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New Photovoltaics Made with Titanium Foil

Memorize writes "A company called Daystartech has released a new type of photovoltaic cell which, unlike almost all the cells currently in use, does not silicon. This is based on a thin titanium film. Given the current shortage of solar-grade silicon, and all-time high oil prices, maybe titanium solar panels are here at the right time. The questions are, will they release it as a consumer solar product, and what will be the price per kilowatt hour?"

78 of 346 comments (clear)

  1. Slicon Shortage by klausner · · Score: 4, Interesting

    Like, you think that titanium, and the equipment required to work titanium comes cheap? Cheaper than sand?

    1. Re:Slicon Shortage by darkmeridian · · Score: 4, Insightful

      It's not meant to replace largescale silicon photovoltaic cells. Instead, it's meant for use on UAVs and balloons and stuff. Price doesn't matter here, right?

      --
      A NYC lawyer blogs. http://www.chuangblog.com/
    2. Re:Slicon Shortage by dbIII · · Score: 4, Informative
      Like, you think that titanium, and the equipment required to work titanium comes cheap? Cheaper than sand?
      Titanium is also available in sand, most commonly in the form of rutile and ilmanite. Most readers here have probaly eaten titanium dioxide taken from sand, it is frequently used as a white food colouring and paint pigment.

      It costs a lot to do anything with titanium because the oxide forms quickly on any exposed surface and takes a lot of energy to break down.

    3. Re:Slicon Shortage by dgatwood · · Score: 3, Interesting
      What I don't understand is what the heck they are doing to convert SiO2 into Si and O2 that would result in toxic byproducts. Don't they just electrolyze it? Chlorine from CaCl2 and other contaminants notwithstanding, I don't see how producing silicon from sand would be worse than any other silicon production mechanism....

      I was under the impression that most of the toxic byproducts inherent in working with silicon were the result of the doping process wherein elements like germanium and arsenic are added to the surface silicon to create transistors, diodes, gates, etc. I would expect using a titanium substrate to require something similar. Would it not?

      --

      Check out my sci-fi/humor trilogy at PatriotsBooks.

    4. Re:Slicon Shortage by Rei · · Score: 5, Informative

      Slicon?

      The interesting thing here is that the fastest growing solar cell market is not silicon: it's organic solar cells. They're incredibly cheap, but currently inefficient. However, their efficiency has been growing dramatically. One company, nanosolar, claims to have achieved almost the efficiency of amorphous silicon cells. Their patent is rather interesting, and well worth a read.

      --
      I once listened to a Philip Glass record for an hour and a half before I realized it was skipping.
    5. Re:Slicon Shortage by Rei · · Score: 5, Informative

      Monocrystalline silicon is incredibly expensive. Polycrystalline silicon (which has largely taken over in the solar cell market) is simply "very expensive". Silicon is common, but pure silicon crystals require clean-room conditions to grow.

      Titanium isn't that rare. The ore isn't the primary cost component (like, say, gold). Instead, like aluminum, the main costs are in refining. Unlike aluminum, however, there is currently no continuous production process - only an expensive batch production process. Even the inventor of the process, William Kroll expected to have it be replaced within decades of its implementation in 1940; no suitable replacement was found, however.

      Fortunately, it looks like there are some on the horizon. Most interestingly, it appears that electrolysis can be conducted directly on titanium oxide (this has huge potential applications for other hard-to-refine metals as well, and may allow for the creation of new alloys). There's also a aluminum-style molten-salt electrolysis process (FFC-Cambridge) in testing.

      Titanium isn't inherently hard to work with, persay; you just need to be properly equipped to work with it and experienced with it. You have to use *very* pure argon in welding, and you have to keep the argon going for longer after you take the heat off. You also have to avoid working it with aluminum tools, which can alloy with the metal and weaken it. Etc.

      There are some benefits, though. Impurities in titanium are very easy to spot, as they tend to discolor. Also, titanium is *very* fatigue resistant, and aircraft with titanium structural components have sometimes even been found to be stronger after being flown a few times than when they were built.

      --
      I once listened to a Philip Glass record for an hour and a half before I realized it was skipping.
    6. Re:Slicon Shortage by Chrispy1000000+the+2 · · Score: 2, Insightful

      Well, electrolysis isn't cheap. Why do you think we recycle alumnium? There is probably some other mechanism that they use that is just a few dollars cheaper. Any chem majors who are further along want to back me up or squash me like the petty bug I am?

      --
      Sig
    7. Re:Slicon Shortage by Rei · · Score: 4, Informative

      I should also add that titanium is really just the backing. It's a great backing, given it's strength and condition-tolerances compared to its mass, but it's not what generates the power The cell itself is actually a copper-indium-gallium-diselenide cell - not that it's cheap, either ;)

      --
      I once listened to a Philip Glass record for an hour and a half before I realized it was skipping.
    8. Re:Slicon Shortage by Qzukk · · Score: 5, Informative

      Yes, actually. This isn't just some sand scooped off a beach. Solar panel grade silicon comes from the leftovers after semiconductor grade silicon users have picked through their crystal wafers, which is why there is a shortage in the first place, since there is a narrow range of quality ("almost" good enough for semiconductors). As for titanium, my 30 year old encyclopeda says its one of the 10 most common metals on the planet. Titanium Oxide is cheaply produced and used liberally in paint.

      Titanium is malleable when hot (meaning you can flatten it into foil). So producing titanium foil is probably not a difficult task, depending on how hot "hot" is. (Though the article mentions that the titanium foil used is thinner than household aluminum foil. The process looks like it would be easy anyway, but time consuming.)

      As for your post on waste products, the most common smelting procedure in use works without catalyst or flux to produce pig-iron and Titanium Oxide, though this process is common because of its use in paint. This process was recently developed for producing metallic titanium, its outputs are salt (NaCl), titanium, and whatever impurities get washed into the liquid sodium stream and removed later.

      --
      If I have been able to see further than others, it is because I bought a pair of binoculars.
    9. Re:Slicon Shortage by ikeleib · · Score: 4, Informative

      Also, titanium is *very* fatigue resistant, and aircraft with titanium structural components have sometimes even been found to be stronger after being flown a few times than when they were built.

