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Electrolytic Etching, For What A Dremel Can't Do

Dustin writes "A lot of people modify computer cases, often requiring them to cut intricate custom designs in sheet metal. For most, there is the Dremel tool. But sometimes, that just isn't good enough. Possibly due to an insanely complex design, or unsteady hands, a Dremel just might not cut it (pun honestly wasn't intended). JimBob, a member at OverhauledPC.com, has a much better way. Using readily available salt water and electricity, his technique is much easier than trying to cut patterns with a rotary tool."

45 of 242 comments (clear)

  1. Coral Cache, just in case... by BobPaul · · Score: 4, Informative

    I preloaded this into the Coral Cache, just in case it gets slashdotted.

    Here's the Cache Link if it's needed.

    1. Re:Coral Cache, just in case... by techno-vampire · · Score: 4, Funny

      Your link is currently 404 compliant.

      --
      Good, inexpensive web hosting
  2. Dremels are bad web server too by Anonymous Coward · · Score: 2, Funny

    Or maybe someone used one in the server network cable... no comments and down.

  3. My guess at his method... by Faust7 · · Score: 4, Funny

    Using readily available salt water and electricity, his technique is much easier than trying to cut patterns with a rotary tool.

    The site is down. Therefore I will assume that he poured water over the case and shocked the shit out of it.

    You could get some interesting burn patterns that way. You might even match your case.

  4. slashdotted already. by gambit3 · · Score: 2, Funny

    any of the paying Slashdotters wanna grace us with the text?

    I promise you'll get lots of Karma for it! ;)

    1. Re:slashdotted already. by elid · · Score: 4, Interesting

      Let me introduce you to mirrordor.

    2. Re:slashdotted already. by nxtr · · Score: 3, Funny

      >>Let me introduce you to mirrordor.

      The Mirrordoor? Is it like the door where you see your self coming into? It only managed to cache the introduction page of the website.

  5. Wait a minute. by Tackhead · · Score: 4, Funny
    > Electrolytic Etching, For What A Dremel Cant Do

    First off, there's nothing a Dremel can't do.

    But since your alternative involves electricity, water, and chemicals, we'll forgive it. (But next time, could you kindly use something more dangerous than sodium chloride? We've got reputations to uphold here, and if the case mod weren't so danged cool, we'd feel we were slipping.)

    1. Re:Wait a minute. by Ann+Elk · · Score: 4, Funny

      Try it without the chloride.

    2. Re:Wait a minute. by Tumbleweed · · Score: 4, Funny

      there's nothing a Dremel can't do

      Welll, let's be fair, here, there _are_ some things that a Dremel can't do. But that's what duct tape and/or WD-40 are for!

    3. Re:Wait a minute. by kryogen1x · · Score: 5, Funny
      Try it without the chloride.

      That, or NaCl sans sodium. Gotta love those chlorine fumes.

    4. Re:Wait a minute. by Aglassis · · Score: 3, Informative

      You said: "I encourage you to try it without the sodium... chlorine ions are, shall we say, not very good for you. Salt may dissociate in water, but it's safe there in equal quantities. Surprising that something so bad for you doesn't violate sanjimon(?)'s principle."

      And chlorine isn't good for the metal either. If you are interested in preserving the mechanical properties (especially the surface properties), using chlorine in an electrolytic metal removal process is a bad idea (in general, any electrolytical metal removal process will contaminate the remaining surface). Many bad types of corrosion are started with just a little bit of chlorine. Do a google search for chloride stress corrosion cracking for one of the very worst types of corrosion known.

      Anyone interested in using electrolytic metal removal for any project that is under high temperature and stress (a case mod *probably* won't qualify) should definately not use the NaCl procedure. In fact, if you ever want to do a project under high temperature and stress you need to carefully monitor the exposure of chlorine, oxygen, hydrogen, and sulfur ions (to name a few) as well as things like the pH to ensure that your piping doesn't fail.

