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Buckyballs Can Store Concentrated Hydrogen

Pickens brings news that researchers from Rice University have discovered that it's possible to store hydrogen inside buckyballs. Hydrogen can be an excellent power source, but it is notoriously difficult to store. The buckyballs can contain up to 8% of their weight in hydrogen, and they are strong enough to hold it at a density that rivals the center of Jupiter. "Using a computer model, Yakobson's research team has tracked the strength of each atomic bond in a buckyball and simulated what happened to the bonds as more hydrogen atoms were packed inside. Yakobson said the model promises to be particularly useful because it is scalable, that is it can calculate exactly how much hydrogen a buckyball of any given size can hold, and it can also tell scientists how overstuffed buckyballs burst open and release their cargo."

193 comments

  1. A point worth making- by Naughty+Bob · · Score: 5, Funny

    ...and they are strong enough to hold it at a density that rivals the center of Jupiter.
    Something the summary doesn't make clear is that Buckyballs are much more convenient in portability terms, as compared with Jupiter.
    --
    "Be light, stinging, insolent and melancholy"
    1. Re:A point worth making- by JoeInnes · · Score: 2, Funny

      Summary doesn't make it clear, because it's not true. If you have enough buckyballs to hold as much hydrogen as the centre Jupiter, they'll be just as inconvenient to pop in your briefcase.

      However, it is probably easier to stuff buckyballs with hydrogen than trying to cut off pieces of Jupiter.

    2. Re:A point worth making- by Anonymous Coward · · Score: 5, Funny

      Also for those of you more familiar with the US measurement system (rather than the SI units): The pressures we're talking about here is almost 200 million library of congresses per VW Beetle.

    3. Re:A point worth making- by oni · · Score: 2, Informative

      as much hydrogen as the centre Jupiter,

      So what you're saying is that you don't understand the difference between density and volume.

    4. Re:A point worth making- by elrous0 · · Score: 1

      That's a big twinkie.

      --
      SJW: Someone who has run out of real oppression, and has to fake it.
    5. Re:A point worth making- by draxredd · · Score: 1

      This is Slashdot.
      Jupiter is out.
      Reformulate using the density at the center of Uranus as a point of comparison.

      --
      --- Back to the trees, back to the trees !
    6. Re:A point worth making- by Anonymous Coward · · Score: 1, Funny

      You mean like...

      Wow, there's a lot of gas in Uranus?

    7. Re:A point worth making- by JoeInnes · · Score: 1

      No. In order for buckyballs to hold as much hydrogen as the centre of Jupiter, they would need to have a similar volume as the centre of Jupiter, because they are of a comparable density. Therefore, they're just as non-portable (is that even a word?) as the centre of Jupiter. It was intended as a joke, however, seems I didn't clarify as much as I should have. Sorry.

    8. Re:A point worth making- by redxxx · · Score: 1

      mass.

    9. Re:A point worth making- by frogzilla · · Score: 1


      Excellent!

    10. Re:A point worth making- by amRadioHed · · Score: 1

      But in order for the center of Jupiter to hold as much hydrogen as the center of Jupiter it would need to have a mass as the whole of Jupiter. The problem with Jupiter as a storage medium is that it doesn't scale down as well as buckyballs do.

      --
      We hope your rules and wisdom choke you / Now we are one in everlasting peace
    11. Re:A point worth making- by severoon · · Score: 1

      You guys are all missing the major point here, though...who knew the center of Jupiter was made of buckyballs?!

      --
      but have you considered the following argument: shut up.
    12. Re:A point worth making- by Anonymous Coward · · Score: 0

      And for the Slashdot grammar nazis:
      200 million Libraries of Congress

    13. Re:A point worth making- by clambake · · Score: 1

      How fast is that?

    14. Re:A point worth making- by kesuki · · Score: 1

      pedantic on:
      Technically the 'center' of Jupiter is a single point in the very middle of the planet not the 'entire core of Jupiter' so technically storing 'as much hydrogen as the center of Jupiter' is Technically 1 atom of hydrogen, or perhaps a single quark, which may or may not belong to a hydrogen atom, depending on the resolution of your examination of the Exact Center of Jupiter.

      Just being pedantic, but the core of Jupiter is Much much larger than the exact center of Jupiter. which is a single reference point, and not a mass of atoms. the article suggested that a buckyball could contain a higher Density of hydrogen, without breaking than the hypothetical density of Jupiter at it's central point (which is where mass is the most compressed)

      in no way was the volume of hydrogen in the core of jupiter mentioned, only the density at the 'center point of jupiter'

    15. Re:A point worth making- by JoeInnes · · Score: 1

      True.. but that would have involved me actually reading more than the summary. This is /., right?

    16. Re:A point worth making- by kesuki · · Score: 1

      no the wording thing was in the summary they used the wording of 'as much hydrogen as the center of jupiter' center, not core.

  2. Hmmm. by WindBourne · · Score: 4, Insightful

    it can also tell scientists how overstuffed buckyballs burst open and release their cargo."
    Well, if these are being burst open, then it means that these have to be built AND loaded each time, and then disposed. So now, we are going to either break apart water (cool, but inefficient), or strip H from fossil fuel (efficient, but bad news for the CO2). Then we are going to build bucky balls, store the hydrogen in it (at 8% volume), sell you the buck ball, your car will magically break the balls (most likely pressure or heat), this will power either an ICE (very low efficiency) or a fuel cell/electric motor (high efficiency, but high cost due to fuel cell).

    Of course, we could just take the electricity and charge a battery and then run an electic motor, all at more than double (or even triple) the efficiency and probably half to one third the costs.

    --
    I prefer the "u" in honour as it seems to be missing these days.
    1. Re:Hmmm. by Anonymous Coward · · Score: 0, Insightful

      especially if you put this on a big scale: 8% of its own weight? that's like saying a 100 kg H-fuel-tank can store only 8 kg of H. even the most robust and durable tanks surely have a much higher efficiency - without the added difficulty of having to get the H out of the bucky ball.

      this research is nice to know, but completely impractical.

    2. Re:Hmmm. by turtleAJ · · Score: 0
      I understand your point, but I think you misinterpreted theirs.

      it can also tell scientists how overstuffed buckyballs burst open and release their cargo.
      I think they are saying that they can study how an erronously overstuffed buckyball can burst. As in analyzing and engineering failure/problem.
      I do not remember the diameters, but I would be willing to suspect they are retreiving the H2 atoms between the Carbon rings of a buckyball... or heck, maybe they are not planning on using a 'ball' at all. Maybe they plan on using buckyballs' geometries for nanotubes and similar storage 'containers'.
      Too early for RTFA.

      In addition, it is worth mentioning that,

      The buckyballs can contain up to 8% of their weight in hydrogen,...
      Hydrogen's Atomic weight: 1.00794
      Carbon's Atomic weight: 12.0107


      Roughly 12 orders of magnitude more... per weight.
      Sounds like fun!
    3. Re:Hmmm. by Alwin+Henseler · · Score: 1

      or strip H from fossil fuel (efficient, but bad news for the CO2) Provided you have an efficient process, that would be fine as long as you don't burn the remaining carbon-rich compound (heavy oils / solid carbon). Read: as long as you use only the hydrogen component as fuel, which gives pure water vapor when you burn it.
    4. Re:Hmmm. by mudetroit · · Score: 2, Insightful

      I am in know way saying that this is a perfect solution, but a carrying method for using hydrogen as a fuel is a better long term alternative for us then batteries storing electrial energy.

      The fundamental problem with batteries is that sooner or later the chemical process that you are taking advantage of breaks down and you are left with a battery that no longer functions. As most batteries, actually all the ones I am aware of, are made with particularly noxious chemical compounds now you have the problem of what to do with the no longer functional battery. Let's review the common options:
      1.) Burn it - Not so great for the air.
      2.) Toss it in a landfill - Sooner or later even the best toxic landfills develop leaks. Not so great for the land or water.
      3.) Recycle it - Typically involves large amounts of energy with some nasty chemical by products. Again not so great for land, water, or air depending non where the byproducts go.

      Hydrogen, unless someone can present evidence to the contrary, almost has to be our portable energy source of the future. And if you consider fusion reactors as our best fixed source of energy then it is really the energy source in that case as well.

    5. Re:Hmmm. by bogeyjlg · · Score: 0

      Or perhaps there could be a way to put that carbon to use making buckyballs. Just an idea. I am not ensure what the exact process of producing a buckyball entails but I do know it involves carbon.

    6. Re:Hmmm. by ehrichweiss · · Score: 1

      "8% of its own weight?"

      The GP didn't say 8% of its own *weight*, they said *volume*. And the Buckyballs store it at 8% of it's normal volume, hence "concentrated", not expanded as you seem to be implying.

      --
      0x09F911029D74E35BD84156C5635688C0
    7. Re:Hmmm. by Bloodoflethe · · Score: 2, Interesting

      Point of contention. I believe you meant to say that the difference in weight is a factor of 12.

      Either way you slice it, the weight of a container is always much greater than the weight of the compressed gas within it. In fact the best weight I've seen for a compressed hydrogen container is 6% of the container's (including the hydrogen) overall weight. This buckeyball is about 7.5% (8/108). That's a fairly significant increase in storage capacity.

      --
      "Little is much when little you need."
    8. Re:Hmmm. by Bazer · · Score: 1

      What about energy density?

    9. Re:Hmmm. by ls+-la · · Score: 1

      "8% of its own weight?"

      The GP didn't say 8% of its own *weight*, they said *volume*. And the Buckyballs store it at 8% of it's normal volume, hence "concentrated", not expanded as you seem to be implying. The GP (GGP now) made a mistake. Read the summary, buckyballs can store 8% of their *weight* (although should have said mass). And to actually answer your parent's question, Hydrogen is so small it can escape from any container currently known, at a rate high enough that makes it impractical for long-term storage.
    10. Re:Hmmm. by afidel · · Score: 1

      Well, according to this source 9.5kg of H is equivalent to 25kg gasoline which also requires a 17kg container, so you get about 118kg to about 42kg, or almost tipple. Now most of that weight penalty can probably be made up by the fact that Honda has a fuel cell stack that weighs only 67kg which is way less than an IC engine.

      --
      There are 4 boxes to use in the defense of liberty: soap, ballot, jury, ammo. Use in that order. Starting now.
    11. Re:Hmmm. by Anonymous Coward · · Score: 0

      You forgot option number three, Gather it from Jupiter. And innovative storage is what would make that more feasible.

    12. Re:Hmmm. by bar-agent · · Score: 1

      Dude, right now my "buckyballs" are overstuffed and ready to release their cargo, preferably all over someone's face.

      Buckake?

      --
      i'd hit it so hard, if you pulled me out you'd be the king of britain [bash.org]
    13. Re:Hmmm. by WalksOnDirt · · Score: 1

      The new lithium/phosphate batteries don't seem to have any notably toxic components, and in the larger uses (like cars) they'll almost always be recycled anyway.