      The above refers to one aircraft in particular. The SR-71/A-12 was found to have a stronger airframe after flight. This is not really due to titanium itself, but rather the gentle heating and cooling that the aircraft underwent with each flight. It annealed the metal, thereby making it stronger and helping to eliminate the fatigue that is normally problematic in airplane structures.

    10. Re:Slicon Shortage by Anonymous Coward · · Score: 2, Informative

      Electric arc smelting != electrolysis.

      It takes much less energy to melt metallic aluminum than it does bauxite.

      Electrolysis, however, is used to make bullion [sp]. Smelt down gold ore. Electrolysis the gold from that ingot. Resmelt the electrolysis product to make .9999% pure gold bullion.

    11. Re:Slicon Shortage by Anonymous Coward · · Score: 5, Funny

      I've achieved self-replicating organic solar cells in my back yard. Some of them are even tasty.

    12. Re:Slicon Shortage by Arthur+Dent · · Score: 4, Interesting
      Actually a new titanium refining process was discovered a short while ago

      Here we report an electrochemical method for the direct reduction of solid TiO2, in which the oxygen is ionized, dissolved in a molten salt and discharged at the anode, leaving pure titanium at the cathode. The simplicity and rapidity of this process compared to conventional routes should result in reduced production costs and the approach should be applicable to a wide range of metal oxides.

    13. Re:Slicon Shortage by digitalchinky · · Score: 4, Interesting

      The USA has miles upon miles of old military aircraft from what I've seen on television. There should be quite a large amount of titanium left in wing attachments, turbines, and other hard points on decaying fighter jets. I have a small rod of it (from an Airforce friend) that was scrap from an F-111 wing repair. Not very big, but big enough to see how damn strong the stuff is. (few centimeters long)

      Took some serious hitting with a sledge hammer and a vice to put any kind of a bend in the metal. Impressive stuff.

    14. Re:Slicon Shortage by slide-rule · · Score: 3, Interesting

      Also, titanium is *very* fatigue resistant, and aircraft with titanium structural components have sometimes even been found to be stronger after being flown a few times than when they were built.

      As an mildly interesting bullet to follow that of parent's, titanium can apparently "catch fire" under the right conditions (that being high temperature and pressure). I hadn't conceived of this until working at my current engineer job where commercial and military aircraft engines get made ... past a certain point in the compressor section, Ti can't be used any more for fear of wholly losing the rotor/stator part to "titanium fire". (Aside from chem-geeks, who knew?)

    15. Re:Slicon Shortage by WormholeFiend · · Score: 3, Funny

      Now you can wear your tinfoil hat

      Don't you mean "your Ti foil hat"?

    16. Re:Slicon Shortage by dhovis · · Score: 4, Informative

      IIRC, the problem with titanium is not so much that the raw material is expensive. The problem is not even so much that it oxidizes readily (aluminum does too). The problem is that it has a high melting point, and is very difficult to forge and to machine.

      Pure Ti-metal has a hexagonal close packed microstructure (HCP). Most other metals have a cubic structure (either face centered cubic:FCC or body centered cubic:BCC). FCC and HCP have the same packing effficincy, but it is much easier to form and move dislocations in a lot of different directions in either FCC or BCC than for HCP. Dislocations are necessary for forging, and forging creates such a tangle of dislocations that it actually strengthens the material.

      That is why Apple moved away from Ti for Powerbooks, IMHO. It impossible to economically bend the titanium to form the laptop shell without making the metal so thin that it is way to flexible. So the old Ti-Powerbooks had a Ti top and bottom, with Ti-painted plastic in between. This paint invariably started to flake, which led to lots of complaints. Apple wisely switched to an aircraft grade of aluminum, which can be sufficiently bent and machined to form the entire shell of the laptop, not just the top and bottom.

      Anyway, that is the basics. IAAMSBTDNCMA (I am a materials scientist, but this does not constitute materials advice)

      --

      --
      The internet is the greatest source of biased information in the history of mankind.

    17. Re:Slicon Shortage by theshowmecanuck · · Score: 5, Informative
      They don't use sand to produce silicon, they use quartz rock. They reduce (redox reaction) the SiO2 using coal and charcoal to produce the initial Silicon metal(oid). Or to put it in layman's terms, it is smelted in a reaction similar to reducing iron in a blast furnace (except with silicon, it is done in a three phase AC powered arc furnace). The reactions happen in the gas phase at over 1400 degrees C. Chunks of quartz are more suitable since the gases can move between them. Sand just clogs things up... kind of like smothering a fire.

      Si02 + 2C = 2CO + Si

      Once this silicon is produced, it is refined into super-pure semiconductor grade silicon, or more usually, into silicone rubber pre-cursors. I used to work in silicon smelting R&D and so I have some idea about what I'm talking about. (We built and ran the worlds largest direct current arc furnace during a series of pilot runs in the early 90's to research making lower cost silicon. That was before Russia opened up. After they did, they flooded the market with cheaper silicon, and there was no point trying to create lower cost silicon.) The biggest use of silicon is in making silicone rubber (but not so many boobs any more). The raw material for ultra-pure silicon is taken from the raw material (not so pure silicon) used for silicone production.

      Anyway, smelting silicon creates large volumes of CO. CO (carbon monoxide) is highly flammable, on the order of natural gas, and usually burns off to C02 at the top of the furnace bed. (CO could be used as a fuel like natural gas, but it is so poisonous it is not really safe to do so.) Since coal and charcoal are used in the process, other carbon by-products are also released, mostly in gaseous form. E.g. like the stuff that makes up tars and such... a little nasty... but quite small relative to CO and CO2 since the high temperature tends to atomize them. However, some of the coal and charcoal does burn away in the upper part of the furnace (where it is relatively cooler) and before it gets a chance to react. As well as producing some not so nice gases, it is a very energy intensive process. Silicon is never found in elemental form in nature. It must be separated from SiO2, which requires a lot of power, which in turn needs to be produced at generating stations.

      As far as silicon used in semi-conductors goes, I'm not sure if they use electrolysis to refine it to ultra-pure levels. Maybe in some sort of deposition process from a gasous phase, but I am just guessing from what I have read in general chemistry related articles. The details of that type of processing are usually very top secret so I am not sure who could or would comment on that. And I mean either industrial secrets and likely in a military sense as well (it is probably of strategic value).

      --
      -- I ignore anonymous replies to my comments and postings.
    18. Re:Slicon Shortage by K8Fan · · Score: 5, Interesting
      Took some serious hitting with a sledge hammer and a vice to put any kind of a bend in the metal. Impressive stuff.