      --
      Suddenly, the hairy finger of a familiar monkey tapped me on the shoulder. It was time.--G. T.
    5. Re:Wait a minute. by WhiteDragon · · Score: 2, Interesting

      I can verify first hand the corrosive power of chlorine. When the US Postal Service was anthraxed, we cleaned out the Trenton New Jersey Processing and Distribution Center with Chlorine gas. It killed the anthrax, but just about all the mail processing equipment had some damage due to corrosion, and a great deal of it was so corroded that it was a total loss.

      --
      Did you mount a military-grade, variable-focus MASER on an unlicensed artificial intelligence?
  6. Excellent... by Gorffy · · Score: 5, Funny

    Now, instead of merely cutting myself, I can electrocute myself as well. I love case modding!

  7. Slashdot Kicks In by queenb**ch · · Score: 2, Funny

    Well, either they've taken their site down, or the "Slashdot Effect" has kicked in. They're gone.

    Rats! I wanted to see how this works - suprise my boyfriend by etching the fenders on his 69 Mustang ;)

    2 cents,

    Queen B

    --
    HDGary secures my bank :/
  8. What about what a Dremel CAN do? by Ghostgate · · Score: 4, Funny

    Let's see your fancy "salt water" and "electricity" do this!

    1. Re:What about what a Dremel CAN do? by chadjg · · Score: 2, Funny

      Thank God for morons with active imaginations and spare time. There is always one in every crowd that is willing to eat worms, spray stuff with hairspray and the light it, or spin CDs to destruction.

      Our lives would be so much duller without them.

      --
      Why do I have this? I don't smoke.
  9. "much easier", where's the fun in that? by AC-x · · Score: 3, Funny

    What a true geek would do is build their own computer-controlled laser cutting/etching rig, a few of these together should cut through aluminium or mild steel no problem :)

    1. Re:"much easier", where's the fun in that? by Anonymous Coward · · Score: 3, Interesting

      Even better than wimpy lasers--a friend of mine built a CNC plasma cutter for his metal crafting business (http://texasmetalcraft.com/TMC/pictures.htm). The pics don't do it justice-he once sent me a video that really let you see the plasma head melting the 1/4" steel...and making extremely precise cuts in the process. What could be better--computers+high voltage+very high temperatures+the possibilty of really frying yourself!

    2. Re:"much easier", where's the fun in that? by RockClimb · · Score: 2, Informative

      In theory this MIGHT be possible. In reality a 50W CO2 laser WILL NOT cut sheet metal. A quote from this site "Metal Cutting is "Not" possible, however the system does a fine job of "Etching" Anodized Aluminum" and they are talking about a 50W laser. While my 35W can make a piece of ceramic tile glow red/orange where the laser hits it, it will not even make a mark on steel.

  10. To summarize... by syukton · · Score: 4, Informative

    I'll try to summarize this since I managed to read the first few pages before the horde of slashdot ate the website.

    You take two plates of metal and hold them parallel (not with your hands, they're going to be electrified!) underwater. Electrify the plates and the positive ions in the water will collect at the negative terminal and the negative ions will collect at the positive terminal. By adding some salt to the water however, you can encourage a chemical reaction to happen at a given electrode. By covering the metal with paint or duct tape, you insulate it from this effect. So what they're doing is, essentially, painting around the hole they want to cut, leaving the hole itself barren, then submerging it in saltwater and electrifying it, causing the exposed metal to oxidize and be eaten away.

    It's roughly the opposite of electroplating, which is the procedure which this technique is likened to in the article. Instead of trying to accumulate more on a given electrode you're trying to reduce the amount of matter present there.

    --
    Reinvent the wheel only at either a lower cost, greater effectiveness, or your own personal enrichment and satisfaction.
    1. Re:To summarize... by Vellmont · · Score: 4, Informative


      By adding some salt to the water however, you can encourage a chemical reaction to happen at a given electrode.


      No, the salt is to reduce the electrical resistance of the water and create a greater current flow. Pure water actually has a high amount of electrical resistance. Oxygen will collect at the positive electrode, and hydrogen will collect at the negative (the article author is a bit confused and thinks this is methane).