      Hydrogen might work out in the future as a storage/distribution medium, but for now there are still a lot of problems to be overcome. I think it's a long shot.

      --
      a,e,i,o,u and sometimes w and y (at be if of up cwm by)
    14. Re:Hmmm. by benhattman · · Score: 1

      Does it have to be the storage medium? Aren't ultracapacitors with their rapid charge/discharge capability and unlimited reusability an alternative to hydrogen storage? Research indicates ultracapacitors should be capable of storing as much energy as batteries. They aren't there yet, but they are improving at a rapid rate.

      http://www.greencarcongress.com/2006/02/mit_carbon_nano.html

  3. 8% weight is a bad way to put it by Gopal.V · · Score: 1

    Considering Fullerine is C-60 and therefore weighs 720p (ha! protons) and hydrogen atoms weigh exactly 2, this means that they can hold ~30 hydrogen atoms in it?

    Oddly, I think the issue would be balancing the containment energy of the buckyball versus the energy burning the hydrogen released. There *might* be a sweet spot in the number of hydrogen stable inside versus the tickle required to make the ball release them, for this to make sense.

    1. Re:8% weight is a bad way to put it by Anonymous Coward · · Score: 1, Interesting
      Considering Fullerine is C-60 and therefore weighs 720p (ha! protons) and hydrogen atoms weigh exactly 2, this means that they can hold ~30 hydrogen atoms in it?

      Are you thinking of hydrogen molecules or deuterium atoms? It's hard to tell. The former would be good for burning but hard to get the release energy, the latter for fusion and easier to get the balls to open up.

    2. Re:8% weight is a bad way to put it by John+Hasler · · Score: 1

      > ...hydrogen atoms weigh exactly 2...

      One.

      --
      Warning: this article may contain humor, sarcasm, parody, and perhaps even irony. Read at your own risk.
    3. Re:8% weight is a bad way to put it by gm0e · · Score: 3, Interesting
      Like it or not, percent weight is the common metric to compare hydrogen storage methods. Around 6% by weight, the energy/mass ratio of molecular hydrogen is in the ballpark of gasoline, so 6% is the target you hear all the hydrogen storage scientists talking about. Of course what weight percent sweeps under the carpet are the important issues like stability after many charge/discharges, energy required per cycle, and the operating temperature range. Anybody claiming near or over 6% is cutting major corners on one of those areas. In this case, the buckyball bursting open to release H2 is not an easily reversible step so it will have a lifetime of exactly one discharge before the leftover carbon has to be reclaimed and re-packed with H2.

      As someone who does model calculations involving buckyballs myself, this is a very intriguing calculation. But if I showed this to my buddies down the hall who do fullerene chemistry, they would have a few questions about how they are supposed to pack that much H2 in a fullerene and then scale the process industrially.

    4. Re:8% weight is a bad way to put it by drooling-dog · · Score: 1

      He must be referring to H2 molecules...

    5. Re:8% weight is a bad way to put it by drooling-dog · · Score: 1

      If it's 8% by weight, then 100 grams of C60 can hold 8 g of H2, which is 4 moles or about 90 liters (or 3.2 cubic feet) at standard atmosperic pressure & temp. Sounds more impressive when you convert to volume, doesn't it?

      It's going to take a whole lot of C60 to store enough H2 to get you very far, though.

    6. Re:8% weight is a bad way to put it by John+Hasler · · Score: 1

      > Sounds more impressive when you convert to volume, doesn't it?

      Not when you remember that hydrogen gas at STP is much less dense than air.

      --
      Warning: this article may contain humor, sarcasm, parody, and perhaps even irony. Read at your own risk.
    7. Re:8% weight is a bad way to put it by ardle · · Score: 1

      if I showed this to my buddies down the hall who do fullerene chemistry, they would have a few questions about how they are supposed to pack that much H2 in a fullerene and then scale the process industrially. Was wondering about that myself. Maybe they'll figure out some low-temperature strange behaviour to do the job.
      Doing that would require quite a lot of energy, presumably, so the energy cycle I can envisage is:
      • obtain raw materials (C and H; C may be reprocessed from last cycle, H is expensive to obtain, I hear)
      • process raw materials (C -> fullerene, H -> whatever state works)
      • put H in fullerene/fullerene around H/whatever works
      • do whatever it takes to get new object to where energy can be released
      It seems to me that we'd need a lot of energy to be released for the numbers to work out in our favour. Some posts here have suggested a use in atomic fusion reactions (using lasers). Maybe they could do the same trick with Helium (they haven't actually done it yet)?
      My knowledge of physics these days is thanks to the BBC (nice one BBC :-) and I have only a vague idea of many concepts: can anyone say if it's possible to make a Bose-Einstein condensate from molecules like Methane? I'm imagining that it'd be pretty cool to be able to reprogram something like that into atoms/molecules we want (this may be completely impossible - I'm not claiming to know the theory ;-)
    8. Re:8% weight is a bad way to put it by drooling-dog · · Score: 3, Funny

      How about this, then:

      Store the hydrogen at atmospheric pressure in a large, oblong balloon-like vessel, and strap your vehicle underneath it. You not only have a fuel source, but you have buoyancy as well and can soar above the traffic. We'd finally have those flying cars they've been promising us.

      Oh, the humanity!

    9. Re:8% weight is a bad way to put it by rrohbeck · · Score: 1

      How about this, then:

      Store the hydrogen at atmospheric pressure in a large, oblong balloon-like vessel, and strap your vehicle underneath it. You not only have a fuel source, but you have buoyancy as well and can soar above the traffic. We'd finally have those flying cars they've been promising us.

      Oh, the humanity! Yes! Mooring available at Lakehurst, NJ.
    10. Re:8% weight is a bad way to put it by Dzonatas · · Score: 1

      The scientist claim a gain in the metallic property. That is exactly what is needed in order to set of the reaction of a fuel cell. If a fullerene with H inside is metallic, then just the addition of oxygen on the outside is surely to produce energy. As the energy is released (and H2O), the metallic property fades. There will still be hydrogen left inside the fullerene at that point. Something to model, how much hydrogen is left inside? If 8% is maximum before breakage, then what is minimum after the fuel-cell process (the gained/faded metallic catalyst) is applied to the fullerene with H? (We don't want them to implode either -- we want the fullerene to be 100% re-usable even if there is leftover H inside due to the faded metallic property). What we need to know is a graph of the metallic property compared to percent weight of H inside the fullerene. Then we can use that to graph the percent weight to potential catalytic properties.

    11. Re:8% weight is a bad way to put it by kesuki · · Score: 1

      As long as we don't use zinc painted shells i think we're set here, except for the parking, such a vehicle it is easier to have several ropes pulled by dozens of men to tie the ship down to moorings rather than to reduce the amount of hydrogen gas stored. so who's going to pay for that valet parking service?

  4. Hydrogen? by mlwmohawk · · Score: 1, Insightful

    All this rush to store hydrogen, why not find a way to extract it WITHOUT creating CO2. Currently all commercial processes for extracting hydrogen use fossil fuels to do so.

    Maybe solar and/or wind will be used, but the efficiency is still low.

    1. Re:Hydrogen? by kvezach · · Score: 1

      There are many well known ways to extract hydrogen without creating carbon dioxide (electrolysis from renewable source of your choice, molten salt or gaseous generation IV reactors with thermocracking, etc); they're just not viable.

    2. Re:Hydrogen? by mlwmohawk · · Score: 1

      I said "commercial" which I'm sure you accept also implies "viable."

    3. Re:Hydrogen? by with+a+'c' · · Score: 1

      Thermodynamics anyone? If we need to use energy to extract hydrogen then why not use the energy to do other real work the first place? Hydrogen is not a power source but it may make a reasonably efficient battery or power storage medium. Let's not forget that.

    4. Re:Hydrogen? by kvezach · · Score: 1

      Yes. The important part, however, is that the limit is one of economics, and not of physics; the economic situation may change, so it's reasonable to do research into how to store hydrogen (as in this case) or use it (as with fuel cells and so on) even if hydrogen extraction is too expensive at the moment, or the technology hasn't gone from research to engineering yet.

    5. Re:Hydrogen? by JJJK · · Score: 1

      I don't understand why so many people seem to think that the entire scientific/engineering community can only focus on one thing at once.
      It's like saying "Well, but they STILL don't have a cure for cancer" when reading about some new invention or something.

      I'm sure there is a lot of people working on renewable energy sources as well.

      The ultimate goal is to find ways of extracting, storing and burning hydrogen at high efficiency, without pollution.
      Somebody comes up with a solution to either one of those problems (keep in mind that you can't really force great ideas...), then I think that's a good thing.

    6. Re:Hydrogen? by 0olong · · Score: 1

      I'm getting so sick and tired of reading comments like this on every /. article mentioning H2.

      energy STORAGE =/= energy SOURCE. These 2 areas of engineering are distinct, so keep on topic, ok?

      When talking about energy storage we only care about 3 things: density, degradation and safety.

      H2 then, is obviously not ideal, but at least try to make your objections relevant.

    7. Re:Hydrogen? by BVis · · Score: 1

      I was just about to post a comment saying that exact thing. The biggest problem with hydrogen as an energy storage medium is .. storage. (Nightmare of grammar, that is.) If this, theoretically, can solve that issue in a way that can become commercially viable (and that's an engineering problem, which we've become pretty good at overcoming) that's HUGE. No big pressurized tanks, no risk of leaks, (or, potentially, explosive combustion.. which is actually a much lower risk than the Hindenburg chicken littles would have you believe), no additional (hugely expensive) infrastructure. There's potential to be able to transport hydrogen like gravel, or (more likely) gasoline. (I'm guessing they could make a slurry of some kind, but I'm not a molecular physicist or a chemist.)

      Agreed, the details are muddy, but IMHO this is well worth pursuing (and funding.) Combine this with high-efficiency photovoltaics (and from what I've seen, there's a huge breakthrough in the wings involving using a much wider spectrum of sunlight for energy conversion; current tech only uses one wavelength) and you have a near-100% clean energy source (provided the storage/extraction of hydrogen from these buckyballs can be a green process, which I'm not so sure about.)

      The biggest issue with solar now is energy storage, but people are already using hydrogen for that (in large, expensive, pressurized tanks, granted). This seems like a logical next step, if it can make it out of the laboratory.

      --
      Never underestimate the power of stupid people in large groups.
    8. Re:Hydrogen? by with+a+'c' · · Score: 1

      Yes exactly.
      If H2 is such a fantastic thing then why is it typically vented off at the well head when it comes up with NG. Because of the storage difficulties! In this case the energy used to get H2 is minimal but the energy needed for storage does not make it viable to capture. When H2 comes up with NG it has to be cheeper than making it even with solar cells. Yes the Buckyballs are a cool idea if they make storage better. Go team go.

