Slashdot Mirror

A new adsorbent material "soaks up uranium from seawater, leaving interfering ions behind," reports the ACS's Chemical & Engineering News, in an article shared by webofslime: The world's oceans contain some 4 billion metric tons of dissolved uranium. That's roughly 1,000 times as much as all known terrestrial sources combined, and enough to fuel the global nuclear power industry for centuries. But the oceans are so vast, and uranium's concentration in seawater is so low -- roughly 3 ppb -- that extracting it remains a formidable challenge... Researchers have been looking for ways to extract uranium from seawater for more than 50 years...

Nearly 20 years ago, the Japan Atomic Energy Agency (JAEA) confirmed that amidoxime-functionalized polymers could soak up uranium reliably even under harsh marine conditions. But that type of adsorbent has not been implemented on a large scale because it has a higher affinity for vanadium than uranium. Separating the two ions raises production costs. Alexander S. Ivanov of Oak Ridge National Laboratory, together with colleagues there and at Lawrence Berkeley National Laboratory and other institutions, may have come up with a solution. Using computational methods, the team identified a highly selective triazine chelator known as H2BHT that resembles iron-sequestering compounds found in bacteria and fungi.... H2BHT exhibits little attraction for vanadium but has roughly the same affinity for uranyl ions as amidoxime-based adsorbents do.

"Researchers at Purdue University have developed a new chemical process that they say can convert approximately one-quarter of the world's plastic waste into gasoline and diesel-like fuels," writes Slashdot reader dmoberhaus. Motherboard explains how it works: As detailed in a paper published this week in Sustainable Chemistry and Engineering, the chemists discovered a way to convert polypropylene -- a type of plastic commonly used in toys, medical devices, and product packaging like potato chip bags -- into gasoline and diesel-like fuel. The researchers said that this fuel is pure enough to be used as blendstock, a main component of fuel used in motorized vehicles. Polypropylene waste accounts for just under a quarter of the estimated 5 billion tons of plastic that have amassed in the world's landfills in the last 50 years.

To turn polypropylene into fuel, the researchers used supercritical water, a phase of water that demonstrates characteristics of both a liquid and a gas depending on the pressure and temperature conditions. Purdue chemist Linda Wang and her colleagues heated water to between 716 and 932 degrees Fahrenheit at pressures approximately 2300 times greater than the atmospheric pressure at sea level. When purified polypropylene waste was added to the supercritical water, it was converted into oil within in a few hours, depending on the temperature. At around 850 degrees Fahrenheit, the conversion time was lowered to under an hour. The byproducts of this process include gasoline and diesel-like oils. According to the researchers, their conversion process could be used to convert roughly 90 percent of the world's polypropylene waste each year into fuel.

An anonymous reader quotes a report from NPR: One team of scientists, from MIT's Koch Institute for Integrative Cancer Research and Harvard's Brigham and Women's Hospital, developed a system to deliver insulin that actually still uses a needle -- but is so small you can swallow it and the injection doesn't hurt. They built a pea-size device containing a spring that ejects a tiny dart of solid insulin into the wall of the stomach, says gastroenterologist Carlo Giovanni Traverso, an associate physician at Brigham and Women's Hospital. "We chose the stomach as the site of delivery because we recognized that the stomach is a thick and robust part of the GI tract," Traverso says. Once the device gets into the stomach, the humidity there allows the spring to launch the insulin dart. As the researchers report in the journal Science, they've tested the device on pigs, and it can deliver a therapeutic dose of insulin provided the pig has an empty stomach.

On the other side of the U.S., nanoengineer Ronnie Fang of the University of California, San Diego and his colleagues have a different delivery system. Theirs is a kind of ingestible microrocket, about the size of a grain of sand, that is designed to zip past the stomach and into the small intestine. "It actually propels [itself] using bubbles in a reaction of magnesium with biological fluids," Fang says. The rocket has a coating that protects its payload from the acidic and enzyme-filled environment of the stomach. Once the rocket enters the small intestine, the change in acidity causes the coating to dissolve and lets the rocket stick to the intestinal wall to release its payload, in this case a vaccine protein. As Fang and his colleagues report in Nano Letters, their delivery system works in mice, but human testing is probably many years off.

An anonymous reader quotes a report from Genetic Engineering & Biotechnology News: Now, researchers at the University of Washington (UW) have genetically modified a common houseplant -- pothos ivy or devil's ivy -- to remove chloroform and benzene from the air around it. The modified plants express a mammalian protein, called 2E1, that transforms these compounds into molecules that the plants can then use to support their own growth. Small molecules like chloroform, which is present in small amounts in chlorinated water, or benzene, which is a component of gasoline, build up in our homes when we shower or boil water, or when we store cars or lawn mowers in attached garages. These compounds are too small to be captured by even HEPA air filters and exposure to each has been linked to cancer. Findings from the new study were published recently in Environmental Science & Technology.

Will Moore's law really come to an end by 2025? Maybe not...

An anonymous reader quotes IEEE Spectrum: [R]esearchers at RMIT University in Melbourne, Australia, believe a metal-based field emission air channel transistor (ACT) they have developed could maintain transistor doubling for another two decades. The ACT device eliminates the need for semiconductors. Instead, it uses two in-plane symmetric metal electrodes (source and drain) separated by an air gap of less than 35 nanometers, and a bottom metal gate to tune the field emission. The nanoscale air gap is less than the mean-free path of electrons in air, hence electrons can travel through air under room temperature without scattering...