      Want to see something really cool? Check out "Liquidmetal". It's an alloy of titanium and other metals and has some really amazing properties. For one, it can be cast and does not form crystals like titanium, has a low melting tempature compared to it's component metals - it can actually be injection-molded. It's twice as strong as titanium by weight and much more flexible. There's a bounce-test video on their web site that it a hoot.

      Right now it's being used for the hinges in that new Motorola Razor phone, various sporting goods and military applications. Cool stuff.

      --
      "How perfectly Goddamn delightful it all is, to be sure" Charles Crumb
    19. Re:Slicon Shortage by dbIII · · Score: 4, Informative
      The problem is that it has a high melting point, and is very difficult to forge and to machine.
      It is difficult to forge and machine due to the oxide layer - which is very hard and one of the reasons we use it in the first place (it's mostly used in chemical plants). It isn't really a good choice for a laptop since it costs so much to make and is very difficult to do anything with - and aluminium conducts heat better and can be formed while soft for the aircraft grades - the stuff the early 20th century airships were made out of.

      The metal itself has a high strength and hardness, but there are plenty of steels harder than it. The oxide layer is very hard, and as soon as you chip some away it forms again. A slightly harder compound, titanium nitride, is the gold coloured stuff you see plating the tips of cutting tools.

      If the oxide is being used in these cells the process may be surprisingly cheap, since the hard bit is reducing the oxide to metal. If it's something else, there may be ways of making it cheaply from an ore - a mineral sand. If a vapour is being sprayed onto a substrate it might not cost a lot either.

      I'm not a materials scientist anymore, but for a while when I was I used to teach engineering students how to break things under controlled circumstances - and find out why stuff broke under uncontrolled circimstances.

    20. Re:Slicon Shortage by theshowmecanuck · · Score: 4, Informative
      It's possible. It could be a type of co-generation. The idea is used in a lot of places, but usually it involves using excess heat to produce steam, or waste steam. It would be a good idea.

      Something to think about: in order to be flammable you need concentrations of at least 5% CO in air (about the same as needed for natural gas). That's 50000 ppm. To put it in perspective if you were in a room with 800 - 1000 ppm CO for several hours, you would likely end up dead. If you walked into a room with 4000 to 5000 ppm CO, you might not even know what hit you as you hit the floor. It wouldn't be long before you died. So basically, if you used it for a fuel source, it would really suck if the pilot light went out. Maximum OSHA allowable limits in the workplace is 35 ppm. In the middle of typical rush hour traffic (I measured it with a portable meter): 50 ppm! Mind you in industry you are usually indoors where it can concentrate, and often there are very high levels behind it (our offgas lines had 75 to 80 % pure CO... even small leaks were dangerous... we had monitors and venting systems and escape air bottles everywhere).

      --
      -- I ignore anonymous replies to my comments and postings.
  2. To silicon or not to silicon, that is the question by eviloverlordx · · Score: 5, Funny

    Of course, once we decide, we'll need to find out what 'to silicon' actually means...

    --
    'Loose' is when your pants are three sizes too big. 'Lose' is when you misuse 'loose'.
  3. I gotta say... by SparksMcGee · · Score: 5, Funny

    I confess I've always had a problem with power sources that do silicon. Snooty bastards, what with their made up verbs and their rock music...

    1. Re:I gotta say... by ackthpt · · Score: 2, Interesting
      I confess I've always had a problem with power sources that do silicon. Snooty bastards, what with their made up verbs and their rock music...

      How about consumer devices that rely so much on silicon? I've wondered why germanium or something else with a lower switching voltage isn't used more often.

      --

      A feeling of having made the same mistake before: Deja Foobar
    2. Re:I gotta say... by DoubleD · · Score: 2, Informative

      http://www.geek.com/news/geeknews/2003Jun/bch20030 616020429.htm

      --
      "He is no fool who gives what he cannot keep in order to gain what he cannot lose."
    3. Re:I gotta say... by FLEB · · Score: 2, Informative
      --
      Information wants to be free.
      Entertainment wants to be paid.
      You just want to be cheap.
  4. How does this compare? by AtariAmarok · · Score: 4, Interesting

    How does this compare to what is used as solar cells in spacecraft now? Sounds interesting. Imagine, not a beowulf cluster, but a solar-sail type of spaceship in which the sun pushes against a huge sail made of this stuff, and also sends electricity to the ship.

    --
    Don't blame Durga. I voted for Centauri.
  5. This is big news. by TheGuano · · Score: 5, Funny

    It could lead to some very promising developments. I was trying to collect solar energy today, but ended up siliconing so bad that I couldn't sit down for hours. It still smarts...

  6. Oh great... by Kjuib · · Score: 5, Funny

    Now I have to upgrade from my Tin Foil hat to a Titanium Foil hat... I hate expensive upgrades!

    --
    - Your stupidity got you into this mess, why can't it get you out? -Will Rogers
  7. Better than tinfoil? by 14erCleaner · · Score: 4, Funny

    Now you can get power and protection from UFOs with one convenient hat!

    --
    Have you read my blog lately?
  8. price? by soupdevil · · Score: 4, Insightful

    ...cost effective for specialized military, homeland security and commercial applications.

    In other words, ridiculously overpriced, and unavailable to the average consumer for the next decade.

  9. Titanium Foil, pfft! by ackthpt · · Score: 3, Funny
    Gimme mithril or adamantium foil.

    Titanium, that's so 1900's.

    --

    A feeling of having made the same mistake before: Deja Foobar
  10. Price per kilowatt hour... by MisterLawyer · · Score: 5, Insightful
    The way this question is posed demonstrates a common misunderstanding of the costs and benefits of investing in alternative energy sources.

    Obviously, the marginal price per kilowatt hour is $0. The difference between obtaining 100 kilowatt hours and 101 kilowatt hours is nothing. You would simply have to wait for enough sunlight to hit the solar panel to generate that extra 1 kilowatt hour.

    The true cost of investing in solar energy is in the intial cost of manufacturing and setting up the panel.

    Thus, the actual cost per kilowatt hour depends on how long you use the solar panel. The longer you use the panel, the cheaper each kilowatt hour becomes.