    9. Re:Hydrogen? by Firethorn · · Score: 1

      You forgot the ever so important fourth:

      Cost

      There are plenty of things we can do today, it's just not cost-feasable to do it. We could put up high density storage tanks today; they'd just be too costly to be practical.

      --
      I don't read AC A human right
  5. That's nice and all... by Muad'Dave · · Score: 4, Insightful


    ...but each burst buckyball is 60 carbon atoms floating around in your fuel. Aren't you right back to "hydrocarbons" if you burn this fuel, and won't the carbon poison fuel cell membranes? It's a cool trick _iff_ you can strip the carbon out efficiently before the hydrogen is used.

    --
    Tiller's Rule: Never use a word in written form that you've only heard and never read. You will end up looking foolish.
    1. Re:That's nice and all... by Alwin+Henseler · · Score: 3, Informative

      No prob. The issue here is finding an (energy-)efficient / easy way to make the buckyballs store and release hydrogen. But once the hydrogen is released, I can't imagine it would be hard to separate 2-atom hydrogen molecules from 60-atom buckyball molecules. Or find a way to do so.

      Some hints: at room temperature, buckyball molecules may behave as solid or liquid-like material, or be dissolved in other liquids, while hydrogen is a thin gas. And buckyball molecules come in different sizes (number of C-atoms).

      Summarized: the carbon here should be regarded as a carrier, not part of the fuel.

    2. Re:That's nice and all... by Anonymous Coward · · Score: 0

      Palladium has the strange ability to pass hydrogen through it when heated. I could see a mechanism like this as being ideal for filtering the carbon out of the fuel stream.

    3. Re:That's nice and all... by Muad'Dave · · Score: 1

      Thanks for the reply. I guess the bottom line is how small the buckyball fragments are. My fear is that upon rupture, some of the released hydrogen will combine with the newly-ruptured bucky fragments, creating those evil hydrocarbons. Unless we find some extremely clever scientists, I doubt we'll see buckyballs with a little trap door on them to let the hydrogen out. barring that, there will be various sizes of carbon structures floating around (I liken it to nuclear fission where there's a two-humped distribution of fission fragments - perhaps I'm way off base).

      --
      Tiller's Rule: Never use a word in written form that you've only heard and never read. You will end up looking foolish.
    4. Re:That's nice and all... by clonan · · Score: 1

      Remember, hydrocarbons aren't "bad"

      If the Carbon was extracted from the air to create the buckyballs then there is no problem with burning them...if they were extracted from oil we have an issue regardless.

    5. Re:That's nice and all... by Muad'Dave · · Score: 1

      True, if as you say the carbon is atmosphere-o-genic. I fear that the easiest (and cheapest) route may be to crack aliphatic hydrocarbons from fossil fuels into both the buckyballs and H2, so we're no better off than burning it outright.

      --
      Tiller's Rule: Never use a word in written form that you've only heard and never read. You will end up looking foolish.
    6. Re:That's nice and all... by clonan · · Score: 1

      absolutly agree...until fossil fuels start to become scarse and the price of extracting them from the ground goes up while at the same time solar, and nuclear (Thorium maybe) power prices come down.

      Eventually, probably in the next two decades it will become economically feasible to extract carbon from the air rather than the ground.

    7. Re:That's nice and all... by ceoyoyo · · Score: 1

      It doesn't seem like that cool a trick anyway. 8%? That's a lot of fuel tank and not very much fuel.

    8. Re:That's nice and all... by Farmer+Crack-Ass · · Score: 2, Insightful

      The biggest expense of nuclear power is not the fuel, but the extreme initial capital cost for building the plant. Fuel is actually a pretty small fraction of the cost for nuclear power - the price of fuel could double and the KWh cost would rise very little.

    9. Re:That's nice and all... by clonan · · Score: 1

      Correct, and as the technology has improved over the last 30 years (since the last N-plant went active in the US), the initial capital costs have dropped.

      Also, it is important to remember that other power plants have similar initial upfront costs.

      Hydroelectric dams well exceed nuke plants. Even coal fired plants are approaching the same price as a nuclear plant.

      The major issue is NOT the upfront cost but rather the societal pressure to avoid nuclear and the perceived problem of nuclear waste. The first is dropping fast and the second is solved with reprocessing.

      France gets most of it's energy from nuclear and the processed waste fill one small closet a year. Plus there are also technologies that can "burn" up nuclear waste with neutron bombardment, cutting down the danger period to 50-100 years.

    10. Re:That's nice and all... by afidel · · Score: 1

      Actually there are ways to deform a fullerene lattice without breaking the bonds. Certain catalysts can be used which temporarily bond with the carbon deforming the lattice and allowing appropriate sized captured molecules to escape. This method was developed to deliver chemotherapy drugs more directly, the researchers found a way to attach the catalyst to the cancer site and then injected the chemo containing fullerenes into the patient where they only deformed on and near the cancer site. This significantly reduced collateral damage and also reduced the overall amount of drugs needed.

      --
      There are 4 boxes to use in the defense of liberty: soap, ballot, jury, ammo. Use in that order. Starting now.
    11. Re:That's nice and all... by Muad'Dave · · Score: 1

      Horribly cool! Thanks for the information.

      --
      Tiller's Rule: Never use a word in written form that you've only heard and never read. You will end up looking foolish.
    12. Re:That's nice and all... by Muad'Dave · · Score: 1
      ...since the last N-plant went active in the US...


      It's alright - you can say the 'N' word! Even some environmentalists are saying it (gasp!!) Go ahead, it's easy. Nooo-cleee-urrr. Nu-cle-ur. Nuclear. There, that wasn't so hard. I think we've made great progress.


      Obligatory content: I'm convinced that the only way out of our energy 'crisis' is to adopt IFR technology. This interview in particular spotlights its technical merits and the political stumbling blocks that have been thrown in its path.

      --
      Tiller's Rule: Never use a word in written form that you've only heard and never read. You will end up looking foolish.
  6. So All We Really Need... by camperdave · · Score: 5, Funny

    So all we really need is a really big buckyball, and we've solved the hydrogen storage problem.

    Of course, we still need to figure out how to get the soft gooey hydrogen inside the chocolatey pocket of the buckyball, especially at "center of jupiter" pressures. Maybe the folks at Cadbury might reveal their secret. We'll also need to figure out how to get the hydrogen out once we're ready to use it.

    --
    When our name is on the back of your car, we're behind you all the way!
    1. Re:So All We Really Need... by JZdziarski · · Score: 0, Offtopic

      Well, at least Bucky will be pleased to hear this.

    2. Re:So All We Really Need... by camperdave · · Score: 0, Offtopic

      I'm sorry to have to tell you this, but Bucky's dead.

      --
      When our name is on the back of your car, we're behind you all the way!
    3. Re:So All We Really Need... by datablaster · · Score: 1, Funny

      Bucky's not dead! I saw him buying gas at a truck stop outside of Memphis. Kept mumbling something about tensegrity and the Elvis Effect...

    4. Re:So All We Really Need... by Shakrai · · Score: 1

      I'm sorry to have to tell you this, but Bucky's dead.

      No he's not. He is in prison though ;)

      --
      I want peace on earth and goodwill toward man.
      We are the United States Government! We don't do that sort of thing.
    5. Re:So All We Really Need... by Lazarian · · Score: 1
      So how many licks does it take to get to the center of a Bucky-pop?

      Hmmm, lets see... One, two, thr...BANG!

  7. Clearly I'm missing something by hanshotfirst · · Score: 4, Insightful

    An alternative to carbon-fuel which requires storing that alternative in carbon?

    Once you crack those buckeyballs open to get the H out, the C has to go somewhere, right?

    What am I missing, here?

    --
    Why, oh why, didn't I take the Blue Pill?
    1. Re:Clearly I'm missing something by Dr.+Cody · · Score: 1
    2. Re:Clearly I'm missing something by Anonymous Coward · · Score: 0

      What am I missing, here?

      How desperate you can get for funding.

    3. Re:Clearly I'm missing something by oxidiser · · Score: 2, Informative

      You're comparing apples and oranges here. The buckyballs DO contain carbon, but that fact alone does not make them dangerous to the environment. Carbon as fuel is bad because it gives off CO2 as a byproduct of burning. In this case the carbon is just the container, the hydrogen is the fuel. Unless of course I'm missing something, which is entirely possible.

    4. Re:Clearly I'm missing something by clonan · · Score: 1

      Also you should remember that CO2 is not "bad" per say.

      It is only the addition of EXTRA CO2 that is bad. If we cracked the CO2 already in the air to make the fulerenes and then burned them it wouldn't add anything to the atmosphere at all.

    5. Re:Clearly I'm missing something by John+Hasler · · Score: 1

      > If we cracked the CO2 already in the air to make the fulerenes and then burned them it
      > wouldn't add anything to the atmosphere at all.

      If we cracked the CO2 already in the air (and some water) to make octane and then burned it, it wouldn't add anything to the atmosphere at all.

      --
      Warning: this article may contain humor, sarcasm, parody, and perhaps even irony. Read at your own risk.
    6. Re:Clearly I'm missing something by Dekker3D · · Score: 1

      that should be interesting. the flash would cause the buckyballs to suddenly expand slightly, and apparently release a lot of heat. the hydrogen would quickly decompress though, so it'd get extremely cold. makes me wonder if this would burn or freeze?

    7. Re:Clearly I'm missing something by Anonymous Coward · · Score: 0

      ...per say.
      Do not try to write in Latin, if you only know English.
      Next time just type "by itself".
    8. Re:Clearly I'm missing something by clonan · · Score: 1

      I type as I speak and I often speak "per say" ;-)

    9. Re:Clearly I'm missing something by greyhueofdoubt · · Score: 1

      I apologize if someone else has already pointed this out-

      Ostensibly, the carbon for these balls would come from the atmosphere; therefore, releasing them back in to the atmosphere would not cause a net gain in CO2 levels. Unless we store these buckyballs for millions of years (like oil) thus allowing the planet to settle in to a carbon-sparse ecology, there really is no ill effect from this process.

      You excrete CO2 all the time when you breathe. That carbon comes from recently-expired organic sources and is part of the current carbon cycle. Fossil fuels on the other hand essentially are causing a net increase in carbon because it had been sequestered long enough to not play a part in our ecology/climate.

      -b

      --
      No offense, but I've stopped responding to AC's.
  8. 8%? Why, that's more than half as good as octane! by John+Hasler · · Score: 2, Insightful

    Otherwise known as gasoline.

    --
    Warning: this article may contain humor, sarcasm, parody, and perhaps even irony. Read at your own risk.
  9. Too easy by mokiejovis · · Score: 0, Offtopic

    ...and it can also tell scientists how overstuffed buckyballs burst open and release their cargo.