Using metal and air in place of semiconductors for the main components of the transistor has a number of other advantages, says Shruti Nirantar, a Ph.D. candidate in RMIT's Functional Materials and Microsystems Research Group. Fabrication becomes essentially a single-step process of laying down the emitter and collector and defining the air gap. And though standard silicon fabrication processes are employed in producing ACTs, the number of processing steps are far fewer, given that doping, thermal processing, oxidation, and silicide formation are unnecessary. Consequently, production costs should be cut significantly. In addition, replacing silicon with metal means these ACT devices can be fabricated on any dielectric surface, provided the underlying substrate allows effective modulation of emission current from source to drain with a bottom-gate field. "Devices can be built on ultrathin glass, plastics, and elastomers," says Nirantar. "So they could be used in flexible and wearable technologies."
The article also suggests ACT devices could become important in space exploration, since electrons would be unaffected by extraterrestrial vacuums and radiation.

Nirantar was lead author on a new paper published in Nano Letters, and believes that their new approach "means we can stop pursuing miniaturization, and instead focus on compact 3D architecture, allowing more transistors per unit volume."

Chinese scientists have discovered a type of tea plant that naturally does not produce caffeine. They published their findings in the Journal of Agricultural and Food Chemistry. From a report: In 2017, Americans drank nearly four billion gallons of tea, according to the Tea Association of the US. The association estimates that up to 18 percent of those drinks were decaffeinated. To decaffeinate tea, manufacturers often use supercritical carbon dioxide or hot water treatments. However, these methods can affect the brew's flavor and destroy compounds that are associated with lowered cholesterol and reduced risk of heart attack or stroke. In the present study, researchers led by Dr. Chen Liang at the Chinese Academy of Agricultural Sciences studied hongyacha, a rare wild tea found in the mountains of southern China. They used high-performance liquid chromatography to analyze hongyacha buds and leaves collected during the growing season.

An anonymous reader quotes a report from National Geographic: New research shows microplastics in 90 percent of the table salt brands sampled worldwide. Of 39 salt brands tested, 36 had microplastics in them, according to a new analysis by researchers in South Korea and Greenpeace East Asia. Salt samples from 21 countries in Europe, North and South America, Africa, and Asia were analyzed. The three brands that did not contain microplastics are from Taiwan (refined sea salt), China (refined rock salt), and France (unrefined sea salt produced by solar evaporation). The study was published this month in the journal Environmental Science & Technology.

The density of microplastics found in salt varied dramatically among different brands, but those from Asian brands were especially high, the study found. The highest quantities of microplastics were found in salt sold in Indonesia. Asia is a hot spot for plastic pollution, and Indonesia -- with 34,000 miles (54,720 km) of coastline -- ranked in an unrelated 2015 study as suffering the second-worst level of plastic pollution in the world. In another indicator of the geographic density of plastic pollution, microplastics levels were highest in sea salt, followed by lake salt and then rock salt. Even though the study found that the average adult consumes approximately 2,000 microplastics per year through salt, it's not clear what the health consequences are.

An anonymous reader quotes a report from Engadget: [N]ew research published in ACS Applied Energy Materials shows that it's possible to 3D-print lithium-ion batteries into whatever shape you need. The problem that has stood in the way of 3D-printed lithium-ion batteries (at least, until now) is that the polymers traditionally used in this kind of printing aren't ionic conductors. The goal was to find a way to print custom-sized lithium-ion batteries in a cost-effective way using a regular, widely available 3D printer. In order to make the batteries conductive, the team led by Christopher Reyes and Benjamin Wiley infused the polylactic acid (PLA) usually used in 3D printing with an electrolyte solution. The researchers also incorporated graphene and carbon nanotubes into the design of the case to help increase conductivity. After these design modifications, the team was able to 3D print an LED bracelet, complete with a custom-sized lithium-ion battery. The battery was only able to power the bracelet for about 60 seconds, but the researchers have ideas for how to improve the capacity. For those interested, Engadget has a short video on the subject.

An anonymous reader quotes a report from Phys.Org: Rice University scientists have developed micron-sized calcium silicate spheres that could lead to stronger and greener concrete, the world's most-used synthetic material. The researchers formed the spheres in a solution around nanoscale seeds of a common detergent-like surfactant. The spheres can be prompted to self-assemble into solids that are stronger, harder, more elastic and more durable than ubiquitous Portland cement. He said the spheres are suitable for bone-tissue engineering, insulation, ceramic and composite applications as well as cement. The research appears in the American Chemical Society journal Langmuir.

In tests, the researchers used two common surfactants to make spheres and compressed their products into pellets for testing. They learned that DTAB-based pellets compacted best and were tougher, with a higher elastic modulus, than either CTAB pellets or common cement. They also showed high electrical resistance. [Rice materials scientist Rouzbeh Shahsavari] said the size and shape of particles in general have a significant effect on the mechanical properties and durability of bulk materials like concrete. He said increasing the strength of cement allows manufacturers to use less concrete, decreasing not only weight but also the energy required to make it and the carbon emissions associated with cement's manufacture. Because spheres pack more efficiently than the ragged particles found in common cement, the resulting material will be more resistant to damaging ions from water and other contaminants and should require less maintenance and less-frequent replacement.

Iwastheone quotes Phys.org: First, according to Rice University engineers, get a nanotube hole. Then insert water. If the nanotube is just the right width, the water molecules will align into a square rod. Rice materials scientist Rouzbeh Shahsavari and his team used molecular models to demonstrate their theory that weak van der Waals forces between the inner surface of the nanotube and the water molecules are strong enough to snap the oxygen and hydrogen atoms into place. Shahsavari referred to the contents as two-dimensional "ice," because the molecules freeze regardless of the temperature.

He said the research provides valuable insight on ways to leverage atomic interactions between nanotubes and water molecules to fabricate nanochannels and energy-storing nanocapacitors... The researchers already knew that hydrogen atoms in tightly confined water take on interesting structural properties. Recent experiments by other labs showed strong evidence for the formation of nanotube ice and prompted the researchers to build density functional theory models to analyze the forces responsible... They discovered that nanotubes in the middle diameters had the most impact on the balance between molecular interactions and van der Waals pressure that prompted the transition from a square water tube to ice.
The paper describes "solid-like water nanotubes," and the head of the research team believes they could have practical applications, according to the article.