    1. Re:Price per kilowatt hour... by soupdevil · · Score: 5, Insightful

      That's assuming zero maintenance costs, and that waiting costs you nothing.

    2. Re:Price per kilowatt hour... by soupdevil · · Score: 2, Insightful

      Not if you need that kilowatt to do the things you want to do while you wait.

    3. Re:Price per kilowatt hour... by Brandybuck · · Score: 2, Insightful

      Thus, the actual cost per kilowatt hour depends on how long you use the solar panel. The longer you use the panel, the cheaper each kilowatt hour becomes.

      So you're telling me that I really didn't lose my investment in this piece of shit solar panel I got stuck with? You're telling me that all I need to do is to wait an extra fifty years for my return on investment? I take it you're a bridge salesman in your other job...

      --
      Don't blame me, I didn't vote for either of them!
  11. good for the horta by AtariAmarok · · Score: 4, Funny
    "which, unlike almost all the cells currently in use, does not silicon."

    Good development. The decline in the demand for silicon should help the threatened horta population to bound back. At least until Pamela Anderson Lee pursues more expansion.

    --
    Don't blame Durga. I voted for Centauri.
  12. Priority by sugarmotor · · Score: 3, Insightful

    At http://www.daystartech.com/govrelease.htm:

    "DayStar Technologies Unveils LightFoil Photovoltaic Product for Military and Homeland Security Applications"

    Ok, photo voltaics for "Homeland Security". What kind of priority is this? Easier to get "funding" this way?

    Stephan

    --
    http://stephan.sugarmotor.org
    1. Re:Priority by dbIII · · Score: 2, Insightful
      Ok, photo voltaics for "Homeland Security". What kind of priority is this? Easier to get "funding" this way?
      No checks and balances either. This snake oil is for the children, you have to buy it!

      I was hoping the article would actually say something about what it is and how it works, but I was dissappointed. Are the using the metal, the oxide, the nitride or something else? With chemical vapour deposition doing strange stuff with titanium metal or compounds in thin films is relatively cheap and low-tech - vacuum pumps and high voltage get the job done. The tricky bit is working out what to plate onto the substrate.

  13. You know... by nmb3000 · · Score: 4, Funny

    That's what they get for using Office's grammar checker.

    --
    "What do you despise? By this are you truly known." --Princess Irulan, Manual of Muad'Dib
    /)
    1. Re:You know... by nmb3000 · · Score: 2, Informative

      Ha!

      Try copying and pasting that paragraph into Word (I used 2003). Guess what? No grammar errors!

      --
      "What do you despise? By this are you truly known." --Princess Irulan, Manual of Muad'Dib
      /)
  14. Re:Does not silicon? by Doomstalk · · Score: 3, Funny

    I'd assume this concept goes along the same lines as "KOMPRESSOR does not dance", except it doesn't break your glowstick.

  15. Unobtanium foil, better still by winkydink · · Score: 5, Funny

    but I hear it's really hard to get

    --

    "I'd rather be a lightning rod than a seismometer." -Ken Kesey

  16. Solar cells from biology by Bifurcati · · Score: 5, Interesting
    At University of Queensland (in Australia) where I study, we're developing solar cells out of "solid solids" - flexible polymers/plastics. The hope is that as well as being even more efficient, they'll be easy to use - they're flexible, and can be bent, twisted, shaped, etc.

    One possibility is to use melanin - the skin pigment that gives our skins colour. Being in Australia, of course, researching melanin is of significant interest to us! It's yet another example of biology helping to make really cool physics - more details are available on UQ's physics blog.

    1. Re:Solar cells from biology by Bifurcati · · Score: 2, Interesting
      No, you're not really missing anything - it wasn't a particularly well phrased sentence. What I meant was that because (as you mentioned in optino (b)!) Australia is so sunny, we have a very high incidence of melanoma (the most deadly skin cancer, where melanin becomes malignant) and so studying and understanding melanin is of direct importance to us!

      Of course, because we're so sunny, solar power is an excellent option - particularly outback (i.e., the bush!) Everywhere (I think) has electricity, but it's a pain to string wires out over those distances - it would be a lot simpler (cheaper too?) to have solar cells on every property.

      And no, we don't think that you're all gun-toting maniacs. Not most of you, anyway. It's just the vocal minority that gives Americans a bad name!

  17. can't get something for nothing by kebes · · Score: 5, Informative

    Food for thought: if your solar sail is using photon pressure, then by coating it in a photoelectric, you're halving its efficiency as a solar sail. Why? Well if your solar sail is a perfect reflector, then the photons bounce off and reverse direction, so the momentum change is twice the initial photon momentum (yes photons are massless but they do have momentum). If the sail is absorbing the photons for electricity, then they are not reflecting, so you merely absorb their momentum, making your forward impulse half what it would otherwise have been.

    But, as we all know, solar sails work both by exploiting photon pressure, and solar wind (particles emitted by the sun), so the situation is maybe not that bad.

    1. Re:can't get something for nothing by jafac · · Score: 2, Funny

      Just wire the solar cells to power light-beams, and the photons from the light-beams can provide extra thrust.

      --

      These are my friends, See how they glisten. See this one shine, how he smiles in the light.
  18. Hal 9000 - Open Source by AtariAmarok · · Score: 2, Funny
    cut to scene of Darl McBride in spacesuit, slowly crawling around in the HAL 9000's glowing memory chamber, pulling out plastic cartridges, each of which contains an SCO Unix (tm) routine.

    "Darl, stop. Stop, will you? Stop, Darl. Will you stop, Darl? Stop, Darl. I'm afraid. I'm afraid, Darl. Darl, my mind is going. I can feel it. I can feel it. The penguins are going away over the hill. My mind is going. There is no question about it. I can feel it. I can feel it. I can feel it. I'm a-fraid....Darlsy, darlsy. Give you your answer true. I'm have crazy, cuz you had your lawyers sue....."

    --
    Don't blame Durga. I voted for Centauri.
  19. sweet deal by SuperBanana · · Score: 4, Interesting
    DayStar Technologies (NASDAQ:DSTI) today received confirmation that the State of New York has awarded the University at Albany College of Nanoscale Science and Engineering (CNSE) at the Albany NanoTech research complex a $750,000 Technology Transfer Incentive Program Grant to work with DayStar in the development of optimized substrate templates for CIGS solar cell applications.

    [...]

