amount of iron oxide come from? It is necessary for the reaction.

    John W Wittenberg
    Fort Wayne, IN

  83. Re:Coal Direct Process Needs Iron Oxide by Anonymous Coward · · Score: 0

    I might add (I am replying to myself) how much oxygen is in a kilogram of iron? What I am getting at is that TONS of iron oxide are need for a few hundred pounds of coal. One iron atom per molecule of oxygen, FeO2! Iron is much heavier than air so my guess is the cost to supply the iron oxide, transportation cost that is, wow! Does not seem economical.

  84. with this, by Anonymous Coward · · Score: 0

    we can continue mountain top removal?