"Nanotube ice could find use in molecular machines or as nanoscale capillaries, or foster ways to deliver a few molecules of water or sequestered drugs to targeted cells, like a nanoscale syringe."

An anonymous reader quotes a report from the BBC: Professor Veena Sahajwalla's mine in Australia produces gold, silver and copper -- and there isn't a pick-axe in sight. Her "urban mine" at the University of New South Wales (UNSW) is extracting these materials not from rock, but from electronic gadgets. The Sydney-based expert in materials science reckons her operation will become efficient enough to be making a profit within a couple of years. "Economic modeling shows the cost of around $500,000 Australian dollars for a micro-factory pays off in two to three years, and can generate revenue and create jobs," she says. "That means there are environmental, social and economic benefits." In fact, research indicates that such facilities can actually be far more profitable than traditional mining.

According to a study published recently in the journal Environmental Science & Technology, a typical cathode-ray tube TV contains about 450g of copper and 227g of aluminum, as well as around 5.6g of gold. While a gold mine can generate five or six grammes of the metal per tonne of raw material, that figure rises to as much as 350g per tonne when the source is discarded electronics. The figures emerged in a joint study from Beijing's Tsinghua University and Macquarie University, in Sydney, where academics examined data from eight recycling companies in China to work out the cost for extracting these metals from electronic waste.

Writing in the journal Nano Letters, scientists from Turkey, the U.S. and U.K. describe a material that acts as thermal camouflage. Cosmos reports: Coskun Kocabas and colleagues created a film comprising multiple ultra-thin layers of graphene and a bottom layer of gold, with non-volatile ionic liquid in between them. When a small current is applied, the ions move up into the graphene layer, cutting down the infrared radiation the surface would normally emit. Because it's thin, light and flexible the film can be applied to any number of surfaces, including clothing. Tests have successfully camouflaged a hand owned by a subject wearing a covering of the material, and others have shown it to be indistinguishable from its surroundings in a variety of ambient temperatures.

New submitter Paige.Bennett writes: Up till now, graphene has been produced in small batches in labs. But MIT just found a way to mass-produce graphene in large sheets using a process that rolls out five centimeters of graphene each minute. The longest span so far was nearly four hours, which produced about 10 meters of graphene. According to MIT, here's how their conveyor belt system works: "The first spool unfurls a long strip of copper foil, less than one centimeter wide. When it enters the furnace, the foil is fed through first one tube and then another, in a 'split-zone' design. While the foil rolls through the first tube, it heats up to a certain ideal temperature, at which point it is ready to roll through the second tube, where the scientists pump in a specified ratio of methane and hydrogen gas, which are deposited onto the heated foil to produce graphene." The work has been published in the journal Materials and Interfaces.

According to a new study, the best way to reduce pesticides from your supermarket apple is to use a baking soda solution. The discovery was made by a team of scientists from the University of Massachusetts at Amherst. They compared the effectiveness of plain tap water, a commercial bleach solution and a baking soda/water mix in removing pesticides from apples. CNET reports: The scientists started with organic Gala apples and applied the fungicide thiabendazole and the insecticide phosmet before testing the different washing liquids. "The baking soda solution was the most effective at reducing pesticide," a release on the study notes. "After 12 and 15 minutes, 80 percent of the thiabendazole was removed, and 96 percent of the phosmet was removed, respectively." The researchers say the industry-standard approach of washing fruit in a bleach solution for two minutes after harvest is not an effective way to completely remove pesticides. They also found the fungicide thiabendazole penetrated into the apple peel much more than the insecticide. Apple lovers would need to remove the peel to also get rid of the pesticide that wasn't washed off with the baking soda solution. The researchers published the findings this week in the American Chemical Society's Journal of Agricultural and Food Chemistry.

schwit1 writes: The Rice lab of chemist James Tour developed anodes comprising porous carbon made from asphalt that showed exceptional stability after more than 500 charge-discharge cycles. A high-current density of 20 milliamps per square centimeter demonstrated the material's promise for use in rapid charge and discharge devices that require high-power density. The Tour lab previously used a derivative of asphalt -- specifically, untreated gilsonite, the same type used for the battery -- to capture greenhouse gases from natural gas. This time, the researchers mixed asphalt with conductive graphene nanoribbons and coated the composite with lithium metal through electrochemical deposition. The lab combined the anode with a sulfurized-carbon cathode to make full batteries for testing. The batteries showed a high-power density of 1,322 watts per kilogram and high-energy density of 943 watt-hours per kilogram. Testing revealed another significant benefit: The carbon mitigated the formation of lithium dendrites. These mossy deposits invade a battery's electrolyte. If they extend far enough, they short-circuit the anode and cathode and can cause the battery to fail, catch fire or explode. But the asphalt-derived carbon prevents any dendrite formation.

"The capacity of these batteries is enormous, but what is equally remarkable is that we can bring them from zero charge to full charge in five minutes, rather than the typical two hours or more needed with other batteries," Tour said. "While the capacity between the former and this new battery is similar, approaching the theoretical limit of lithium metal, the new asphalt-derived carbon can take up more lithium metal per unit area, and it is much simpler and cheaper to make. There is no chemical vapor deposition step, no e-beam deposition step and no need to grow nanotubes from graphene, so manufacturing is greatly simplified." The findings have been published in the journal ACS Nano.

Big Hairy Ian quotes New Atlas: The wonder material graphene gets many of its handy quirks from the fact that it exists in two dimensions, as a sheet of carbon only one atom thick. But to actually make use of it in practical applications, it usually needs to be converted into a 3D form. Now, researchers have developed a new and relatively simple way to do just that, using lasers to 'forge' a three-dimensional pyramid out of graphene...