      You're correct about the rest of your summary though.

      --
      AccountKiller
    2. Re:To summarize... by MConlon · · Score: 2, Informative

      Actually, you're going to get hydrogen and chlorine at the electrodes and be left with a solution of sodium hydroxide.

      Chlorine gas is poisonous. Fortunately it's heavier than air so it shouldn't fill the room or anything. Sodium hydroxide is caustic.

      MJC

    3. Re:To summarize... by EggplantMan · · Score: 2, Informative

      No, it doesn't. At room temperature and pressure pure water self ionizes (slightly) and gives it a non-finite resistance.

      --

      ?-|||-----x<*))))><
  11. methane gas???? by Anonymous Coward · · Score: 2, Informative

    how do you produce methane from NaCL, H2O, and Fe ???? I think only H2, and O2 are emitted!!

  12. The 2005 Darwin award goes to! by HockeyPuck · · Score: 3, Funny

    Yeesh, you would have thought the kid would atleast have worn long sleaves and a face mask (welding mask)... They did this on Mythbusters and the fragments when into the human flesh like gel about 2inches...

  13. Effects to look into by Striker770S · · Score: 2, Funny

    One of my friends reminded me the other day of a time when he was making his cooling system. After a while of playing, his computer made wierd noises, and so by looking through the case window we could notice that his cooling system did not work. Basically it looked like a carwash inside his computer. I feel that the best case designs come from mistake, even though that mistake cost him his wonderful computer parts. But lego cases look cool too.

    --
    I thought what I'd do was, I'd pretend I was one of those deaf-mutes. - Catcher in the Rye
  14. Dremel Casemod by HighBit · · Score: 2, Interesting

    Kinda apropos, dremel has a Case Modding Project on their website. They cut the word DREMEL into a case. Looks nifty.

  15. Can also be done in a much simpler... by Lisandro · · Score: 5, Informative

    ...(and safer) way with FeCl3 (ferric clhoride), the very same stuff used to etch circuit boards by hobbyists arround the world. Since it attacks most metals, you can do complex chemical etching with it: i've seen small plates with logos done that way - you just have to find a way to mask the design somehow. It requieres no electricity as well.

    FeCl3 is cheap, relatively safe (don't eat it kids!), and easy to handle. It stains like a bitch though, and will attack most metals so be careful with spills.

    1. Re:Can also be done in a much simpler... by Bootle · · Score: 2, Informative
      All Ferric Chloride does is eat copper. To make a design, you still need to mask it somehow.

      Something as simple as a magic marker can be used, but it will probably look like ass. A better idea is to use a photo-resist kit. With this you spray the metal surface with a chemical that will protect it from the FeCl_3. The kicker is that light will eat away this protection. So you print your design onto an overhead transparency or something, place that atop the metal, and affix it to a window for a while.

      Using these kits is a great way to make high quality designs, and it easy to transfer the design to the metal surface. The drawback is a limit in size and perhaps cost

      Computer chip manufacturors use essentially the same technique, except their designs are so small that the wavelength of visible light is too wide! So they moved towards UV and now are starting to have a lot of problems trying to shrink farther.

      I went to radio shack's site to look up some info on PCB etching kits and, seriously, far too many of the search hits were for HP computers and photo-printers. So sad...

    2. Re:Can also be done in a much simpler... by Lisandro · · Score: 2, Informative

      The two simplest ways i've found to transfer designs for FeCL3 etching were:

      1) Press-n-peel blue, which is a sheet of material that will stick to a surface only where it's printed. It's hard for me to find it where i live, so what i use is...

      2) Laser printer and satin ("photo") paper. Laser printer toner is 100% waterproof and melts when heated; you print you design, mirrored, onto a satin paper sheet, then iron it over the metal (previously cleaned and degreased with alcohol), and carefully peel it, soaking it wet if needed. If done right the toner sticks to the metal, making a perfect etch mask.
      I do this all the time and it works great; just google for more info on the procedure.