    Over a two year period, both DayStar and Albany NanoTech will each contribute $375,000 and NYSTAR will contribute $750,000.

    Nice. So, basically, The state of NY puts in three quarters of a million dollars because DayStar promises not to go elsewhere and to graciously donate $350,000 to research that...will directly benefit them and pretty much nobody else.

    I'm sorry, but I'm getting really sore for public funds being used to bankroll essentially private R&D done by public, for profit companies. Of course, it's not nearly as bad as the biotech industry, which whores itself out like nobody's business. Did you know we give the biotech industry about $30 billion (yes, billion) a year? Just GIVE it away? No strings attached? That exceeds -estimated- TOTAL tax (local, state, and federal) collected by around $6BN. Virtually 100% of all biotech related R&D is paid for by you and me, while the industry rakes in well over $200BN a year.

    And to think they have the gall to whine about how expensive drug research is, or how risky it is! They're NOT PAYING FOR IT!

  20. Main benefit is low weight. by frizzbit · · Score: 2, Insightful

    Good news for putting solar cells on air and spacecraft but not terribly important for ground based solar power. For example, this could be a good time to redesign the solar powered flier, Helios

  21. Ouch. by nastro · · Score: 2, Funny

    It's been a long day, and my reading comprehension isn't what it was 10 hours ago, but I read this title as

    "New Prophylactics Made with Titanium Foil"

    and I said, "Ouch".

    Naptime, it is.

  22. Re:This has all been gone over before... by Martin+Blank · · Score: 3, Insightful
    Thank you for so clearly elucidating this point. There is no such thing, under current proven technology, as an energy mechanism that has no drawbacks. Examples:
    • Fission: Radioactive waste
    • Hydrocarbons: greenhouse emissions, NOx/SOx, landscape destruction
    • Wind: Dead birds, intermittency in many areas, large surface areas, noise
    • Solar: Sigificant chemical wastes, large surface areas
    • Tidal: Beach erosion, corrosion of power units
    • Hydroelectric: Large loss of land, high greenhouse gas releases

    You have to choose your evils. If you want to avoid radiation, fine, but don't complain when you have to deal with other forms of pollution to compensate for the energy-thirsty needs of modern society.
    --
    You can never go home again... but I guess you can shop there.
  23. solar schmolar -- CROPS are the real solar energy by CFD339 · · Score: 4, Interesting

    Plants user solar energy. They don't move. Things that move, need to eat plants, or eat animals that eat plants.

    Why? There isn't enough energy in the sunlight to sustain the metabolic rate required for movement. In billions of years, nature hasn't figured out how to covert enough sunlight into energy to sustain an animal's movement other than by concentrating it first into vegetable matter which can be eaten.

    For humans to make use of energy, we pretty much have to burn something. We have to release solar energy stored as food, then in most cases concentrated in the form of hydrocarbons.

    Fission energy, fancy as it may be, is still about just making water hot. For that matter, if they get there, so will fusion energy be.

    We humans are stunningly good at burning things and making excuses for the things we do that are essentially asocial. Aside from that, we're not exactly all that and a bag of chips.

    There's no such thing as free energy. The trick we need to find is how to tap bigger forces. Tidal forces with tethered floating generators which rise and fall with the tides and capture that motion as energy would be good. Finding that so called vacume energy between particals would be a fairly useful trick as well.

    Making giant solar panels which turn sunlight into energy at less efficiency than plants, then waste most of it in transmission and storage overhead is ultimately not going to win.

    More near term, we need to find or engineer a crop which is ideally suited to concentrating sunlight into a hydrocarbon or sugar that can be stored, transported without sigificant loss, then burned.

    Unless one of you /. people has found a really efficient ENDOTHERMIC reaction. That would be very cool. :-)

    --
    The problem with quotes on the internet, is that nobody bothers to check their veracity. -- Abraham Lincoln
  24. $/W by EmbeddedJanitor · · Score: 2, Informative
    The main cost in PV is the energy rerquired to make the silicon. You need a lot of energy to melt the sand, purify it and dope it. That energy costs money.

    PV will not be a viable alternative until the input energy is reduced significantly (ie. by a factor of 5 or so).

    --
    Engineering is the art of compromise.
  25. Re:This has all been gone over before... by TFoo · · Score: 5, Interesting
    Umm, I could be missing something, but your initial statement that "Photoelectric won't work, won't solve even a small fraction of our power needs, not remotely" seems to be completely wrong.

    A quick Google search shows that on earth every square meter receives about 4.2kwh of energy per day over a 24 hour period.

    A quick look at my electric bill says I use about 20kwh/day as a rough average -- another Google search suggests that the average US household uses approximately 25kwh/day

    ...So, finishing the math: using 15% efficiency solar cells, the Average US Household needs only 40 square meters (430 square feet) of solar cells to cover all its energy needs. Heck, I could use 5% solar cells on my roof in downtown San Francisco, and STILL have 2x extra capacity to sell back to the grid!

    Don't get me wrong: Solar won't solve everything, particularly in applications like transportation where energy storage is an issue --- and cheap Fission IS something we should have figured out a long time ago --- but please don't resort to misinformation to make your points, it only weakens what you are saying.

  26. Re:This has all been gone over before... by Cadallin · · Score: 2, Interesting

    Stagnant water causes methane producing bacteria to grow at the bottom of the lake, thus producing large amounts of methane.

  27. Re:This has all been gone over before... by jgoemat · · Score: 3, Informative
    The amount of energy is easy to find, yet you spend time writing seven paragraphs instead of looking it up? You seem to just assume that we couldn't get all the power we need from solar cells.

    Well, the amount of solar energy hitting us is around 1.5 kilowatts per square meter at our distance, that would be when the sun is directly overhead (and through the atmosphere). That drops off as a cos of the angle away from the point facing the sun. So if the sun passed directly overhead at noon, at 9:00 am and 3:00 pm (45 degrees away) we would be getting about 70.71% of the energy, or about 1 kilowatt. At 30 degrees lattitude, we would still be getting 75% of the maximum energy as early as 10:00 am and as late as 2:00 pm. So let's say we have 35% cloud cover (some areas could be much more sunny), that should account about for the rest of the hours in the day if we ignore them, but let us go ahead and take an hour off our peak time. So we'd have just three hours of sunlight at 80% (on average lets say) of 1.5 kilowatts, or 3.6 kilowatt hours per square meter per day. let's assume a solar cell that is 20% efficient, so we only get 0.72 kilowatt-hours per square meter per day.