By focusing a laser onto a fine point on a 2D graphene lattice, the graphene at that spot is irradiated and bulges outwards. A variety of three-dimensional shapes can be made by writing patterns with the laser spot, with the height of the shape controlled by adjusting the irradiation dose at each particular point. The team illustrated that technique by deforming a sheet of graphene into a 3D pyramid, standing 60 nm high. That sounds pretty tiny, but it's 200 times taller than the graphene sheet itself.
"The beauty of the technique is that it's fast and easy to use," says one of the researchers. "It doesn't require any additional chemicals or processing."

Researchers from the Biosciences and Biotechnologies Institute of the French Alternative Energies and Atomic Energy Commission have discovered a new light-driven enzyme, christened fatty acid photodecarboxylase (FAP), that uses blue light to drive the removal of carboxyl groups from fatty acids to form alkanes or alkenes. Such an enzyme could be used as fuel with no further modification. The Biological SCENE reports: FAP joins a select group of so-called photoenzymes, including DNA-repair enzymes called photolyases, that use light for catalysis on their own rather than functioning as part of a larger complex such as photosystems I or II, which are used by plants and algae for photosynthesis. FAP contains flavin adenine dinucleotide (FAD), which commonly serves as a redox cofactor in biological reactions. In the case of FAP, however, FAD absorbs blue light to reach an excited state that abstracts an electron from the carboxylate group of a C12 to C18 fatty acid, which then decarboxylates to yield an alkane or alkene. The study has been published in the journal Science. Further reading: Ars Technica

Wave723 writes: IEEE Spectrum reports on a true random number generator that was created with single-walled semiconducting carbon nanotubes. Researchers at Northwestern University printed a SRAM cell with special nanotube ink, and used it to generate random bits based on thermal noise. This method could be used to improve the security of flexible or printed electronics. From the report: "Once Mark Hersam, an expert in nanomaterials at Northwestern University, and his team had printed their SRAM cell, they needed to actually generate a string of random bits with it. To do this, they exploited a pair of inverters found in every SRAM cell. During normal functioning, the job of an inverter is to flip any input it is given to be the opposite, so from 0 to 1, or from 1 to 0. Typically, two inverters are lined up so the results of the first inverter are fed into the second. So, if the first inverter flips a 0 into a 1, the second inverter would take that result and flip it back into a 0. To manipulate this process, Hersam's group shut off power to the inverters and applied external voltages to force the inverters to both record 1s. Then, as soon as the SRAM cell was powered again and the external voltages were turned off, one inverter randomly switched its digit to be opposite its twin again. 'In other words, we put [the inverter] in a state where it's going to want to flip to either a 1 or 0,' Hersam says. Under these conditions, Hersam's group had no control over the actual nature of this switch, such as which inverter would flip, and whether that inverter would represent a 1 or a 0 when it did. Those factors hinged on a phenomenon thought to be truly random -- fluctuations in thermal noise, which is a type of atomic jitter intrinsic to circuits." Hersam and his team recently described their work in the journal Nano Letters.

An anonymous reader shares a report: A study by chemists at the University of Connecticut offers new evidence that electronic cigarettes, or e-cigarettes, are potentially as harmful as tobacco cigarettes. Using a new low-cost, 3-D printed testing device, UConn researchers found that e-cigarettes loaded with a nicotine-based liquid are potentially as harmful as unfiltered cigarettes when it comes to causing DNA damage. The researchers also found that vapor from non-nicotine e-cigarettes caused as much DNA damage as filtered cigarettes, possibly due to the many chemical additives present in e-cigarette vapors. Cellular mutations caused by DNA damage can lead to cancer.

drunkdrone quotes a report from International Business Times: Researchers say they have developed a new material that could pave the way for self-repairing smartphones, robots and other electronic devices. Scientists from the American Chemical Society claim that the material, which can stretch up to 50 times its usual size, is able to heal itself "like nothing has happened" even when cut in two. The material is flexible, transparent and shares similar properties to human skin. When exposed to electrical signals, a current is generated that creates a chemical bonding reaction between molecules. The most obvious applications for electronics devices seems to be self-healing displays, although lead researcher Dr Chao Wang is also exploring the possibility of a self-healing lithium-ion battery. While the technology is similar to the hydrogen-infused rear cover found on the LG G Flex, which allows for small scratches to be healed, the material developed by the American Medical Society is a completely new innovation that can "automatically stitch itself back together" within one day of being sliced into pieces. The team will present its research at a Tuesday meeting of the American Chemical Society, according to Business Insider.

Scientists have developed a test designed to estimate how much urine has been covertly added to a large volume of water. "The test works by measuring the concentration of an artificial sweetener, acesulfame potassium (ACE), that is commonly found in processed food and passed through the body unaltered," reports The Guardian. The findings are published in the American Chemical Society journal. From the report: After tracking the levels of the sweetener in two public pools in Canada over a three-week period they calculated that swimmers had released 75 liters of urine -- enough to fill a medium-sized dustbin -- into a large pool (about 830,000 liters, one-third the size of an Olympic pool) and 30 liters into a second pool, around half the size of the first. Although the researchers were unable to confirm exactly what fraction of visitors were choosing to quietly relieve themselves in the water rather than making the shivery trip to the changing rooms, the results suggest that the urine content was being topped up several times each day. The findings make for unwelcome reading, but swimmers might find some comfort in the measurements from eight hot tubs, which were found to have far higher urine levels. One hotel Jacuzzi had more than three times the concentration of sweetener than in the worst swimming pool. In total, the team sampled 31 different pools and tubs in two Canadian cities and found ACE to be present in 100% of the samples, with concentrations up to 570 times the background level in tap water samples. They used the average ACE concentration in Canadian urine to convert their measurements into approximate volumes of urine.