      Both work great for PCBs. If you need to etch a piece of metal, you do the same and paint the sides of your metal block (a waterproof marker works just fine). You clean it well with water to remove the etchant and isopropyl alcohol to remove toner/ink, and voila!

    3. Re:Can also be done in a much simpler... by Dan+East · · Score: 3, Interesting

      I've been using Staples Picture Paper to transfer the ink to PCBs (you have to print your mask with a laser printer - inkjet won't work). That particular brand of paper works extremely well, as determined by a fellow who tested dozens of types of glossy photo-quality printer paper to see what transferred toner the best.

      I don't see why this wouldn't work on cases. You use an iron to transfer the toner from the paper to the surface to be etched. Extremely narrow traces can be obtained ("MUCH less than 0.01 inches") with this method, so I'm sure it would give good results for case mods.

      This website has the detailed instructions:
      http://www.fullnet.com/u/tomg/gooteepc.htm

      Dan East

      --
      Better known as 318230.
    4. Re:Can also be done in a much simpler... by whitis · · Score: 2, Informative

      ...(and safer) way with FeCl3 (ferric clhoride), the very same stuff used to etch circuit boards by hobbyists arround the world.

      I have forgotten a lot of chemistry over the years. I thought Ferric Chloride works as an etchant for copper because the chlorine prefers copper to iron so it is happy to trade an iron atom for copper. But why would it trade an iron atom for another iron atom? Now in a solution, there will be free chlorine and iron ions floating about so the chlorine may etch the steel but I would not expect it to do as well as a compound that combined chlorine with something less desirable than iron. Maybe FeCL3 would rather combine with another Fe to produce two molecules of FeCL2. That would make sense. Some people do use ferric chloride on steel and stainless steel but reportedly it quickly builds up an oxide layer on steel that must be sanded off before it will continue etching. In stainless steel, the ferric chloride attacks the chromium (chromium chloride is very soluable in water) so it neutralizes the "stainless" in "stainless steel" making it more vulnerable.

      I also wonder why you suggest FeCL3 is safer. Is this because there is no need for an electric current (and the free oxygen and hydrogen it produces?) which produce an explosive gas mixture and may also combine with components of steel to make other compounds.

  16. I used to do that with nitric acid by museumpeace · · Score: 3, Informative

    Works on brass too. but its harder to get ahold of that stuff nowadays. Drano will probably work faster on Aluminum and not require electricity but you got to play with the concentrations or the process will heat up so fast it will melt your resist.

    --
    SLASHDOT: news for people who can't concentrate on work or have no life at all and got tired of yelling back at the TV.
  17. Re:Salt + Electricity... by Anonymous Coward · · Score: 2, Informative

    Not directly dioxins, but it does make covalent chlorine, which often ends stabilizing as dioxins. Even if it ain't that, its still BAD (worse than not putting comments in code, Broken As Designed).

    Unfortunately, I was unable to load the article - so I can't comment on the procedure involved. But if you haven't studied electrochemistry to at least a small extent to know whats going on (and I know people with B.S. in chemistry I wouldn't trust with understanding reactions in this catagory), its best you DO NOT try this. The procedure listed may be completely harmless, I can't say without having access to reading the procedure. But if you are someone (like most slashdotters) who doesn't hesitate at "improvising", stick to the dremel.

  18. Bad guide by s0rbix · · Score: 3, Insightful

    This is a terrible guide. Several times he says "make sure you know what you're doing" but offers no help or explanation. It is poorly worded and offers little guidance. The pictures do not help at all, either. Does anyone know of a better guide for electrolytic etching?

  19. Easy design masking by Weaselmancer · · Score: 2, Informative

    ...you just have to find a way to mask the design somehow

    Easily done. Head to Techniks or some other similar place and get some Press 'n Peel PCB transfer film.

    Draw what you want to etch as a negative and then iron it onto your metal. Dip the whole thing in the acid bath and wait a bit. Steel wool to clean off the resist and that should do it.

    If you're really cheap, toner is a decent resist. No different than making a homebrew PCB.