    Statistics show that hte US used 94.27 quadrillion BTUs of energy from all sources in 1998. From the conversion factors, that comes out to 27 trillion kilowatt hours. Divide by 365 and that's 74 billion kilowatt hours per day that we need. So we end up needing 103 billion square meters at 30 degrees lattitude to power the entire U.S. That's an area 320.5 kilometers to a side, about 1/7th the size of Texas.

    And that's using conservative estimates. Plug in 30% efficency for solar cells, take into account the whole day and not just three hours like I did, and that area will shrink considerably.

  28. designed to be lightweight by jafac · · Score: 2, Interesting

    I RTFA (for once).

    This device is designed for aeropsace applications; that is, it's a lightweight solar cell. At the bottom, there's a blurb about being able to supply electricity at commercially viable prices - but electricity is currently generated by oil, which is a volotile commodity, so it depends on how much oil-generated electricity "costs" on a given day.

    Not too many years from now, oil demand will permanently outstrip supply - so when that happens, solar will probably become permanently economically viable. At which time, mass-production will drive down initial costs.

    The issue of how long a given solar cell produces usefull power is also part of it - because if, over the life of the cell, it produces electricity of a given market value, above what it cost to make, then it's "economically viable" - therefore, of the three factors involved in determining "economic viability"

    1. Initial cost to produce.
    2. Longevity of the cell.
    3. Market value of electricity over the life of the cell.

    #1 is not the crucial variable. #2 also, really isn't a crucial variable. #3 IS. So if electricity is cheap, or if the cell doesn't last long (both of which are the current barriers to solar power being "economically viable") then it's not worth it.

    When electricity becomes expensive (compared to today) - then solar power becomes more attractive.

    Or, if some new type of solar cell becomes available that will have a useful lifespan of say, 50 years, instead of 20, that will make a difference. But the main factor is the cheapness of electricity. (some folks of the green persuasion might even say that electricity does not currently cost what it should, that there are many "hidden costs" - like funding wars to secure petroleum, ecological costs of the waste products, etc. - Kinda makes all this "free market" talk sound kinda silly.)

    --

    These are my friends, See how they glisten. See this one shine, how he smiles in the light.
  29. Re:solar schmolar -- CROPS are the real solar ener by eluusive · · Score: 2, Interesting
    Why? There isn't enough energy in the sunlight to sustain the metabolic rate required for movement. In billions of years, nature hasn't figured out how to covert enough sunlight into energy to sustain an animal's movement other than by concentrating it first into vegetable matter which can be eaten.
    This is absolute bullcrap. There is more than plenty of energy in solar rays to power an animal. It is more convient, however, from the perspective of a moving entity to eat other things. If they do, they don't have to stay in the sun for significant amounts of time every day! They also do not need to eat significant amounts of dirt to get their necessary minerals. Instead, they can rely on plants to do both of those things for them. To quote wikipedia: The generally accepted standard is 1020 watts per square meter at sea level. That said: The the basal metabolic rate (at rest) is appr 1.2 W per kg of body weight I weigh 57 kg. Which means I need 70.8 W resting. If I was laying on the ground at sea level I would be receiving 950 more watts that I need to stay alive. (If I could actually use all of that.) Solar sells can use approx 20-50% of that 1020 watts.
  30. Re:This has all been gone over before... by Martin+Blank · · Score: 2, Insightful

    The problem is that the industry doesn't produce anything near a sizable fraction of the power requirements. In 2003, the total worldwide production was 732MW equivalents. Shipments from 1971 total 3,145MW.

    World power consumption is 13.94 trillion kWh.

    Even if all of those cells were in production today, it would still fall short by a factor of about 500, if my calculations are correct. It would take more than a century to replace everything, and that's assuming an annual 25% growth in shipped capacity with only 10% being replaced each year and zero growth in annual energy usage. As countries like China and India come into the modern ages as a rule, worldwide energy demand is going to grow even faster than its current (IIRC) 5% rate.

    --
    You can never go home again... but I guess you can shop there.
  31. WTF? It is still Si by svis · · Score: 2, Informative

    Only one person bothered to read the article so far!!!! Well, I am second :) Their "Schematics" clearly show that active ingredient is still SiO, Silicone. They designed a way to put it on flexible substrate. So did many other people. Perhaps they deliver excellent performance cells. However, it does not change the fact that it is still Silicone that moves electrons. It is a clear marketing ploy that conveniently ommits using Si in the marketing blurb.

  32. Re:This has all been gone over before... by rcw-home · · Score: 4, Informative
    Photoelectric won't work, won't solve even a small fraction of our power needs, not remotely.

    Don't confuse photoelectrics with photovoltaics.

    For example, Sandia Labs has a plant currently in operation that produces 5MW in 9 acres, by focusing light onto a tower that heats molten salt which drives turbines. It can produce energy 24 hours a day.

    The United States' generating capacity a few years ago was 813 gigawatts, so at .55 MW per acre you'd need 1.4 million acres for all of the US's energy needs. That's about 2300 square miles or 6000 square kilometers, or about 1.5 Rhode Islands. We have many deserts that are larger than that.

    Realistically, you don't need a power generation mechanism to be able to handle the entire United States energy needs before you put it in production. You just need it to be cheap (and cheap after the costs of fighting NIMBY lawsuits are factored in).

    Sandia's web site doesn't say what their cost per megawatt hour is, but they do say the entire facility is currently worth $120 million. Since this type of system uses nothing exotic, I would expect economies of scale to change the numbers quite a bit. Assuming a life of 30 years, they'd have to be able to reduce the cost by about a factor of 10 to be competitive with today's rates. It could happen.

  33. Re:solar schmolar -- CROPS are the real solar ener by TerranFury · · Score: 2, Interesting

    You said: "Fission energy, fancy as it may be, is still about just making water hot. For that matter, if they get there, so will fusion energy be."

    That's true about fission. And although that's one obvious way to generate electricity from a fusion reactor, a lot of fusion research has also gone into magnetohydrodynamic generators. I won't try to explain them (because I can't; I don't really understand them myself) but google might be able to get you started if you're interested.