An anonymous reader quotes a report from Quartz: Nearly 1% of carbon emissions annually can be attributed to paper production, even though we recycle much of the paper we produce. Yadong Yin has a solution. He and his colleagues at the University of California at Riverside have invented a type of paper that can be printed on using just light, erased by heating, and reused up to 80 times. Yin created nanoparticles, which are a million times smaller than the thickness of human hair, with the dye Prussian blue, or its chemical analogues, and titanium oxide, which is commonly used in white wall paint. This mixture is then applied to normal paper. When the coating is exposed to ultraviolet light, electrons from titanium oxide move to the dye in the nanoparticle. This addition of electrons makes the blue dye turn white. Focusing the ultraviolet light into shapes, you can print white words on a blue background -- or blue words on a white background, which are easier to read. If left alone, the paper reverts to its original state in five days. That process can be accelerated by heating the paper to 120 C (250 F) for 10 minutes.

dryriver quotes CNN: Most of the time, when you order fast food, you know exactly what you're getting: an inexpensive meal that tastes great but is probably loaded with fat, cholesterol and sodium. But it turns out that the packaging your food comes in could also have a negative impact on your health, according to a report published Wednesday in the journal Environmental Science & Technology Letters. The report found fluorinated chemicals in one-third of the fast food packaging researchers tested.

These chemicals are favored for their grease-repellent properties. Along with their use in the fast food industry, fluorinated chemicals -- sometimes called PFASs -- are used "to give water-repellant, stain-resistant, and non-stick properties to consumer products such as furniture, carpets, outdoor gear, clothing, cosmetics (and) cookware," according to a news release that accompanied the report. "The most studied of these substances (PFOSs and PFOAs) has been linked to kidney and testicular cancer, elevated cholesterol, decreased fertility, thyroid problems and changes in hormone functioning, as well as adverse developmental effects and decreased immune response in children."
The chemicals can migrate into your food, says one of the study's authors, who suggests removing it from the packaging as quickly as possible. (You might also request your french fries in a paper cup, which are free from "chemicals of concern".) But they also suggest pressuring fast food chains to remove the chemicals from their packaging, and the president of the Foodservice Packaging Institute acknowledges that after the study concluded in 2015, fluorochemical-free packaging was introduced.

randomErr quotes a report from Quartz: In the last 10 years, researchers have developed specific sniff tests for diagnosing tuberculosis, hypertension, cystic fibrosis, and even certain types of cancer. A group of global researchers led by Hossam Haick at the Israel Institute of Technology have taken the idea a step further. They've built a device -- a kind of breathalyzer -- that is compact and can diagnose up to 17 diseases from a single breath of a patient. The breathalyzer has an array of specially created gold nanoparticles, which are sized at billionths of a meter, and mixed with similar-sized tubes of carbon. These together create a network that is able to interact differently with each of the nearly 100 volatile compounds that each person breaths out (apart from gases like nitrogen, oxygen, and carbon dioxide). Haick's team collected 2,800 breaths from more than 1,400 patients who were each suffering from at least one of 17 diseases (in three classes: cancer, inflammation, and neurological disorders). Each sample of the disease was then passed through the special breathalyzer, which then produced a dataset of the types of chemicals it could detect and in roughly what quantities. The team then applied artificial intelligence to the dataset to search for patterns in the types of compounds detected and the concentrations they were detected at. As they report in the journal ACS Nano, the data from the breathalyzer could be used to accurately detect that a person is suffering from a unique disease nearly nine out of ten times.

An anonymous reader quotes a report from The Telegraph: A new type of battery that lasts for days with only a few seconds' charge has been created by researchers at the University of Central Florida. The high-powered battery is packed with supercapacitors that can store a large amount of energy. It looks like a thin piece of flexible metal that is about the size of a finger nail and could be used in phones, electric vehicles and wearables, according to the researchers. As well as storing a lot of energy rapidly, the small battery can be recharged more than 30,000 times. Normal lithium-ion batteries begin to tire within a few hundred charges. They typically last between 300 to 500 full charge and drain cycles before dropping to 70 per cent of their original capacity. To date supercapacitors weren't used to make batteries as they'd have to be much larger than those currently available. But the Florida researchers have overcome this hurdle by making their supercapacitors with tiny wires that are a nanometer thick. Coated with a high energy shell, the core of the wires is highly conductive to allow for super fast charging. The battery isn't yet ready to be used in consumer devices, the researchers said, but it shows a significant step forward in a tired technology.

Science_afficionado writes: A team of engineers and materials scientists at Vanderbilt University have discovered how to make high-performance batteries using scraps of metal from the junkyard and common household chemicals. The researchers believe their innovation could provide the large amounts of economical electrical storage required by the grid to handle alternative energy sources and may ultimately allow homeowners to build their own batteries and disconnect entirely from the grid. Vanderbilt University News reports: "To make such a future possible, Pint headed a research team that used scraps of steel and brass -- two of the most commonly discarded materials -- to create the world's first steel-brass battery that can store energy at levels comparable to lead-acid batteries while charging and discharging at rates comparable to ultra-fast charging supercapacitors. The research team, which consists of graduates and undergraduates in Vanderbilt's interdisciplinary materials science program and department of mechanical engineering, describe this achievement in a paper titled 'From the Junkyard to the Power Grid: Ambient Processing of Scrap Metals into Nanostructured Electrodes for Ultrafast Rechargeable Batteries' published online this week in the journal ACS Energy Letters. The secret to unlocking this performance is anodization, a common chemical treatment used to give aluminum a durable and decorative finish. When scraps of steel and brass are anodized using a common household chemical and residential electrical current, the researchers found that the metal surfaces are restructured into nanometer-sized networks of metal oxide that can store and release energy when reacting with a water-based liquid electrolyte. The team determined that these nanometer domains explain the fast charging behavior that they observed, as well as the battery's exceptional stability. They tested it for 5,000 consecutive charging cycles -- the equivalent of over 13 years of daily charging and discharging -- and found that it retained more than 90 percent of its capacity."