    --
    Weaselmancer
    rediculous.
  20. Tape, knife, and bead-blaster by RiffRafff · · Score: 2, Insightful

    Cover the "canvas" with masking tape. Draw your design. Cut out your design with a sharp X-Acto blade. Etch the exposed design with a bead-blaster (like a sand-blaster, but uses smaller, more uniform glass beads, and doesn't eat away as much, as fast).

    Been doing this for years.

    --
    "I might have made a tactical error in not going to a physician for 20 years." -- Warren Zevon
  21. A link dug from the hurlage by sl4shd0rk · · Score: 2, Informative

    I managed to grab a link out of the page from mirrordot before it went tits-up again. This is the link the guy got part of his idea from.

    http://gravert.club.fr/galvetch/contfram.htm

    --
    Join the Slashcott! Feb 10 thru Feb 17!
  22. Are you sure it's not electrodynamic machining? by Ungrounded+Lightning · · Score: 3, Interesting

    This technology is nothing new. My father built systems to do R&D and production using Electro Chemical Machining. [...]

    Items used every day may have under gone this process, turbine fan blades, air bag explosive chambers, hard drive motors (meow), test sabot rounds for tanks.


    Are you sure those are all built by electrochemical machining? I suspect some of them are built by its close relative: electrodynamic machining.

    Electrochemical machining is reverse electroplating. It pulls metal atoms out, not just from the cut, but from the surrounding metal that is intended to remain, changing its properites.

    Electrodynamic machining is a spark to the workpiece through a dilectric solution (typically water or oil). It can cut through anything that can be made to conduct. (You do diamonds by flashing a bit of metal over them for the initial contact. As you're removing diamond, the surface that's left has a microscopic layer that is converted to graphite to keep you going.)

    Three sorts of tools:
    - Use the end of a wire as a drill. (Feed the wire as the end erodes.)
    - Use the side of a wire as a bandsaw. (Feed the wire in the inches-per-minute range so the cutting edge is always smooth and of a known size.)
    - Make a graphite electrode in the shape of the hole you want and burn your way in. (Graphite doesn't erode much at all. Replace as needed.)

    Cutting action: The spark vaporizes a path through the dilectric and melts a tiny pit in the workpiece. (Polarity is chosen so most of the melting is on the workpiece.) When the spark stops the channel collapses and the shockwave blasts the molten material out of the pit before it can re-harden. Repeat at a rate in the kilohertz range. Spark generally forms at the shortest space, which is where you want to remove the most metal, giving you a mirror finish.

    (This effect was originally discovered in Russia about WW II when an engineer tried increasing the life of ignition "points" by putting them in an oil bath to cool them. They disintegrated within hours. It's also why you always use a brush to run current around a lubricated ball- or roller-bearing instead of passing it through the bearing: The effect would destroy the bearing surfaces in a similarly short time.)

    The cut-away material ends up as a contaminant in the dilectric. So you pump that through a filter to clean it out.

    Motion control is paramount: You sense the spark voltage to tell how far you are from the workpiece and use it for feedback, advancing or backing up to keep your spark path at the correct length.

    Contaminants (especially chips) sometimes short the gap, so you back out until you clear it and can spark again. Sometimes you end up machining away the chip. Sometimes you may have to back far - even completely - out of a cut to clear the contaminant from your gap. This may mean retracing your path around several turns. (In the shaped-carbon-rod drill-in mode you also run the rod in little circles and/or back-and-forth it now and then to pump the dirty dilectric out and clean stuff in.)

    You're CONSTANTLY backing-and forthing. MOST of your tool motion is back-and-forth, a small fraction is motion into the workpiece as the cut advances. So you MUST use an integer motion-control algorithm that retraces its steps exactly (or within an LSB or so) and doesn't accumulate roundoff err. Any accumulated roundoff, even a TINY bit, quickly walks you out of your path and into the workpiece, shutting you down.