    That's what she said!

  10. Read the Warning... by ayjay29 · · Score: 5, Funny

    Pregnant women, the elderly and children under 10 should avoid prolonged exposure to Hydrogen Filled Buckyball.

    Caution: Hydrogen Filled Buckyball may suddenly accelerate to dangerous speeds.

    Hydrogen Filled Buckyball contains a liquid core, which, if exposed due to rupture, should not be touched, inhaled, or looked at.

    Do not use Hydrogen Filled Buckyball on concrete.

    Discontinue use of Hydrogen Filled Buckyball if any of the following occurs: Itching, Vertigo, Dizziness, Tingling in extremities, Loss of balance or coordination, Slurred speech, Temporary Blindness, Profuse sweating, Heart Palpitations.

    If Hydrogen Filled Buckyball begins to smoke, get away immediately. Seek shelter and cover head.

    Hydrogen Filled Buckyball may stick to certain types of skin.

    When not in use, Hydrogen Filled Buckyball should be returned to its special container and kept under refrigeration... Failure to do so relieves the makers of Hydrogen Filled Buckyball, Wacky Products Incorporated, and its parent company Global Chemical Unlimited, of any and all liability.

    If Hydrogen Filled Buckyball should become soiled, wipe gently with a soft cloth moistened with sulfuric acid.

    Ingredients of Hydrogen Filled Buckyball include an unknown glowing substance which fell to Earth, presumably from outer space.

    Hydrogen Filled Buckyball has been shipped to our troops in Saudi Arabia and is also being dropped by our warplanes on Iraq.

    Do not taunt Hydrogen Filled Buckyball.

    Hydrogen Filled Buckyball comes with a lifetime guarantee.
    Hydrogen Filled Buckyball. ACCEPT NO SUBSTITUTES!

    --
    Offtopic, Inflammatory, Inappropriate, Illegal, or Offensive comments might be moderated up.
    1. Re:Read the Warning... by Alwin+Henseler · · Score: 1

      Hydrogen Filled Buckyball contains a liquid core, which, if exposed due to rupture, should not be touched, inhaled, or looked at. I'd quote this one as: "Do not look at Hydrogen Filled Buckyballs with remaining eye."
    2. Re:Read the Warning... by Huge_UID · · Score: 1

      I started seeing "Hydrogen Billed Fuckyball".

    3. Re:Read the Warning... by Wizard+Drongo · · Score: 1

      You forgot "The Hydrogen Filled Buckyball will never threaten to stab you, and, in fact, cannot speak. In the event that the Hydrogen Filled Buckball does speak, we advise you to disregard it's advice."

      --
      The truth shall always be free: Boris Floricic is Tron.
    4. Re:Read the Warning... by magus_melchior · · Score: 1

      Not nearly as brilliant as your "Happy Fun Ball" ripoff, but...

      Side effects may include: dry mouth, nausea, vomiting, water retention, painful rectal itch, hallucination, dementia, psychosis, coma, death, and halitosis. Buckyballs are not for everyone. Consult your doctor before use.

      --
      "We are Microsoft. You shall be assimilated. Competition is futile."
  11. Devolution by Anonymous Coward · · Score: 0

    Cool -- So instead of about 10 LBS empty, the fuel tank in my truck would weigh 400 LBS.

    Glad to see we are making progress.

  12. Exotic pressures by Dr.+Cody · · Score: 5, Interesting

    In the nuclear fuels field, we deal with really exotic temperatures and pressures in materials whose bulk properties might be only two or less orders of magnitude from standard temperature and pressure. Did you know that there are people sitting around, calculating the pressure of an individual helium atom in a crystal lattice? The pressures that arise put planetary cores to shame.

    1. Re:Exotic pressures by zippthorne · · Score: 1

      Can you really call that *pressure* though? I mean, the concept of pressure works under the assumption of a continuous medium, or an aggregate of particles so large that it can be approximated as a continuous medium, which you definitely do not have if you're considering individual particles. You might as well calculate the "pressure" of an individual air molecule striking an individual molecule of a pressure vessel by computing it's impulse, and dividing by the cross sectional area of the smaller of the two atoms.

      BTW, recreational scuba divers use materials whose bulk properties are two orders of magnitude from STP, and put their own personal materials under conditions of nearly one order of magnitude away, so that's not actually all that impressive.

      --
      Can you be Even More Awesome?!
  13. Next week... by downix · · Score: 1

    And next week the announcement of the Hindenberg II...

    --
    Karma Whoring for Fun and Profit.
  14. That's Nice by Greyfox · · Score: 2, Interesting

    Could densely packed hydrogen be encouraged to fuse somehow? Perhaps with some sort of "laser"?

    --

    I'm trying to teach myself to set people on fire with my mind... Is it hot in here?

    1. Re:That's Nice by Anonymous Coward · · Score: 0

      In short -- No.

      If it is only 8% of the mass of (very light) Carbon buckey balls, that is not much density. Getting hydrogen to have any significant density is really tough. That's the whole problem. Even what we call "liquid" hydrogen, is actually closer to a really dense gas (think really cold, flowing air). Slush hydrogen actually does get it to the point where you can actually get lots of it stored in a (somewhat) practical fuel tank, although making it, and the tank is a huge challenge. Making, storing, transferring liquid or slush hydrogen requires a very tight process, or the entire facility, tanks, vehicles, etc. tend to simply go away.

      We've even made solid hydrogen. but even that is still a ways (as far as we know) from getting it to fuse.

  15. Film at 11 by mac1235 · · Score: 1

    Call me when they can get the hydrogen out again...

  16. The rest of the press release by The+Fun+Guy · · Score: 3, Funny

    "Professor, that's amazing! The buckyballs will bind the hydrogen so well that it won't leak out of the container?"

    "That's correct. We're very pleased with these results."

    "And to release the hydrogen to be able to use it, you just crack open the buckyballs, right?"

    "I beg your pardon? No, no, it's bound extremely tightly to the carbon matrix. That's what we've developed, a way to bind hydrogen."

    "But to actually use the hydrogen, professor, you have to get it back out. How do you get it out of the buckyballs?"

    "Ah, well, that's something that we'll address in year 4 of the grant."

    "Which is...?"

    "2011."

    --
    The man who does not read good books has no advantage over the man who cannot read them. - Mark Twain
  17. Meh. Methane has about 20 percent by Anonymous Coward · · Score: 0

    Just do the numbers. Methane (CH4) has 12 weight units of C plus 4 of H.

    Makes 25 per cent H.

    This buckyball thing may be cool for other things, but as a storage...

  18. Aluminum can store hydrogen too by nbritton · · Score: 1

    Hydrogen is soluble in aluminum. Its solubility varies directly with temperature and the square root of pressure. During the cooling and solidification of molten aluminum, dissolved hydrogen in excess of the extremely low solid solubility may precipitate in molecular form, resulting in the formation of primary and/or secondary voids.

    Moisture in the atmosphere dissociates at the molten metal surface, offering a concentration of atomic hydrogen capable of diffusing into the melt. The barrier oxide of aluminum resists hydrogen solution by this mechanism, but disturbances of the melt surface that break the oxide barrier result in rapid hydrogen dissolution.

    Two types or forms of hydrogen porosity may occur in aluminum. Inter-dendritic porosity, which is encountered when hydrogen contents are sufficiently high that hydrogen rejected at the solidification front results in solution pressures above atmospheric. Secondary (micron-size) porosity occurs when dissolved hydrogen contents are low, and void formation is characteristically subcritical.

    The disposition of hydrogen in a solidified structure depends on the dissolved hydrogen level and the conditions under which solidification occurs. Because the presence of hydrogen porosity is a result of diffusion-controlled nucleation and growth, decreasing the hydrogen concentration and increasing the rate of solidification act to suppress void formation and growth.

    Source: http://www.key-to-metals.com/Article83.htm

    1. Re:Aluminum can store hydrogen too by Ant+P. · · Score: 1

      Right, now that you've demonstrated an excessively verbose knowledge of the subject, demonstrate the usefulness of this impure aluminium as a fuel storage method.

    2. Re:Aluminum can store hydrogen too by nbritton · · Score: 1

      I haven't thought about that... I do know from experience (I have a furnace in my shop for aluminum casting) that if you put hydrogenated aluminum into a bucket of water the hydrogen will bubble out. I use ammonium perchlorate (a strong oxidizer that decomposes mainly into chlorine, nitrogen, and oxygen) to degas and promote dross separation.

      I imagine if you heated aluminum to just below it's boiling point and then poured water onto it it would dissociate lots of hydrogen, then you cap it and drop the temp till the aluminum is just above it's freezing point... the excess hydrogen should come out of solution because its solubility varies directly with temperature and the square root of pressure. I'm not sure how efficient this would be compared to electrolysis thought.

  19. Don't you mean "could" store hydrogen? by Fysiks+Wurks · · Score: 5, Informative

    Let's RTFA a bit: "'Based on our calculations, it appears that some buckyballs are capable of holding volumes of hydrogen so dense as to be almost metallic,' said lead researcher Boris Yakobson"..." If a feasible way to produce hydrogen-filled buckyballs is developed, Yakobson said, it might be possible to store them as a powder."

    What a difference one word can make in a summary. News flash, "Miss Universe can have sex with Slashdot users! According to simulations conducted with fold-out pictures in Randy's basement..um...research center"

    The simulation work is pretty cool, the headline and summary can and does mislead the reader.

    --
    P226
    1. Re:Don't you mean "could" store hydrogen? by MarsMartian · · Score: 0

      This is chemistry, everything is based on calculations and inferences. It would be wrong to assert that the buckyballs can hold volumes of hydrogen when it only appears that they can.

  20. Not true! They will be VERY convenient for a bit. by clonan · · Score: 3, Interesting

    While I haven't run the math, I think if you compress the hydrogen in Jupiter's core down to briefcase size you will find that it will keep going and form a nice little singularity....very easy to fit in a briefcase....shortly before it EATS the briefcase and then you...

    Back of envelope math:

    One earth mass will form a singularity at around 10 CC (or so I've heard)

    Jupiter's core is about 10 earth masses (or so I've heard)

    Ergo one Jupiter core will form a singularity at about 100 CC.

    A small briefcase will hold 100 CC plus a little extra.

    Only one questions remains...how will we get the core of Jupiter to LOOK like the report I was supposed to read last night?

  21. Look, I don't wish to be rude... by pandrijeczko · · Score: 1
    ...but when someone puts a new word like "buckyballs" in the title of a posting, rather than trying to outsmug the rest of us by looking more intelligent, can they also briefly explain in the first paragraph what that word actually is?

    There's me over here in "The Old World" looking at the article thinking "Buckyballs? What are they then? Some brand of American breakfast cereal or cured meat product being a spherical version of beef jerky? How can processed foodstuffs be used as containers for hydrogen? And why when there's perfectly good pressurised cannisters available?"