Science_afficionado writes: A team of engineers and materials scientists at Vanderbilt University have discovered how to make high-performance batteries using scraps of metal from the junkyard and common household chemicals. The researchers believe their innovation could provide the large amounts of economical electrical storage required by the grid to handle alternative energy sources and may ultimately allow homeowners to build their own batteries and disconnect entirely from the grid. Vanderbilt University News reports: "To make such a future possible, Pint headed a research team that used scraps of steel and brass -- two of the most commonly discarded materials -- to create the world's first steel-brass battery that can store energy at levels comparable to lead-acid batteries while charging and discharging at rates comparable to ultra-fast charging supercapacitors. The research team, which consists of graduates and undergraduates in Vanderbilt's interdisciplinary materials science program and department of mechanical engineering, describe this achievement in a paper titled 'From the Junkyard to the Power Grid: Ambient Processing of Scrap Metals into Nanostructured Electrodes for Ultrafast Rechargeable Batteries' published online this week in the journal ACS Energy Letters. The secret to unlocking this performance is anodization, a common chemical treatment used to give aluminum a durable and decorative finish. When scraps of steel and brass are anodized using a common household chemical and residential electrical current, the researchers found that the metal surfaces are restructured into nanometer-sized networks of metal oxide that can store and release energy when reacting with a water-based liquid electrolyte. The team determined that these nanometer domains explain the fast charging behavior that they observed, as well as the battery's exceptional stability. They tested it for 5,000 consecutive charging cycles -- the equivalent of over 13 years of daily charging and discharging -- and found that it retained more than 90 percent of its capacity."

An anonymous reader quotes a report from Business Insider: A new study out Tuesday in the journal Environmental Science and Technology Letters looked at a national database that monitors chemical levels in drinking water and found that 6 million people were being exposed to levels of a certain chemical that exceed what the Environmental Protection Agency considers healthy. The chemicals, known as poly- and perfluoroalkyl substances, or PFASs, are synthetic and resistant to water and oil, which is why they're used in things like pizza boxes and firefighting foam. They're built to withstand the environment. But PFASs also accumulate in people and animals and have been observationally linked to an increased risk of health problems including cancer. And they can't be easily avoided, like with a water filter, for example. You can view the chart to see the tested areas of the U.S. where PFASs exceed 70 ng/L, which is what's considered a healthy lifetime exposure.

An anonymous reader quotes a report from UPI: All electronic cigarettes emit harmful chemicals, and levels of those toxic compounds are affected by factors such as temperature, type and age of the device, a new study finds. In laboratory tests, scientists found that the heat-related breakdown of propylene glycol and glycerin -- two solvents found in most e-cigarette liquids -- causes emissions of toxic chemicals such as acrolein, acetaldehyde and formaldehyde. All three are either respiratory irritants or carcinogens, the investigators said. The researchers also found that levels of harmful chemicals in e-cigarette vapor increase between the first few puffs and later puffs as the device gets hotter, and with each use of the device.The new study was published July 27 in the journal Environmental Science and Technology. "Advocates of e-cigarettes say emissions are much lower than from conventional cigarettes, so you're better off using e-cigarettes," study corresponding author Hugo Destaillats said in a Berkeley news release. "I would say, that may be true for certain users -- for example, long-time smokers that cannot quit -- but the problem is, it doesn't mean that they're healthier. Regular cigarettes are super unhealthy. E-cigarettes are just unhealthy," he explained. The FDA will start regulating e-cigarettes like tobacco on August 8, 2016.

Reader Socguy writes: A typical Lithium-ion battery breaks down badly between 5000-7000 cycles. Researchers at the University of California may have discovered a simple way to build a Lithium battery that can withstand 100,000+ cycles. This was a serendipitous discovery as the researcher was playing around with the battery and coated it in a thin gel layer. The researchers believe the gel plasticizes the metal oxide in the battery and gives it flexibility, preventing cracking.Dave Gershgorn, reporting for Popular Science: Instead of lithium, researchers at UC Irvine have used gold nanowires to store electricity, and have found that their system is able to far outlast traditional lithium battery construction. The Irvine team's system cycled through 200,000 recharges without significant corrosion or decline. However, they don't exactly know why. "We started to cycle the devices, and then realized that they weren't going to die," said Reginald Penner, a lead author of the paper. "We don't understand the mechanism of that yet." The Irvine battery technology uses a gold nanowire, no thicker than a bacterium, coated in manganese oxide and then protected by a layer of electrolyte gel. The gel interacts with the metal oxide coating to prevent corrosion. The longer the wire, the more surface area, and the more charge it can hold. Other researchers have been experimenting with nanowires for years, but the introduction of the protective gel separates UC Irvine's work from other research.Also from the report, "Penner suggests that a more common metal, like nickel, could replace the gold if the technology catches on."

An anonymous reader quotes a report from Ars Technica: A study published Tuesday in Environmental Science and Technology is the first to validate the long-held suspicion that pharmaceuticals may get trapped in infinite pee-to-food-to-pee loops, exposing consumers to drug doses with unknown health effects. In a randomized, single-blind pilot study, researchers found that anti-convulsive epilepsy drug carbamazepine, which is released in urine, can accumulate in crops irrigated with recycled water -- treated sewage -- and end up in the urine of produce-eaters not on the drugs. While the amounts of the drug in produce-eater's pee were four orders of magnitude lower than what is seen in the pee of patients purposefully taking the drugs, researchers speculate that the trace amounts could still have health effects in some people, such as those with a genetic sensitivity to the drugs, pregnant women, children, and those who eat a lot of produce, such as vegetarians. And with the growing practice of reclaiming wastewater for crop irrigation -- particularly in places that face water shortages such as California, Israel, and Spain --- the produce contamination could become more common and more potent, the authors argue.