    The device is essentially a big power supply, a resistor, a switch, a voltage measurement peripheral, a computer, a motion table, and a dilectric pump/filter. Most of the energy ends up in the resistor. You do it that way as the easy way to control the spark's waveshape. The switch might be a bunch of paralleled FETs on a big heatsink. The resistor might be a bunch of foot-long power resistors, with a fan blowing on them so you can run them far beyond their normal ratings, carefully wired to minimize parasitic inductance.

    That's the bulk of the specialized knowlege you'd need to build one, as they were about 15-20 years ago (when I did software for one).

    --
    Bantam Dominique roosters crow a four-note song. Once you've heard it as "Happy BIRTHday" you can't NOT hear it that way
  23. Re:Acid? by DarkMan · · Score: 2, Informative

    Roughly speaking, you don't use acid because you would need too much of it, and it sucks at cutting, and at giving neat edges. Oh, and resists are difficult, and it's slow.

    Resists: You need something that is resistant to the acid, but can be applied neatly, and removed neatly afterwords. It needs to adhere well to the metal surface, yet be resistant to the acid and to water, and any by-product produced. Also, it needs to be resistant to exfoliation - as you start to etch, it's no good if your resist falls off around the cut. Oh, and it needs to be cheap and easily available.

    Rates: Acid is slow. Or, rather, acid's that you would want to use for this purpose are slow. Anything that can eat through steel or aluminum at a decent rate is not something you want to handle. (Consider: What do you store it in, and what do you do the reaction in? Both are doable - but not strightforward). So you're left with acids that don't eat the metal very fast.

    Edges: With an electrical current, you can ensure that the direction of cutting is more or less perpindicular to the surface of the metal (that's why it's two large plates, for example). With an acid, that's not the case. They will tend to etch out round indentations under the edges of the resist - giving you razor sharp edges to your cut out. Which would need filed down afterwords, and means there is a minium thickess of cut, proprtional to the thickness of the sheet.

    My back of envelope sums suggest that the miniumum width of cut by acid etch is roughly equal to the thickness of the material, assuming an infitessimally small start. For 1.2 mm sheet metal, that's a 1.2 mm width - easily doable with a Dremel.

    It would also take around 3-4 months, I think.

    Acids are good at etching a surface layer. I would use an acid if I wanted a matt surface - for example, to etch details onto sheet metal. A combination of cut outs and etching would work very well in giving a unique appearence to a panel.

  24. Salt = Bad by the+pickle · · Score: 2, Informative

    Using salt for this will produce chlorine in addition to oxygen.

    Use baking soda or sodium hydroxide instead. Either electrolyte will give off substantially less-dangerous byproducts.

    p

  25. Electrolytic deplating is for pussies. by sakusha · · Score: 2, Interesting

    A REAL geek would use Explosive Forming.

  26. Not H2+O2- H2+BLEACH! by Homer's+Donuts · · Score: 2, Informative
    The O2 will not come off as gas, but will react with the Na+ and Cl- to form NaOCl in water (Bleach).


    The 40% solution mentioned in the article probably limits the strength.


    Keep it off of your 501's or we will know you can't use a Dremel tool.


    From: Electrochlor.com




    1.2 Reactions
    The principle reactions occurring in the electrolytic cell that produces sodium hypochlorite are quite simple, as shown in the following:

    Oxidation of the chloride ion occurs at the anode:

    2Cl- -> 2Cl2 + 2e-

    Followed by a rapid hydrolysis of the chlorine:

    Cl2 + H2O -> HOCl + HCl

    Reduction of the sodium ion occurs at the cathode:

    Na+ + e- -> Na

    Followed by a rapid reaction of the sodium with water:

    Na+ + H2O -> 1/2H2 + NaOH

    The acids (HCl and HOCL) produced at the anode react with the base (NaOH) produced at the cathode:

    HCl + NaOH -> NaCl + H2O and,
    HOCl + NaOH -> NaOCl + H2O

    The net reaction of electrolysis is:
    NaCl + H2Oe- -> NaOCl + H2

    The amount of hypochlorite produced is related directly to the amount of direct electrical current passed through the cell.



    Easier to read on web site. I had to hack in '->'s.