    A brief explanation of a word allows me to quickly decide if an article is going to be of interest to me or not - in this case, it's all that high-brow hoity-toity chemistry nonsense where there's absolutely bugger all chance of talking about Linux, music, computer games or laughing at the Vista users.

    So basically I'm off to better threads.

    Thanks for listening and "Toodle Pip" from Blighty!

    --
    Gentoo Linux - another day, another USE flag.
    1. Re:Look, I don't wish to be rude... by Anonymous Coward · · Score: 0
      to summarize your post, then:

      Get off my lawn!
    2. Re:Look, I don't wish to be rude... by Alwin+Henseler · · Score: 1

      Ehmm, a *new* word? Look here ...

    3. Re:Look, I don't wish to be rude... by egomaniac · · Score: 1

      The word "buckyball" is hardly new. I'm pretty sure it's been around since the mid-1980s, and I don't consider it to be any more obscure than, say, "triglyceride". Yet few people complain when the word triglyceride appears in an article without a definition.

      And is it really that hard to look it up in Google? I'm pretty sure you've got Internet access, or else your ability to post here is a really neat trick.

      --
      ZFS: because love is never having to say fsck
    4. Re:Look, I don't wish to be rude... by Anonymous Coward · · Score: 0

      I thought that you Euros were supposed to be smarter and more sophisticated than us "dumbass Americans," at least according to the standard /bot groupthink around here. Shhh...you're ruining it for the rest of them!

    5. Re:Look, I don't wish to be rude... by pandrijeczko · · Score: 1
      Yes, I accept that entirely but this is a news site which means that a chemistry layperson like myself needs to see a potted summary of what's being reported in plain English.

      If all you chemistry boffins want to sit in here and talk hydrocarbons all day, that's fine by me. But if you're trying to maximise the audience and interest of an article, spare a thought for the likes of me who rarely get their noses out of UNIX manuals who would probably be quite interested in reading about other stuff occasionally, as long as it didn't require bringing up half of the Internet in my browser to translate it first.

      --
      Gentoo Linux - another day, another USE flag.
    6. Re:Look, I don't wish to be rude... by pandrijeczko · · Score: 1
      If I continue to engage in this conversation with you about the differences in sophistication between Europeans and Americans, you know precisely how it will all end.

      You'll question me about why the British can't get proper dental treatment and why French/Italian women don't shave their armpits and I'll ask you about why you lot were late for the World War II and demand that we have the blueprints for the Harrier back.

      So let us politely agree that we have now reached that point and go from there, shall we without all that "needless mucking about in the middle" as the late Douglas Adams once said.

      --
      Gentoo Linux - another day, another USE flag.
    7. Re:Look, I don't wish to be rude... by Anonymous Coward · · Score: 0

      You're on the wrong site. Slashdot is a technical forum.

      Not every technical person knows what a buckyball is, but at least they know how to find out. This differs from your average non-technical telly viewer, who expects everything to be presented to him in noddy form.

    8. Re:Look, I don't wish to be rude... by pandrijeczko · · Score: 1
      Yes, okay, I admit to being about as knowledgeable in chemistry as a subnormal wooden rocking horse and that I care little for chemical reactions unless the end result is lukewarm pint of British real ale - but I'm sure that if I throw a few of the more wackier UNIX tool names at you and asked you to tell me what they do without looking them up elsewhere, you'd struggle.

      So ner-ny-ner-ny-ner-ner!

      --
      Gentoo Linux - another day, another USE flag.
    9. Re:Look, I don't wish to be rude... by pandrijeczko · · Score: 1
      Oh now look, don't take it all that serious, please.

      It was meant to be a light-hearted comment taking the pee out of my own polite British attitude as much as anything else.

      Lighten up, have a bit of fun and try to see the funny side.

      --
      Gentoo Linux - another day, another USE flag.
    10. Re:Look, I don't wish to be rude... by imsabbel · · Score: 1

      As a fellow european, i have to put in a word:
      You are dumb, and your original post a petty complained.

      Go away.

      --
      HI O WISE PRINCE. WHT TOOK U SO DAM LONG?
  22. Pumping Gas by infonography · · Score: 2, Funny

    My question is how to you stick the nozzle in from the gas pump. And when will it work in my Hummer? Will they start installing Electron Microscopes at Chevron?

    --
    Sorry about the writing. Robot fingers, you know? Cliff Steele in DOOM PATROL #23
  23. Superconductor encasement? by Ioldanach · · Score: 1

    I don't see anywhere in the article where they mention how many gigapascals that is, but I see varying references that depending on how deep you mean, they could mean anywhere from 140 to 300 GPa. At that pressure, this might make a suitable container for the room temperature superconducting silicon mentioned earlier this week on slashdot. So, we have a compound that can compress to a room temperature superconductor. We have a container to keep it compressed in. Now we just need to figure out how to stuff it all in there!

    1. Re:Superconductor encasement? by Garridan · · Score: 1

      http://www.ruf.rice.edu/~biy/Selected%20papers/NanoLett-H@Cage.pdf Tops out at about 130GPa. With a little cooling, this could be a feasible cage for a tiny little bit of superconducting hydrogen. Neat. However, what we want is buckytubes full of superconducting hydrogen.

    2. Re:Superconductor encasement? by Ioldanach · · Score: 1

      Baby steps. Given that they achieved 100GPa at 17K, it might just be possible to combine them into something that's usable and maintainable. With the structure of a buckeytube, I doubt it would behave much worse than a buckeyball, and would allow for tiny 'wires'. If they can tweak the substance to achieve 100GPa at 300K, then its still incredibly high pressure but the two things can be combined to work together.

  24. How about fusion instead of fuel cells... by clonan · · Score: 3, Interesting

    Everyone assumes that these will be used for fuel cells, but why not use them for fusion?

    I know one technique has been laser fusion. Target several lasers at one point and they reinforce each other. Then drop in a tiny sphere of fusion fuel surrounded by glass of plastic and the lasers cause the sphere to exploded both outward and in which increases the pressure enough to cause fusion.

    This concept has to be more efficient with a VERY high pressure fuel. So we give our packed buckyballs a charge and electromagnetically shoot them into the center of the lasers and POOF you have fusion..

    Just a thought, any comments?

    1. Re:How about fusion instead of fuel cells... by mako1138 · · Score: 1

      Assuming the things can be manufactured (big if), there wouldn't be enough fuel inside a single buckyball to make igniting it worthwhile.

      It's not like you turn up the lasers to 100% and start throwing in fuel. The pulse applied to an ICF pellet is carefully shaped to achieve the maximum neutron yield. Lining everything up properly is also a pain. Plus current laser facilities are only able to do a few shots per day, at most.

      I guess the problems with this are the problems with ICF in general: our technology isn't there yet.

  25. Re:Not true! They will be VERY convenient for a bi by TheHawke · · Score: 4, Interesting

    One thing is that theoretics will blow singularities out the window. One theory holds that Jupiter's core is a solid mass of crystallized carbon. Yep, you can guess what that is, Diamond. Another theory, with a more stable foundation, is that hydrogen at that pressure and temperature, becomes metallic. Essentially within your little buckyball, you would have a sphere of hydrogen metal. If your buckyball can handle > 100GPa,(over one million atmospheres) then the hydrogen atoms will undergo a phase change and become metallic.

    If this is practical and it's energy potential can be tapped, we'll have at our fingertips, an unlimited power source that won't kill you with radiation.

    http://en.wikipedia.org/wiki/Metallic_hydrogen

    --
    First rule of holes; When in one, stop digging.
  26. Re:Not true! They will be VERY convenient for a bi by clonan · · Score: 1

    ummm....I hope you are suggesting that we could pull it from Jupiter's core rather than treating the H2 we compress as an energy SOURCE.

    Even pulling it from the core doesn't really help us. What would we use to oxidse it once we have burned ALL the Oxygen?

    Can you go into more detail on what you are suggesting?

  27. Re:Not true! They will be VERY convenient for a bi by ArcherB · · Score: 2, Insightful

    ...If your buckyball can handle > 100GPa,(over one million atmospheres)... If your buckyball can handle > 100GPa,(over one million atmospheres), then you should just be able to inject a few under a piston, release the pressure and use the released pressure to drive your engine.

    --
    There is no "I disagree" mod for a reason. Flamebait, Troll, and Overrated are not substitutes.
  28. Energy costs by gnixdep · · Score: 1

    The cost of splitting hydrogen from water, then recombining it in a fuel cell is huge. It operates at approximately 35% efficiency. Lithium-ion batteries have a round trip efficiency of over 90%, are cheaper, and can be recharged in minutes.

    Hydrogen has been passed by as a technology, and nobody seems to realize it yet, because it has enough capital behind it which is pushing for it's adoption so the investments made can be paid off.

  29. H, a power source by Ralph+Spoilsport · · Score: 2, Interesting
    Hydrogen can be an excellent power source

    Hydrogen is more of a battery than a fuel and it is ALWAYS by DEFINITION going to have negative ER/EI. Why? Because the energy required to pull hydrogen out of water or methane or petroleum is going to be greater than the energy you get from burning the hydrogen. What the "hydrogen economy" seeks to do is to protect the sunken cost of the suburbs, and the sunken costs of the automotive infrastructure, both of which are joined at the hip and are completely unsustainable. It's a fools errand and will fail. There is also the not inconsiderable energy that goes into making the bucky balls, etc.

    Face it: gigs up. Game over. Prepare to slowly powerdown.

    RS

    --
    Shoes for Industry. Shoes for the Dead.
  30. Here's How They Work (Informative!) by Colonel+Korn · · Score: 5, Informative

    Okay, no one in a modded-up post on this story understands the concept. Buckyballs look like soot. You have a tank filled with this soot in your car. Then you flow very high pressure hydrogen gas over them for awhile (this has been done for years with carbon nanotubes, which offer more storage but because they only confine in 2 dimensions, unlike the balls, they don't provide the capillary forces necessary to make this easy). Hydrogen then adsorbs (notice ADsorbs, not ABsorbs) onto the inner surfaces of the Buckyballs. Capillary forces, like those that cause liquid to be drawn into a straw, allow the hydrogens to live essentially as liquids inside the balls, meaning that when you remove the high pressure hydrogen flow, the hydrogren in the buckyballs doesn't all immediately fly out. Hydrogen leaks out of the balls slowly, becoming a gas and maintaining a roughly constant pressure in the tank, and you then siphon off the hydrogen that you want to power your car. You can control the leakage rate by changing the temperature.

    You then reuse the Buckyballs by flowing hydrogen gas over them when they're empty. They're 100% reusable storage, not tiny gas tanks. Someone mod this up so that the dozens of "oh nos, Buckyballs hurt teh environments" posts go away.