ckwu writes: Superhydrophobic coatings that make water droplets dance and roll off of a surface show promise for applications such as self-cleaning cars, buildings, and food processing equipment. A new method creates a durable superhydrophobic coating by combining two common materials -- Teflon and a shrinkable plastic -- in a few simple steps. The researchers took inspiration from work done with the polystyrene material found in Shrinky Dinks -- the children's crafting kit. They deposited Teflon onto a similar material called PolyShrink, heated it, and found that the Teflon formed a crinkled surface that caused water to bead and roll off easily. The best results came from polyolefin shrink wrap coated with a 10nm-thick layer of Teflon. What's more, the surface is durable, having about the same scratch resistance as an aluminum coating, and repels water even after being scratched. Update: 03/09 16:10 GMT by T : Note: That's nm, rather than mm; now fixed.

ckwu writes: Tiny rocketlike particles that move around on their own in a hydrogen peroxide solution can detect trace amounts of the lethal toxin ricin within minutes. The tube-shaped, microsized particles--made of graphene oxide lined with platinum--carry sensor molecules that glow when they bind to ricin. In a dilute hydrogen peroxide solution, the platinum catalyzes the breakdown of the peroxide into water and oxygen. The oxygen bubbles shoot out one end of the tube, propelling them in the liquid like little rockets. The swimming motors could actively seek out ricin in a sample and speed up detection, paving the way towards a quick, easy way to detect the bioterrorism agent in food and water samples (without having to bring them back to a lab).

ckwu writes: Carbon nanotubes are exceptionally strong and stretchy. But so far, films made out of them have come nowhere close to having the mechanical strength of individual nanotubes. Researchers now report a simple fabrication method to make carbon nanotube films that are five times as strong as those made before—and stronger than films made from Kevlar or carbon fiber. The films had an average tensile strength of 9.6 gigapascals. By comparison, Kevlar fibers and commercially used carbon fibers are around 3.7 and 7 GPa, respectively. The films are also four times as pliable as conventional carbon fibers, able to elongate 8% on average.

An anonymous reader writes: A new study in the journal Environmental Science & Technology by researchers at Illinois Institute of Technology and The University of Texas at Austin sheds more light on potentially harmful emissions from desktop FDM 3D printers. The researchers measured emissions of both ultrafine particles (UFPs) and volatile organic compounds (VOCs) from 5 commercially available polymer-extrusion 3D printers using up to 9 different filaments. [The researchers] found that the individual VOCs emitted in the largest quantities included caprolactam from nylon-based and imitation wood and brick filaments (ranging from ~2 to ~180 g/min), styrene from acrylonitrile butadiene styrene (ABS) and high-impact polystyrene (HIPS) filaments (ranging from ~10 to ~110 g/min), and lactide from polylactic acid (PLA) filaments (ranging from ~4 to ~5 g/min). Styrene is classified as a "possible human carcinogen" by the International Agency for Research on Cancer (IARC classification group 2B). While caprolactam is classified as "probably not carcinogenic to humans," the California Office of Environmental Health Hazard Assessment (OEHHA) maintains low acute, 8-hour, and chronic reference exposure levels (RELs) of only 50, 7, and 2.2 g per cubic meters, respectively, all of which would likely be exceeded with just one of the higher emitting printers operating in a small office.

hypnosec writes: Researchers have developed a graphene-based coating they have proved effective at melting ice from a helicopter blade, paving the way for a real-time de-icer. The thin coating of graphene nanoribbons in epoxy has been developed by researchers at Rice University. In their tests, researchers show the coating is capable of melting centimeter-thick ice from a static helicopter rotor blade in a -4 degree Fahrenheit environment. A small voltage was applied to the coating that delivered electrothermal heat — called Joule heating — to the surface, which melted the ice.

ckwu writes: Last year, the news broke that in the U.S. almost 600,000 Volkswagen diesel vehicles, model years 2009 to 2015, contain software that altered engine performance and lowered emissions of toxic nitrogen oxides (NOx) during emissions tests but not during normal driving. A new study calculates the societal impact of this extra NOx: 46 excess expected deaths and $430 million in excess damages. U.S. regulators have filed a federal lawsuit against the automaker alleging violations of the Clean Air Act.

JMarshall writes: A new, elastic silver ink allows stretchy circuits to be drawn using a regular pen. Unlike previous inks, which have been made with silver nanoparticles and are prone to clog pens over time, this ink begins as a silver salt mixed with adhesive rubber (abstract). After writing, the ink is brushed with a formaldehyde and sodium hydroxide solution that reduces the silver ions to conductive silver nanoparticles. Researchers strung 14 LED lights together using the ink. The lights stayed lit even through stretching and bending the rubber sheet the circuit was drawn on.

JMarshall writes: A new, elastic silver ink allows stretchy circuits to be drawn using a regular pen. Unlike previous inks, which have been made with silver nanoparticles and are prone to clog pens over time, this ink begins as a silver salt mixed with adhesive rubber (abstract). After writing, the ink is brushed with a formaldehyde and sodium hydroxide solution that reduces the silver ions to conductive silver nanoparticles. Researchers strung 14 LED lights together using the ink. The lights stayed lit even through stretching and bending the rubber sheet the circuit was drawn on.

MTorrice writes about a new study that suggests neonicotinoids, one of the most widely used insecticides in the world, turn bumblebees into poor pollinators, leading to lower yields of apples and other plants. Chemical & Engineering News reports: "Neonicotinoid pesticides have been blamed for declines in bee populations worldwide. The chemicals don't kill bees, instead neonicotinoids impair the insects' abilities to learn, navigate, forage for nectar, and reproduce, according to studies published over the past several years. Now, researchers report that bees exposed to the pesticides also become less effective pollinators for crops. The study is the first to demonstrate that neonicotinoids can decrease the quality of a food crop by affecting bee pollination. About 30% of our food comes from crops, including fruits, nuts, seeds, and oils, that depend on insect pollinators, according to Dara A. Stanley of Royal Holloway, University of London, who led the new study. 'Basically,' she says, 'you can't have a balanced diet without insect pollination.'"