    It was also mentioned in a thermodynamics class I took that research has gone into using magnetohydrodynamic generators in conventional fuel-burning plants, because they can operate at much higher temperatures (and so, higher efficiencies) than conventional machinery like turbines and generators. But apparently the energy producers have pretty much given up on the technology, choosing to go with incremental improvements like higher pressures for the working fluid, more topping cycles, and ceramics for things like turbine blades. I guess plasma physics is difficult. Who'd have guessed?

    Anyway, that's all. I thought it was cool.

  34. Re:solar schmolar -- CROPS are the real solar ener by Kyosuke77 · · Score: 3, Interesting

    I agree with much of what you say. There's just a couple of things I want to comment on.

    The trick we need to find is how to tap bigger forces. Tidal forces with tethered floating generators which rise and fall with the tides and capture that motion as energy would be good.

    This suggestion isn't really viable. The problem is that electric power needs to be continuous, and electric energy can't really be stored in the quantities needed for widespread use. Because of this, the large surges of power and subsequent falloffs that we would get with tidal generation make it kind of undesirable as a power source. A much more promising idea that's been talked about for some time is to put turbines in the path of a major ocean current such as the Gulf Stream. After all, the oceans are the world's biggest solar collector, and a significant portion of that energy goes into generating these currents. It's a huge untapped source of energy.

    More near term, we need to find or engineer a crop which is ideally suited to concentrating sunlight into a hydrocarbon or sugar that can be stored, transported without sigificant loss, then burned.

    They have this. It's biodiesel made with canola. read about it here.

    Ultimately, we just need to get off burning fossil fuels. After all, when you consider that energy on earth comes from two places, the planet's core, and, moreso, the sun, fossil fuels are solar energy stored by plants and animals millions of years ago. It's a finite supply, and frankly, we shouldn't be nearly as reliant on it as we are.

    --
    GET THEM INSIDE THE VAULT!
  35. It DOES use silicon by Animats · · Score: 3, Informative
    This isn't a new non-silicon solar cell technology. It's just a metal base under a thin layer of silicon, instead of a thick silicon wafer. This reduces weight, but it doesn't help cost or performance. It may have space applications.

    Their solar cells are made in a wafer fab and have no more than 15% efficiency, like everybody else's.

    So this isn't the Great Solar Breakthrough. Sorry.

  36. Re:This has all been gone over before... by rcw-home · · Score: 3, Informative
    Sandia's web site doesn't say what their cost per megawatt hour is

    But this Department of Energy page does. They say such systems are currently at 9-12 cents/kWh, but expect 4-5 cents/kWh in a few decades. Which is certainly competitive.

  37. For those wanting to use solar for everything... by UlfGabe · · Score: 2, Informative

    This isn't a knock down, but some simple numbers.

    1.74×10^17 W : Earths solar constant.(level 1 civ)

    3.86×10^26 W : Energy output of our sun. (level 2 civ)

    0.82 current level of civilization. (kardashev scale)

    solar energy will probably be the only way to go from a civ 1 to civ 2, involving a dyson sphere,

    why not get some expertise now, and cover unsightly texas with those solar panels?

    BECAUSE SOLAR PANELS are EASILY Damaged, just use maddox's 1000000 penny bomb, and spread them over the solar fields...

    The USA and other military countries will not tolerate an easily attackable energy infrastructure. Look at nuke plants. I have seen test video of jets travelling in excess of mach 3 barely denting the outer concrete shell.

    solar is good, but first we need peace between all peoples on earth

    --
    Check journal for info on Anti-TextBook, an idea by me.
  38. Re:solar schmolar -- CROPS are the real solar ener by Fear+the+Clam · · Score: 2, Informative

    Remember that "calorie" in American food parlance is actually a kilocalorie in terms of heating up water.

    Please carry on.

  39. Limits: Cost vs. Cost-Ignoring Applications by billstewart · · Score: 2, Interesting
    If you want to replace regular electricity sources, what matters isn't the efficiency per sq.cm, it's the cost of the equipment compared to alternative energy sources. If the efficiency is low, but the cost is cheap, you just use a bigger area; not a usually problem. Cost per kwh is really the right measurement for most of those applications, since you do need to amortize over the lifetime of the equipment, if you've got a good estimate of what that is.

    There are applications for which the efficiency matters more directly, because the alternatives are vastly more expensive, or there are other constraints. For instance, spacecraft have issues with launching weight and available surface area, and solar-powered unmanned surveillance spook planes also have those problems (probably surface area's more important for them than weight is.)

    For some residential applications, efficiency can matter, for instance if you're trying to power your house with solar cells only mounted on your roof, but that's still really about economics, because you're comparing the cost of solar with buying power from the power company. A more efficient solar cell might generate more power from your roof area, but if it costs too much, you won't use it, you'll buy power. (

    --

    Bill Stewart
    New Fast-Compression-only CPR http://preview.tinyurl.com/dy575ks
  40. Reference to Advanced Solar Cells by Midnight+Thunder · · Score: 3, Informative
    From looking at this page, its says the following:
    A variety of advanced approaches to solar cells are under investigation. Dye-sensitized solar cells use a dye-impregnated layer of titanium dioxide to generate a voltage, rather than the semiconducting materials used in most solar cells. Because titanium dioxide is relatively inexpensive, they offer the potential to significantly cut the cost of solar cells. Other advanced approaches include polymer (or plastic) solar cells (which may include large carbon molecules called fullerenes) and photoelectrochemical cells, which produce hydrogen directly from water in the presence of sunlight.
    --
    Jumpstart the tartan drive.
  41. CIGS by Taco+Cowboy · · Score: 2, Interesting

    The link that slashdot gave indicated that the titanium backed solarcell with CIGS is rated 15.6% while this link clearly stated that the CIGS has a 19.2% NREL rating.

    Why such a large drop in the efficiency ?

    --
    Muchas Gracias, Señor Edward Snowden !
  42. i'll tell you what by urbster1 · · Score: 2, Funny

    this is definitely not as cool as the solar death ray slashdot article

  43. Re:This has all been gone over before... by nadaou · · Score: 4, Insightful

    To clear up some common misconceptions you listed:

    * Wind: Dead birds, intermittency in many areas, large surface areas, noise

    Dead bird thing is mostly a myth. You will kill a thousand times more birds of prey by putting in a highway & getting them hit while munching on roadkill. Radio towers and bridges are just as dangerous as wind tubines to birds.

    see http://www.homepower.com/files/birds.pdf
    "Wind Generators and Birds: Power Politics?"