    --
    "I zero-index my hamsters" - Willtor (147206)
    1. Re:Here's How They Work (Informative!) by John+Hasler · · Score: 1

      > Hydrogen leaks out of the balls slowly, becoming a gas and maintaining a roughly constant
      > pressure in the tank...

      What happens when you leave the car parked over the weekend? Seems like the pressure is going to rise to the "very high pressure" at which it was put in the balls.

      --
      Warning: this article may contain humor, sarcasm, parody, and perhaps even irony. Read at your own risk.
    2. Re:Here's How They Work (Informative!) by mapsjanhere · · Score: 4, Informative

      You will reach an equilibrium pressure in your tank at which adsorption and desorption occur at the same speed. The big question here is kinetics anyway. How fast does the hydrogen adsorb, and how fast can it be released? The whole idea only becomes practical if you can "fill your tank" in a reasonable time and with decent equipment requirements, lets say 5 min at 2000 psi. And the release has to be fast enough to allow an engine to generate 100 kW or so without depleting the hydrogen flow (or needing a m^3 of tank).

      --
      I'm aging rapidly, I bought a new game and had no idea if my machine was good for it.
    3. Re:Here's How They Work (Informative!) by Anonymous Coward · · Score: 0

      Wrong. What you are describing is how you load hydrogen into the pores between buckyballs in a C60 crystal. What this article describes is theory based on hydrogen loaded inside a single buckyball cage. Due to the pore size (basically it's a C6/C5 ring, depending on where you are on the buckyball), you can't load hydrogen into the cage of a buckyball.

      To get hydrogen inside a buckyball, you actually have to synthesize the buckyball with hydrogen in there (at least, at this point. No one has a better way to do it). This has been done for a single hydrogen molecule. Being able to do it for the pressures they are talking about . . . is nowhere on the horizon.

      The gas adsorption method that you describe is typical, but it's not what we're talking about in the case. It was shown a while back (FitzGerald et al, Phys. Rev. B, 65, 2002) that the kinetics of the situation are just absurd. It takes hours to reach an equilibrium loading situation at room temperature, and even that is only about 1 H2 per C60 (I'll let you do the math, but 1 C is ~ 6 times as massive as an H2, so the loading by volume . . . is very low). C60 through traditional gas adsorption has no potential to store hydrogen for commercial purposes. These days, much attention is being focused on metal organic frameworks (MOFs), which operate by similar methods, but hold much more C60 by weight (~10% for the best) . . . the problem is the binding energies are still so low that they don't hold hydrogen at room temperature very well at all.

    4. Re:Here's How They Work (Informative!) by Gryphia · · Score: 2, Informative

      Oops. Wasn't logged in. So no one will see the previous comment, I'm sure. Wrong. What you are describing is how you load hydrogen into the pores between buckyballs in a C60 crystal. What this article describes is theory based on hydrogen loaded inside a single buckyball cage. Due to the pore size (basically it's a C6/C5 ring, depending on where you are on the buckyball), you can't load hydrogen into the cage of a buckyball. To get hydrogen inside a buckyball, you actually have to synthesize the buckyball with hydrogen in there (at least, at this point. No one has a better way to do it). This has been done for a single hydrogen molecule. Being able to do it for the pressures they are talking about . . . is nowhere on the horizon. The gas adsorption method that you describe is typical, but it's not what we're talking about in the case. It was shown a while back (FitzGerald et al, Phys. Rev. B, 65, 2002) that the kinetics of the situation are just absurd. It takes hours to reach an equilibrium loading situation at room temperature, and even that is only about 1 H2 per C60 (I'll let you do the math, but 1 C is ~ 6 times as massive as an H2, so the loading by volume . . . is very low). C60 through traditional gas adsorption has no potential to store hydrogen for commercial purposes. These days, much attention is being focused on metal organic frameworks (MOFs), which operate by similar methods, but hold much more C60 by weight (~10% for the best) . . . the problem is the binding energies are still so low that they don't hold hydrogen at room temperature very well at all.

    5. Re:Here's How They Work (Informative!) by DerekLyons · · Score: 1

      Someone mod this up so that the dozens of "oh nos, Buckyballs hurt teh environments" posts go away.

      And no Buckyballs will ever be released in accidents? (Industrial or automotive?)
    6. Re:Here's How They Work (Informative!) by cupofjoe · · Score: 2, Informative

      I'd like to second Colonel Korn on this one (I've certainly never written THAT before); the concept of reusable hydrogen storage materials is not a new one. It's devilishly difficult, of course, but not new. Check out http://hydrogen.energy.gov/ to see what's been done so far.

      Buckyballs, like carbon nanotubes (CNTs) before them, store hydrogen by physisorption, whereby hydrogen molecules (not atoms, usually) "stick" to the near-surface via van der Waals forces (or equivalent). The issue with CNTs, of course, is that they really didn't do it as well as folks had hoped (or originally thought; there was some controversy over this). Overall, physisorption systems (the AD- vs. AB-sorption that the parent was referring to) don't do as well as chemisorption systems like metallic hydrides, though. The peak capacities are something like 3-6% vs. 12-15%, respectively.

      But let's not mince words here; the real key issue in this case is that the nice folks at Rice have RUN A MODEL. They haven't done any empirical work to determine whether this actually works. If you've been keeping score here, that's where the rubber meets the road. Personally, I'm not holding my breath on the claimed 8% number.

      After working in this field for a while, I've noticed that these kinds of claims appear at regular intervals (usually from universities with good media departments) regarding "miracle materials" that store tons of hydrogen. Don't get me wrong; any active thinking is progress - but let's be productively skeptical, eh?

      To Rice's PR department: good show, but I don't buy it. Sorry for the cynicism.

      Cheers,
      --joe.

    7. Re:Here's How They Work (Informative!) by fritsd · · Score: 1

      To get hydrogen inside a buckyball, you actually have to synthesize the buckyball with hydrogen in there (at least, at this point. No one has a better way to do it).
      Can't the H2 tunnel in through the center of one of the hexagons (I mean minimum of the potential energy surface)? Or am I talking stupid now..
      --
      To be, or not to be: isn't that quite logical, Slashdot Beta?
    8. Re:Here's How They Work (Informative!) by Gryphia · · Score: 1


      Can't the H2 tunnel in through the center of one of the hexagons (I mean minimum of the potential energy surface)? Or am I talking stupid now..

      Not in any significant quantity. If you mean tunneling in a quantum mechanical sense . . . I don't have any actual numbers, but I'm going to go out on a limb here. I've never seen any mention in the literature (and H2 storage in similar materials has been my research for the past year or two) of such a thing happening. I'm sure it's possible, but I think the probability of getting 1 H2 in there is rather low, let alone enough to achieve the pressures they're talking about.

      What you have to realize is that the distance across one of the C6 or C5 rings is on the order of 1nm. And the bond length of H2 is on the order of .1nm. So, it's going to get *really* close to the carbons to do that. Some recent calculations I ran (suspect, as they used DFT, which is notoriously bad for hydrogen . . . but we're thinking of doing some work with the H2 inside C60 samples that have been synthesized recently) suggested that there's a repulsive potential for H2 near the C6 or C5 ring on the order of ~100 times of the attractive potential the hydrogen experiences in crystaline C60 (when you just let it seep in).

      That's a very large (and thick, compared to the size of the H2) potential barrier to overcome, and so the probability that the wavefunction will exist on the other side . . . is likely pretty low. I don't have any numbers on it, but I wouldn't bet on ever having it happen in a high enough quantity to be observable, let alone useful.
    9. Re:Here's How They Work (Informative!) by fritsd · · Score: 1

      Thanks for your response. And hey, don't berate DFT (because it doesn't use Slater functions?), at least it's cheap :-)

      --
      To be, or not to be: isn't that quite logical, Slashdot Beta?
  31. Wow, I was just asking about.... by otis+wildflower · · Score: 1

    ... something similar... Presumably a Buckytube wouldn't be able to handle as much pressure, but could it handle enough to compress silane into superconductivity? Sealed off at each end with, I guess you'd call it a Buckydome?

  32. Just another good idea, with no way to execute... by ZonkerWilliam · · Score: 1

    Good idea, but without a solid method to encapsulate and remove the hydrogen, in a rapid cost effective manner, this is just a scientific curiosity.

  33. Re:Not true! They will be VERY convenient for a bi by Naughty+Bob · · Score: 1

    A small briefcase will hold 100 CC plus a little extra.
    That's would be one tiny briefcase. 100cc is about the size of a small apple, and I don't mean a MacBook Air.
    --
    "Be light, stinging, insolent and melancholy"
  34. Re:Not true! They will be VERY convenient for a bi by MindStalker · · Score: 1

    A fact about something we can never physically see? Sure...

  35. Weight ratio by Midnight+Thunder · · Score: 0

    Hmm, I wonder how much weight the bucky balls add to the whole solution. If it does not add too much weight, maybe it could be a solution for future airships. Would have to do some research here.

    --
    Jumpstart the tartan drive.
  36. trap door required by dougwhitehead · · Score: 1

    Yes this is not practical today. This will likely require an atom or two of something else that can mimic a carbon bond in certain conditions and not under other. Open the trap doors, compress the hydrogen, close the trap doors. Now the hydrogen is trapped in the buckyball powder. It would make a nice release mechanism as well.

    Currently this is science fiction.

  37. Re:Just another good idea, with no way to execute. by John+Hasler · · Score: 1

    And of course no one will look for such a method because this is just a "scientific curiosity".

    --
    Warning: this article may contain humor, sarcasm, parody, and perhaps even irony. Read at your own risk.
  38. memories of 1992 by u8i9o0 · · Score: 1

    A classmate of mine in a chemistry class was discussing with the instructor some potential practical applications for fullerenes, and the only example I can remember was that of hydrogen storage for automobile fuel. I also remember him referring to Popular Science Magazine for that example.

    This scene occurred in late July of 1992.

    I never saw the actual article, but maybe someone here can confirm this. I would assume it to have been published sometime within 1 year before that date.

    --
    This is not my sig
  39. Re:Not true! They will be VERY convenient for a bi by ukemike · · Score: 4, Informative

    If this is practical and it's energy potential can be tapped, we'll have at our fingertips, an unlimited power source that won't kill you with radiation. It astonishes me how often /.ers forget the first and second law of thermodynamics. You'll only have the unlimited source of energy after you expended the same amount of energy (and more) generating and compressing the hydrogen to get it into the buckyballs in the first place.

    Wake up world. Hydrogen isn't a source of energy any more than capacitors are. It's a way to store energy.
    --
    -- QED
  40. I thought... by Anonymous Coward · · Score: 0

    I thought BuckyBalls were those fake testicles that rednecks hang from the back of their over-sized mud-covered trucks...