An anonymous reader writes: Modern storage methods are designed with longevity in mind. But we haven't always had the scientific knowledge or the foresight to do so. From the late 60s to the late 80s, much of the world's cultural history was recorded on magnetic tapes. Several decades on, those tapes are disintegrating, and we're faced with the permanent loss of that data. "The Cultural Heritage Index estimates that there are 46 million magnetic tapes in museums and archives in the U.S. alone—and about 40 percent of them are of unknown quality. (The remaining 60 percent are known to be either already disintegrated or in good enough condition to be played.)" Fortunately, researchers have worked out a method to determine which copies are recoverable. They "combined a laptop-sized infrared spectrometer with an algorithm that uses multivariate statistics to pick up patterns of all the absorption peaks." Here's the abstract from their research paper. "As the tapes go through the breakdown reaction, the chemical changes give off tiny signals in the form of compounds, which can be seen with infrared light—and when the patterns of reactions are analyzed with the model, it can predict which tapes are playable."

Science_afficionado writes: A lot of attempts have been made to use nanocrystals to improve battery performance, but the results have been disappointing. The problem is that when the size of the crystals drop below a certain size they begin to react chemically with the electrolytes which prevents them from recharging. Now, however, a team of engineers from Vanderbilt University report in an article published in the journal ACS Nano that they can overcome this problem by making the nanocrystals out of iron pyrite, commonly known as fool's gold.

JMarshall writes: Wildflowers growing near fields sown with pesticide-treated seeds can be reservoirs of bee-harming neonicotinoid compounds, according to new research. The study suggests bees get most of their exposure to these pesticides from wildflowers, rather than from the crops the pesticides are designed to protect. At the peak of flowering season, 97% of the pollen brought back to beehives tested in the UK came from wildflowers, not the canola crops they were growing alongside.

JMarshall writes: Impossible Foods, a Silicon Valley food start-up started by a Stanford professor who quit his job, just raised $108 million to pursue a plant-based burger that truly tastes like meat. This ACS article explains how Impossible Foods and other startups and researchers are tackling the tricky chemical and engineering challenge of making fake meat that tastes real. "Meat flavors and aromas come from thousands of volatile small molecules released by muscle and fat cell destruction. Flavor precursors start with an animal’s diet, which influences the molecular composition of its cells. After slaughter, enzymes in an animal’s muscle cells begin breaking down biomolecules into simpler amino acids, sugars, and fatty acids. This means some flavor molecules develop even as the meat ages during its trip to the store. Other flavor and aroma components emerge from reactions between sugars, amino acids, or fatty acids as the meat is cooked."

MTorrice writes: After a nice long bout of aerobic exercise, some people experience what's known as a "runner's high" — a feeling of euphoria coupled with reduced anxiety and a lessened ability to feel pain. For decades, scientists have associated this phenomenon with an increased level in the blood of beta-endorphins, which are opioid peptides thought to elevate mood. Now, German researchers have shown the brain's endocannabinoid system—the same one affected by marijuana's 9-tetrahydrocannabinol (THC)—may also play a role in producing runner's high, at least in mice.

ckwu writes: Polystyrene foams—including products like Styrofoam—are rarely recycled, and the materials biodegrade so slowly that they can sit in a landfill for hundreds of years. But a pair of new studies shows that mealworms will dine on polystyrene foam when they can't get a better meal, converting almost half of what they eat into carbon dioxide. In one study, the researchers fed mealworms polystyrene foam and found that the critters converted about 48% of the carbon they ate into carbon dioxide and excreted 49% in their feces. In the second study, the researchers showed that bacteria in the mealworms' guts were responsible for breaking down the polystyrene--suggesting that engineering bacteria might be a strategy for boosting the reported biodegradation.

MTorrice writes: Our chromosomes hold a partial record of prehistoric viral infections: About 8% of our genomes come from DNA that viruses incorporated into the cells of our ancestors. Over many millennia, these viral genes have accumulated mutations rendering them mostly dormant. But one of these viruses can reawaken in some patients with amyotrophic lateral sclerosis (ALS), a progressive muscle wasting disease commonly known as Lou Gehrig's disease. A new study demonstrates that this so-called endogenous retrovirus can damage neurons, possibly contributing to the neurodegeneration seen in the disease. The findings raise the possibility that antiretroviral drugs, similar to those used to treat HIV, could slow the progression of ALS in some patients.

MTorrice writes: Scientists in Wisconsin have grown three-dimensional brain-like tissue structures from human embryonic stem cells. These new structures are easy to grow and contain vascular cells and microglia, a type of immune cell. The breakthrough may change the way we test drugs and chemicals for their effect on the human brain. Currently most tests use multiple generations of rats and cost about $1 million to test one chemical. “In the near term, the approach might be more valuable to identify pathways and mechanisms of toxicity,” says William Murphy, a biomedical engineer at the University of Wisconsin. “We are gathering so much data on responses of these human brain mimics to known toxic chemicals that we can start to understand the signaling pathways affected by the chemicals. Not just whether, but how the chemicals are affecting the developing human brain.”

JMarshall writes: Recordings on old audio tapes won't be worth much in another 20 years, and some are already too degraded to play. A team including members from the Library of Congress report that infrared spectroscopy can noninvasively separate magnetic tapes that can still be played from those that can't, without risking the tapes by sticking them in a player. Unplayable tapes can sometimes be rescued by heating, which can make them playable for long enough to digitize. This method could help archivists identify which tapes need special handling before they get any worse.

MTorrice writes: A new study concludes that a brain protein causes the rare, Parkinson's-like disease called multiple systems atrophy (MSA) by acting like a prion, the misbehaving type of protein infamously linked to mad cow disease. The researchers say the results are the most definitive demonstration to date that proteins involved in many neurodegenerative disorders, such as Alzheimer's and Parkinson's, exhibit prion-like behavior: They can misfold into shapes that then coax others to do the same, leading to protein aggregation that forms neurotoxic clumps. If these other diseases are caused by prion-like proteins, then scientists could develop treatments that slow or stop disease progression by designing molecules that block prion propagation.