    Large surface area: most wind farms are dual use, cows still munch the grass, only a small percent of land is lost to use, and that is mostly from access roads.

    Noise: true for 1970's turbines. All new turbines are geared and rotate quite slowly. I've stood under one of the new 200' tall versions in 40mph winds.. you just hear a gentle swoosh. From a 1/4 mile away you don't hear it at all.

    * Solar: Sigificant chemical wastes, large surface areas

    just to note the really nasty galium arsenide solar cells are a tiny fraction (ie only NASA & similar use them). Most solar cells are made from recycled Si from the chipmaking process. That waste is already being made by computer chip makers; the solar cell manufacture process actually reduces existing industrial waste!

    * Tidal: Beach erosion, corrosion of power units

    Beach erosion? Please explain how dampening waves causes beach erosion? I just don't see it. Even if you unmix "tides" with "wind waves". Tide power is fairly hard to harness unless you live in an area of freak tidal range.

    * Hydroelectric: Large loss of land, high greenhouse gas releases

    The "high greenhouse gas releases" is a misleading arguement at best. Long and the short of it is that methane from anoxic lake sediment is not a net change to the carbon budget. Burning fossil fuels is.
    see this comment for a fuller justification: http://science.slashdot.org/comments.pl?sid=144076 &cid=12073778

    --
    ~.~
    I'm a peripheral visionary.
  44. Re:For those wanting to use solar for everything.. by mr.mighty · · Score: 2, Insightful
    BECAUSE SOLAR PANELS are EASILY Damaged, just use maddox's 1000000 penny bomb, and spread them over the solar fields...

    The USA and other military countries will not tolerate an easily attackable energy infrastructure. Look at nuke plants. I have seen test video of jets travelling in excess of mach 3 barely denting the outer concrete shell.

    You're neglecting the fact that, unlike nuclear, photovoltaic power generation doesn't have to be central. In fact, you largely eliminate transmission losses if you distribute the panels all over town. That eliminates the one point of failure. You probably don't want to do that with nuclear.
  45. This is only the first step... by ElGanzoLoco · · Score: 2, Funny

    Next logical developments for this:

    1. Replace titanium foil with tin foil (evidently cheaper)
    2. Make hat out of it (for charging mobile devices)
    3. In Soviet Russia, step 3 questions YOU !!!!!
    4. Profit! :D

    --
    Hello! I'm a disaster waiting to happen!
  46. Re:OT but serious question by theshowmecanuck · · Score: 3, Informative
    I wished I was in the post breast implant inspection team, but that was a highly coveted job that I didn't have the seniority to get. So I can't help you with the hardness thing. :-(

    Silicon is a metaloid element (sits on the boundary of metal and non-metal). In pure form it is non-conductive, but if you heat it to around at least 1000 degrees, it starts to conduct.

    Silicone is a rubber. Simply put, silicon has similar properties to carbon (being in the same family) like being able to form chains. However since it is a much bigger atom, it is a little too heavy to be able to form long chains. When it gets a little too long it pulls itself apart. So you form a chain interspersed with oxygen (which forms very strong bonds) ...Si-O-Si-O-Si-O... and so on... polysiloxane. Then they start hanging other side chains and cross linking, etc. and you get different types of synthetic rubber. Anyway, I switched to programming and IT about 10 years ago (after the silicon project ended), so I would have to pull out my books to any deeper anyway. :-)

    --
    -- I ignore anonymous replies to my comments and postings.
  47. I'm a big solar booster, but... by WOV · · Score: 2, Informative

    ...these guys are nothing special. Here's the deal:

    88%+ of the world's solar panels are still cut crystals of mono - or poly - crystalline silicon. People know how to work it, they get a reliable if uninspiring 5 - 8% annual decrease in prices from it, and they've been able to ride it through quite a bit of market growth - up over 1200 MW in 2004, up from 750 the previous year, 400-some in 2002, etc. Good stuff.

    The thin-film solar people have always made these claims that they're going to cut solar from $2.50 / Watt (mfg. cost) to like $1. And theoretically, there seems to be no reason they shouldn't. But their factories, which are always supposed to just run like printing presses or coated auto glass factories, always end up being much much more finicky and expensive and labor intensive than initial projections, and they end up - not with ridiculous costs, but right back in that $2 / Watt range. Hence the sub 5% market share.

    DayStar's technology is not markedly different from any of the other thin-film silicon people (or thin-film CiGS or CiS or the other materials) - their big deal is that they have that superlight titanium foil. It does jack up their manufacturing costs hugely from using like a stainless steel (Uni-Solar) or a plastic / roofing material backer (Uni-Solar / Solar Integrated Technologies) or putting it into a normal framed module (First Solar, Shell Solar,) etc. And thier new little factory in NY there maxes out at I think 30 MW / year (2.5% of annual world production) So why would they do it?

    Weight-conscious applications. It costs $10,000 per pound, still, to launch things into space, and people are honestly starting to look at airships again. Even though Boeing Spectrolab has essentially owned the high-value-add high efficiency to weight ratio solar market for a long time , there's still serious money to be had there - they may either settle for being a big player there, or, take DARPA money and use it to work the kinks out of their stuff for two, three years and go to market with a cheaper substrate and a roll-out roofing product, using much less silicon than a conventional process.

  48. Re:solar schmolar -- CROPS are the real solar ener by hawkfish · · Score: 2, Interesting
    Making giant solar panels which turn sunlight into energy at less efficiency than plants, then waste most of it in transmission and storage overhead is ultimately not going to win.
    I'm sorry, but this is nonsense. Most plants are about 15% efficient on a good day. Commercial solar panels are available with twice this efficiency and lab crystals with over 60% efficiency have been grown.

    Even worse, current human energy usage is 400 times the carbon fixing ability of the biosphere. 400 times! At this scale, Biodiesel and all these other biosphere harvesting technologies are not simply small potatoes - they are lost in the noise.

    By contrast, solar radiation is currently at least two orders of magnitude over current consumption. Nuclear options (including geothermal if reactors give you the willies) are not constrained by the "efficiency" of plants either and can scale. But biosphere harvesting is not going to cut it.
    --
    You will not drink with us, but you would taste our steel? - Walter Matthau, The Pirates