  41. Re:Not true! They will be VERY convenient for a bi by Anonymous Coward · · Score: 0

    The first law of thermodynamics is: you do not talk about thermodynamics.
    The second law of thermodynamics is: you DO NOT talk about thermodynamics.

  42. Re:Not true! They will be VERY convenient for a bi by Anonymous Coward · · Score: 0

    If this is practical and it's energy potential can be tapped, we'll have at our fingertips, an unlimited power source that won't kill you with radiation.
    Hydrogen is a portable power source, but you need energy to extract and package the hydrogen. That will come from nuclear power plants. Fortunately, those won't kill you either. Unless you open that door, that door, that hatch, the other hatch, climb down that ladder, go back and get a 2x6, bring it back, prop it across to the support frame, climb over, crack open a fuel rod, and swallow some fuel. That might do the trick. Oh, you first should have checked the inventory and chosen a fuel rod with old fuel. Try again.
  43. Leaks by YetAnotherBob · · Score: 2, Interesting

    So, you have a system that can store hydrogen in carbon balls at high pressures. (the cold fusion folks manage to get 6000 pascals or so inside a metal lattice chemically.) What I want to know is how long can you store it. Hydrogen leaks through anything. the atoms fit BETWEEN the molecular bonds in most metals, plastics, even wax. That's the reason that space rockets are refueled constantly. (boil off of something that boils at 4 Kelvin is really something too!) The tanks leak!

    What is the half life of the hydrogen storage in this system?

    So, if the buckyball left the factory last month, how much H2 content will it still have? Once it decays down to atmospheric temperature, it does me no practical good.

    --
    Everybody knows 3 people with my name.
    1. Re:Leaks by Gryphia · · Score: 1

      Hydrogen doesn't go in or out of the cage of a buckyball. That's why you have to put it in there during synthesis. Which is the whole problem with this idea. No one can do that yet, except with a single H2. I suppose it's possible that with such a high pressure, you might get some leakage, but at least with the single H2 in buckyball samples, it's perfectly stable.

  44. Re:Just another good idea, with no way to execute. by ZonkerWilliam · · Score: 1

    Not at all, But the media tends to put a spin on "scientific breakthrough's" that lead the average reader to be let down when they realize it will be many years before we see this type of technology materialize, if ever.

  45. Re:Not true! They will be VERY convenient for a bi by kestasjk · · Score: 1

    If this is practical and it's energy potential can be tapped, we'll have at our fingertips, an unlimited power source that won't kill you with radiation. Sounds like nuclear power; unlimited and won't kill you with radiation.
    --
    // MD_Update(&m,buf,j);
  46. Re:Not true! They will be VERY convenient for a bi by BlueParrot · · Score: 1

    I still prefer to obey the laws of thermodynamics.

    Also, radiation won't kill you if you just make sure it is absorbed in something that isn't alive. Like 3-4 meters of boron and uranium spiked concrete.

  47. Re:Not true! They will be VERY convenient for a bi by Rei · · Score: 4, Insightful

    Well, this seems to be purely theoretical work about whether buckyballs *could* contain dense hydrogen, not how to achieve it. However, I can think of two very interesting possibilities, energy-wise, if it could be achieved.

    1) Superconductivity: Metallic hydrogen is a superconductor. Not sure how that would work conducting current through the shells, though. While just being a superconductor doesn't give you energy, it makes it easier to transmit energy.

    2) Fusion is all about the combination of the density of your targets and energy of your collisions. This is some impressive hydrogen density being discussed.

    --
    That was either the start of something bad or the end of something stupid.
  48. Re:8%? Why, that's more than half as good as octan by Chris+Johnson · · Score: 1

    Actually, more than half as good as gasoline is pretty damn good. If anyone managed to do energy storage more efficiently than hydrocarbons it would really be impressive...

  49. Hydrogen is Not a Power Source by Doc+Ruby · · Score: 1

    Hydrogen can be a useful element for storing power, but it is not a power source, except (shortsightedly) when looking only at the device in front of you at the moment.

    Sure, the only true power sources are the Sun, the Earth's core, and radioactive decay, but I'm not being hair-splitting. Even petroleum or gasoline can be considered "power sources", because they've already been "charged" (by the Sun and the Earth's gravity). There are no standing deposits of hydrogen around on the Earth already charged and waiting. The only way to get power from hydrogen here is to charge it up with an actual power source, and use the hydrogen as transport, like when electrolyzing water. Or to purify charged hydrogen from other charged energy-bearing materials, like from ethanol, gasoline or the like. Producing hydrogen with enough energy in it to use to power devices requires putting energy in, and is a net reduction in the total energy available before producing the charged hydrogen.

    As transport, hydrogen has many efficiencies, so it's well worth exploring as a storage material. Handling it can be energy inefficient, so converting it to other materials (especially room-temperature/pressure liquids) can be a net gain, though that expends energy, too.

    --

    --
    make install -not war

  50. Re:8%? Why, that's more than half as good as octan by Anonymous Coward · · Score: 0

    That's not even a little true. Gasoline is a complex cocktail of hydrocarbons, which may not include an octane isomers in appreciable amounts. The octane rating of gasoline does not actually mean the amount of octane contained by it.

  51. Re:Not true! They will be VERY convenient for a bi by Anonymous Coward · · Score: 0

    And can you see the Earth's molten core?

  52. change the name to BuckyBombs then? by peter303 · · Score: 1

    Anything with that high of an energy density could release it is suddenly?

  53. Re:Not true! They will be VERY convenient for a bi by Anonymous Coward · · Score: 0

    "A small briefcase will hold 100 CC plus a little extra."

    A small briefcase indeed, considering 100CC is about 1x2x3 inches.

  54. Re:Not true! They will be VERY convenient for a bi by Xyrus · · Score: 1

    Actually, I was thinking that since hydrogen becomes super-conductive at high pressures at room temperature this would be one way to achieve a room temp super conductor. Or possibly apply this with the salene (SiH4?) compound from the other day and have higher temperature super conductors.

    ~X~

    --
    ~X~
  55. Still seems overly complex. by Pedrito · · Score: 1

    This still seems like a lot more trouble than the existing solution of dropping an aluminum/gallium alloy in water and presto, hydrogen on demand (with aluminum oxide as waste which can be restored to aluminum). No high pressures required, the only production required is the aluminum/gallium alloy. The gallium is completely reusable and the aluminum can be recovered from the aluminum oxide and at commercial production levels would be around the price of gas now. It would get cheaper with time as the processes are streamlined.

    The only problematic issue is recovery of the aluminum from aluminum oxide which requires a good deal of electricity (it requires electrolysis). That said, if this step could be done with a green energy source (say wind, solar, geothermal, whatever) then it would be a completely clean source of energy.

  56. Use the excess energy from the sun by Anonymous Coward · · Score: 0

    [Ralph Spoilsport wrote] Because the energy required to pull hydrogen out of water or methane or petroleum is going to be greater than the energy you get from burning the hydrogen


    However, a lot of that "wasted" excess energy could be harvested from the sun, which produces energy that is currently wasted in heating up dirt. NPR's "Talk of the Nation" has had two interesting segments which introduce the idea of building a vast solar array in the Nevada desert to power ALL of the electricity needs of the United States of America:

    -February 1, 2008 A Bright Future for Solar Energy?
    - March 14, 2008 The Potential of Solar Power

    You can listen to both segments for free at http://www.npr.org/templates/story/story.php?storyId=88239836

    The United States Congress has been holding hearings on the feasibility of these projects.

    PBS's "NOVA" science program also has a program "Saved by the Sun" discussing current projects underway, such as those in Germany and the United States, to tap into solar power. You can watch the whole show online for free at

    http://www.pbs.org/wgbh/nova/solar/program.html
  57. High pressure? by Anonymous Coward · · Score: 0

    What kind of temperature is needed to maintain containment?

    I don't claim to know enough about this, but can it be used in relation to the high-pressure super conductors linked recently? If the buckyballs can hold silicon-hydrogen at high-pressures and the temperature requirements for containment in this case are not as difficult to maintain as our best efforts at temperature based super-conductors... well, you see where I'm going with this.

  58. Re:Not true! They will be VERY convenient for a bi by nuzak · · Score: 1

    Pshaw, you can almost solo molten core these days with tier 3 gear.

    --
    Done with slashdot, done with nerds, getting a life.
  59. Re:Not true! They will be VERY convenient for a bi by Dzonatas · · Score: 1

    When hydrogen gains a metallic property, then the fullerene become a ready fuel cell itself. The metallic property will create the needed catalyst (while it lasts as a metal) in order for the fuel-cell process to react and produce energy.

  60. Re:The Kinetics Suck by Gryphia · · Score: 1

    First off, the type of loading described in the parent isn't what's going on here. We don't have gas trapped in pores in crystaline C60 in between buckyballs, we actually have H2 stuck inside a buckyball cage. Which you can only get in there during synthesis. This isn't gas adsorption. And right now, we only know how to stick 1 H2 inside a buckyball cage during synthesis. Not the insane pressures they talk about in the article. Those are probably a *long* way off. Second, the kinetics for loading H2 in C60 are very slow. It takes hours to load at room temperature, and even then it only loads to 1 H2 per C60 (see FitzGerald et al, Phys. Rev. B, 2002), which, in terms of loading by weight, is . . . low. 1 C is ~6x as massive as an H2. So, 1 C60 is ~360x as massive as an H2. So, you have a loading of . . . 1/360th by weight. Nowhere near the DOE standard of ~10% by weight that is the goal right now.

  61. Comparing to pyrene by vuo · · Score: 2, Informative

    Pyrene is a hydrogen transfer catalyst that can contain 0.99% hydrogen if hydrogenated to 4,5-dihydropyrene. I did the same H2 content calculation for C60 and found that the current state of the art, one H2 in one fullerene or C60@H2, is 0.28% hydrogen. To be better than pyrene, you need to put in eight hydrogen atoms as four H2 molecules, or C60@4H2. To give that 8% storage capacity you need not less than 62 hydrogens, or C60@31H2. That's slightly more than one hydrogen per one carbon, which is a lot. (Gasoline is 16% hydrogen, btw.)

    The major problem with this "discovery" (it's just a calculation, I'd say) is that you'll need to design a chemical synthesis that forces metallic hydrogen into a buckyball, without inducing hydrogenolysis (spontaneous production of hydrocarbons from hydrogen and carbon). Then you should be able to design molecular "hatch" that you can open and close while being under this enormous hydrogen pressure. A small obstacle to this being that I suspect nearly any heteroatom you'd need for the hatch would be immediately torn off by hydrogenolysis. My guesstimate would in fact be that the fullerenes themselves would be hydrogenolyzed on contact with metallic hydrogen. As you can see, it's the physicists and their phyucher flying cars again. It's interesting but no real problem has been solved.

    And also, the problem of producing the hydrogen is still unsolved, no matter the hype. The problem that we want a reducing agent (H2), which unavoidably requires energy to produce. The major options are fossil and nuclear; the world runs out of arable land area if we try to produce it by agriculture. Actually the situation can be summarized like this:

    1. Invent technologies to transport or spend existing hydrogen (fuel cells, hydrogen storage, etc.)
    2. ???
    3. Hydrogen economy!

  62. Re:Not true! They will be VERY convenient for a bi by bar-agent · · Score: 1

    Superconductivity: Metallic hydrogen is a superconductor. Not sure how that would work conducting current through the shells, though.

    Aren't buckyballs small enough to allow quantum tunneling from one ball's hydrogen core to an adjacent ball's core? If so, and if quantum tunneling doesn't break superconductivity properties, Bob's yer uncle.

    (BTW, anyone who comes up with some good ball jokes here gets an e-cookie.)

    --
    i'd hit it so hard, if you pulled me out you'd be the king of britain [bash.org]
  63. Re:Not true! They will be VERY convenient for a bi by amRadioHed · · Score: 2, Insightful

    Pedantically speaking oil isn't an energy source either, it's just a storage medium for solar energy.

    --
    We hope your rules and wisdom choke you / Now we are one in everlasting peace
  64. Re:Not true! They will be VERY convenient for a bi by xtal · · Score: 2, Insightful

    We have, already, an unlimited source of energy in the Sun. The real problem is how to transport and condense that energy into useful-to-us forms..

    --
    ..don't panic
  65. Re:Not true! They will be VERY convenient for a bi by TheHawke · · Score: 1

    You are onto something there. "Pelletized" Hydrogen or Deuterium in a high pressure, semi metallic or metallic state, do you think that there might be a energy bonus there?

    --
    First rule of holes; When in one, stop digging.
  66. Oh Wait by Anonymous Coward · · Score: 0

    Great, you can now store 8% by weight of H in buckyballs. How do you get it out? Oops!

  67. Re:Not true! They will be VERY convenient for a bi by Anonymous Coward · · Score: 1, Interesting

    I wonder if the silane mentioned in yesterdays article could be kept in those buckyballs at extreme pressure? That might prove to be interesting.

  68. Re:Not true! They will be VERY convenient for a bi by celtic_hackr · · Score: 1

    I'm not sure you want to compress just the core, which is *estimated* to be between 10 to 45 times as massive as Earth not just about 10x, instead of the whole planet which is estimated about 318 times as massive.

    Me, personally, I'd like to have a point point singularity encased in a graviton isolation sphere suspended on a chain to wear around my neck.
    Not to mention your back of the envelope math sucks, because I'm pretty sure Euclidean geometry breaks down when dealing with singularities and volume:mass relations are nonlinear. Not to mention that I'm not entirely sure that the mass:volume relation of 1:1 is a valid assumption. It would be my guesstimate that with more mass the volume would decrease and a 10x massive object would shrink logarithmically.

    What would be interesting is to compress Hydrogen to it's liquid-metal state, like the core of Jupiter and place it inside a Buckyball.

    I see potential for this Hydrogen-Buckyball in creating a new energy storage system. You could create long string-like buckyballs filled with Hydrogen, and line them up in a plane and encase them in a thin plate with oxygen or fluorine or some other electron hungry element and bang you've got a Hydrogen Ion battery. So now don't any of you greedy Corporate B!@#$$#S try and patent it, because it's now public domain and the prior art is /. archived!

    Or perhaps you could accelerate the Hydrogen Buckyballs to near light speed and slam them into each other at a steady rates to make a pulsed fusion reactor that could be used a a clean source of energy or even as engines for interstellar travel.

  69. Re:Not true! They will be VERY convenient for a bi by WalksOnDirt · · Score: 2, Funny

    ...an unlimited source of energy in the Sun. I understand why you would say this, but you think too small for my tastes. The Sun doesn't contain enough energy in total for some of my more grandiose schemes.
    --
    a,e,i,o,u and sometimes w and y (at be if of up cwm by)
  70. Re:Not true! They will be VERY convenient for a bi by sbeckstead · · Score: 0

    Surplus Tardis Chameleon Circuit...

  71. up to 8% of its weight by neonsignal · · Score: 1

    ...hey, I've found this stuff called methane that can store up to 30% of its weight in hydrogen!

  72. Re:8%? Why, that's more than half as good as octan by ChrisMaple · · Score: 1

    Considering gasoline as octane is a good approximation for many purposes, one of which is hydrogen fraction.

    --
    Contribute to civilization: ari.aynrand.org/donate
  73. Re:Not true! They will be VERY convenient for a bi by Skevin · · Score: 1

    But you know what they say, it's never about the size... it's all about the mass and how you use it.

    S.

    --
    "Twice half-assed makes an ass whole." --Solomon K. Chang
  74. Re:Not true! They will be VERY convenient for a bi by amRadioHed · · Score: 1

    Those are problems but I think the biggest problem is just turning the energy into useful forms. Photovoltaic, wind, ethanol, these are all still niche power sources.

    --
    We hope your rules and wisdom choke you / Now we are one in everlasting peace
  75. Re:Not true! They will be VERY convenient for a bi by Naughty+Bob · · Score: 1

    Volcanoes.

    --
    "Be light, stinging, insolent and melancholy"
  76. i've seen this before by Anonymous Coward · · Score: 0

    they had this on the last season of andromeda
    seefra 2 was an artificial sun with hyrogen stored in carbon arms

  77. the math: not quite by Anonymous Coward · · Score: 0
    You're thinking of the Schwarzschild Radius, which describes the even horizon of any given mass density. It works like this: any mass that resides within its Schwarzschild radius (after being compressed, etc.) will be a "black hole" because no force can prevent such a mass from collapsing ever further, into a so-called singularity. The mass in question doesn't have be symmetric, as proven by Penrose.

    So for any given mass, we can calculate the threshold radius (the Schwarzschild radius), and conversely for any given radius, we can find the threshold mass, which is the same thing stated differently anyway. At the Schwarzschild radius, the escape velocity is equal to the speed of light; that's why an early concept/name for what we now call "black holes" was "frozen stars": the image of the star would be "frozen" into the even horizon as it existed at the moment of last escape.

    So, the Schwarzschild radius for:
    Earth = 9mm (true radius is ~6350km; your 10cc figure is about 3x larger than the volume of a spherical shell with r=9mm)
    Sun = ~3km (a bit less; true radius is ~695,000km)
    white dwarf = ~2.5km (for an individual with ~.8 solar masses; true radius is something like ~10,000km, so somewhat larger than Earth)
    neutron star ~= 6km (for an individual with ~2 solar masses; note that they are compressed nearly this small with their radii of 8~10km, so they're almost black holes! This is known as the "Tolman-Oppenheimer-Volkoff limit" for neutron stars.)

    Jupiter's core is about 10 earth masses Depending on how one defines Jupiter's "core", you could simply pick a corresponding mass.

    Ergo one Jupiter core will form a singularity at about [10x the Earth-mass singularity volume]. Not quite:
    Rs = 2*G*m/c^2
    and let's say 2*G/c^2 = k, so we can write it more simply as:
    Rs = m*k

    So the Schwartzschild radius increases linearly with mass, but you were talking about the volume:
    (4/3)*Pi*Rs^3 = 10cc for Earth (it's actually about 3cc, but we'll use your numbers)
    Volume goes as the cube of the Schwarzschild radius (which fixes the mass), so equivalently the mass (which fixes the Schwarzschild radius) goes as the cube root of volume.
  78. This has super conductor implcations too. by dsmatthews · · Score: 1

    If you can get the pressure high enough on the hydrogen trapped in a long carbon nano tube with end caps, then you have a high temperature super conductor. dan@tekgnu.com

    1. Re:This has super conductor implcations too. by dsmatthews · · Score: 1

      And if you make a carbon nano torus containing compressed hydrogen you have a nano super conducting magnet. I wonder if you can cut a template out of a 2d sheet of graphene using a particle beam so that when it is allowed to fold up it will form such a torus? http://en.wikipedia.org/wiki/Graphene If that works you can make any form that is a developable surface from a graphene template. http://en.wikipedia.org/wiki/Developable_surface The idea being that the template is folded into the surface while in the presence of hydrogen under extreme pressure so that the hydrogen is trapped inside in an almost metallic configuration. dan@tekgnu.com

  79. Yes, an atom /can/ have a pressure. by Dr.+Cody · · Score: 1
    For the purposes of gas-solid diffusion, yes, these terapascal pressures play a large role in the migration of former alpha particles into grain boundaries and other imperfections, where they can produce "bubbles"--or even out of the fuel entirely. Pressure is energy divided by volume, and a particle bouncing around with kinetic energy in a volume as small as a lattice gap is going to get weird. These pressures are vitally important for the lifetime of an individual nuclear fuel element and frustratingly difficult to theoretically model.

    BTW, recreational scuba divers use materials whose bulk properties are two orders of magnitude from STP, and put their own personal materials under conditions of nearly one order of magnitude away, so that's not actually all that impressive.
    I don't see how we disagree; that was exactly my point.
  80. Hydrogen is not an energy SOURCE !! by RockDoctor · · Score: 1

    Hydrogen can be an excellent power source, but it is notoriously difficult to store.

    At least, not under conditions vaguely like Earth's surface. Hydrogen can be a good (or even very good) tool for storing and transporting energy from one place to another on the Earth's surface, but until someone discovers a hydrogen mine on the surface of the Earth, and someone else discovers a separate oxygen mine on the surface of the Earth, then neither is an energy source.
    To produce hydrogen in significant quantities on Earth, you need to chemically reduce water. You can do that directly (with electrolysis) or indirectly (for example, by electrolysing molten rubidium chloride to produce rubidium, then reducing water with the rubidium. It's the same reaction at the atomic level, but likely to be thermodynamically less efficient than the direct route.)

    It dismays me that even a forum like SlashDot, which claims to have a technically competent audience, allows such sloppy writing to persist. It might not be "kewel", but chemistry and thermodynamics are important, dammit! If it weren't for understanding thermodynamics, neither the engine in your car, nor the engine in the bus I use would work. And without the chemistry, we wouldn't have the materials to build either.
    --
    Birds are not dinosaur descendants;birds are dinosaurs, for all useful meanings of "birds", "are" and "dinosaurs"
  81. Re:Not true! They will be VERY convenient for a bi by emilper · · Score: 1

    If this is practical and it's energy potential can be tapped, we'll have at our fingertips, an unlimited power source that won't kill you with radiation.

    How about the CO2 ? It's only 8% hidrogen ... the rest is carbon. Kind of difficult to burn it without burning the C.

  82. The center of a gas giant by Anonymous Coward · · Score: 0

    No, no, no...haven't you read "The Algebraist"? We'll end up with a super-secret network of hidden wormholes.